Recording medium

• US 5,800,950 A
• Filed: 03/13/1996
• Issued: 09/01/1998
• Est. Priority Date: 03/16/1995
• Status: Expired due to Fees

• Current Assignee: Kabushiki Kaisha Toshiba (Toshiba Corporation)
• Original Assignee: Kabushiki Kaisha Toshiba (Toshiba Corporation)
• Inventors: Miyamoto, Hirohisa, Hirao, Akiko, Hosoya, Masahiro, Nishizawa, Hideyuki, Sugiuchi, Masami
• Primary Examiner(s): ANGEBRANNDT, MARTIN J
• Application Number:
  US08/615,687
• Time in Patent Office: 902 Days
• Field of Search: 430/2, 430/1, 430/290, 359/1, 359/2, 359/3, 365/106, 365/124
• US Class Current: 430/1
• CPC Class Codes: G03G 5/02 Charge-receiving layers G03G5/153 takes precedence
• CPC Class Codes: G11B 11/08 using recording by electric charge or by variation of electric resistance or capacitance G11B11/002, G11B11/10 take precedence
• CPC Class Codes: G11B 7/00455 involving reflectivity, absorption or colour changes
• CPC Class Codes: G11B 7/0055 Erasing G11B7/006, G11B7/0065 take precedence
• CPC Class Codes: G11B 7/24 Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the arrangement of information on the carrier G11B7/007

Abstract

A recording element which comprises a recording layer containing, a first charge-generating material adapted to generate a first electric charge by a supply of external energy, a first charge-transporting material for transporting the first electric charge, a charge-capturing material for capturing the first electric charge, and a material having an electro-optical effect, wherein a change in optical properties of the recording layer is caused only through an inner electric field to be generated by a delivery of electric charge between the first charge-generating material generating electric charge and the charge-capturing material capturing the electric charge.

Claims

1. A recording element which comprises a recording layer containing:

a first charge-generating material adapted to generate a first electric charge by irradiation with light;

a first charge transporting material for transporting said first electric charge;

a charge-capturing material for capturing said first electric charge; and

material having an electro-optical effect;

wherein said recording element does not comprise means for applying an external electric field.

2. The recording element according to claim 1, wherein a dipole moment of at least one of said materials contained in said recording layer is 3.5 or more.

3. The recording element according to claim 2, wherein the material having a dipole moment of 3.5 or more is said first charge-transporting material.

4. A method of recording information, wherein the recording of information is carried out through a diffraction grating to be formed by irradiating a pair of coherent lights onto the recording element as claimed in claim 1, and

wherein no external electric field is applied to said recording layer.

5. A method of recording information in the recording element of claim 1, comprising:

irradiating said charge-generating material so as to generate an electric charge in said recoding element; and

diffusing said electric charge whereby said electric charge is captured by said charge-capturing material and an inner electric field is produced between said charge-generating and charge-capturing material;

wherein no external electric field is applied to said recording layer.

6. The method of recording information according to claim 5, wherein the recording of information is carried out through a diffraction grating to be formed by irradiating a pair of coherent lights onto the recording element.

7. The method of recording information according to claim 5, wherein said method further comprises changing the light absorption coefficient of said recording layer.

8. The method of recording information according to claim 5, wherein said method further comprises changing the fluorescence yield of said recording layer.

9. The method of recording information according to claim 5, wherein said method further comprises changing the refractive index of said recording layer.

10. A recording element which comprises a recording layer containing;

a compound which can be ionized or has a capability of increasing dipole moment by the application of external energy;

a charge-generating material generating an electric charge;

a charge-transporting material transporting said electric charge; and

a charge-capturing material for capturing said electric charge;

wherein said recording element does not comprise means for applying an external electric field.

11. The recording element according to claim 10, wherein a dipole moment of the charge-transporting material is 3.5 or more.

12. A method of recording information, wherein the recording of information is carried out through a diffraction grating to be formed by irradiating a pair of coherent lights onto the recording element as claimed in claim 10.

13. A drift mobility modulating element which comprises a recording layer containing;

a charge-generating material adapted to generate an electric charge by irradiation with light;

a charge-capturing material for capturing said electric charge; and

a charge transporting material for transporting said electric charge;

wherein a change in conductivity of said recording layer is caused by changing a drift mobility of said charge-transporting material according to an inner electric field to be generated by delivery of electric charge between said charge-generating material generating electric charge and said charge-capturing material capturing said electric charge; and

wherein said drift mobility modulating element does not comprise means for applying an external electric field.

