Method for flame stabilization in a process for preparing synthesis gas

• US 5,803,724 A
• Filed: 06/04/1996
• Issued: 09/08/1998
• Est. Priority Date: 06/06/1995
• Status: Expired due to Term

• Current Assignee: Shell Oil Company (Shell Plc)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Wentinck, Hendrik Martinus, Oortwijn, Peter
• Primary Examiner(s): Jones, Larry
• Application Number:
  US08/657,574
• Time in Patent Office: 826 Days
• Field of Search: 431/4, 431/12, 431/75, 431/177, 431/10, 110/347
• US Class Current: 431/4
• CPC Class Codes: C01B 3/363 characterised by the burner used
• CPC Class Codes: F23D 14/74 Preventing flame lift-off

Abstract

A method is presented for stabilizing the flame on the tips of burner internals in a process for preparing synthesis gas by partial oxidation of a gaseous hydrocarbon-containing fuel. The method comprises supplying a gaseous hydrocarbon-containing fuel, a moderator gas and an oxidizer through a burner to a reactor, and adjusting the mass flow of the moderator gas such that the moderator gas concentration does not exceed a predetermined limit. The process conditions are effected such that the flame contacts the burner internal tips. In case