14. A method of recording information, wherein the recording of information is carried out through a diffraction grating to be formed by irradiating a pair of coherent lights onto the drift mobility-modulating element as claimed in claim 13.

15. A recording element which comprises a recording layer containing;

a first charge-generating material adapted to generate a first electric charge by irradiation with light;

a first charge-transporting material for transporting said first electric charge;

a charge-capturing material for capturing said first electric charge; and

a material having an electro-optical effect;

wherein said recording element does not comprise means for applying an external electric field, and a dipole moment of at least one of said materials is 3.5 debye or more.

16. A recording element which comprises a recording layer containing;

a first charge-generating material adapted to generate a first electric charge by irradiation with light;

a second charge-generating material adapted to generate a second electric charge having an opposite polarity from that of said first electric charge;

a first charge transporting material for transporting said first electric charge;

a charge-capturing material for capturing said first electric charge; and

material having an electro-optical effect;

wherein said recording element does not comprise means for applying an external electric field.

17. The recording element according to claim 16, wherein an ionization potential and electron affinity of each components meet the following equations:

space="preserve" listing-type="equation">Ip(g)>

Ip(ct)>

Ip(tr)

space="preserve" listing-type="equation">X(tr)>

X(e)

wherein Ip(g) represents an ionization potential of the first charge-generating material, Ip(ct) represents an ionization potential of the first charge-transporting material, Ip(tr) represents an ionization potential of the charge-capturing material, X(tr) represents an electron affinity of charge-capturing material and X(e) represents an electron affinity of the second charge-generating material.

18. The recording element according to claim 16, wherein an ionization potential and electron affinity of each components meet the following equations:

space="preserve" listing-type="equation">Ip(g)>

Ip(ct)-σ

(ct)>

Ip(tr)+σ

(tr)

space="preserve" listing-type="equation">X(tr)>

X(e)

wherein Ip(g) represents an ionization potential of the first charge-generating material, Ip(ct) represents an ionization potential of the first charge-transporting material, Ip(tr) represents an ionization potential of the charge-capturing material, σ

(ct) represents an energy distribution width of the first charge-transporting material, σ

(tr) represents an energy distribution width of the charge-capturing material, X(tr) represents an electron affinity of charge-capturing material and X(e) represents an electron affinity of the second charge-generating material.

19. The recording element according to claim 16, which further comprises a second charge-transporting material which is adapted to transport said second electric charge.

20. The recording element according to claim 19, wherein an ionization potential and electron affinity of each components meet the following equations:

space="preserve" listing-type="equation">Ip(g)>

Ip(ct)>

Ip(tr)

space="preserve" listing-type="equation">X(tr)>

X(rt)>

X(e)

wherein Ip(g) represents an ionization potential of the first charge-generating material, Ip(ct) represents an ionization potential of the second charge-transporting material, Ip(tr) represents an ionization potential of the charge-capturing material, X(tr) represents an electron affinity of charge-capturing material, X(rt) represents an electron affinity of the second charge-transporting material and X(e) represents an electron affinity of the second charge-generating material.

21. A method of recording information, wherein the recording of information is carried out through a diffraction grating to be formed by irradiating a pair of coherent lights onto the recording element,

wherein said recording element comprises:

a recording layer comprising;

a first charge-generating material adapted to generate a first electric charge by irradiation with light;

a second charge-generating material adapted to generate a second electric charge having an opposite polarity from that of said first electric charge;

a first charge transporting material for transporting said first electric charge;

a charge-capturing material for capturing said first electric charge; and

material having an electro-optical effect;

wherein no external electric field is applied to said recording layer.

22. A method of erasing information, wherein the erasing of information is carried out through an elimination of a diffraction grating that can be effected by irradiating light onto the recording element,

wherein said recording element comprises:

a recording layer comprising;

a first charge-generating material adapted to generate a first electric charge by irradiation with light;

a second charge-generating material adapted to generate a second electric charge having an opposite polarity from that of said first electric charge;

a first charge transporting material for transporting said first electric charge;

a charge-capturing material for capturing said first electric charge; and

material having an electro-optical effect;

wherein no external electric field is applied to said recording layer.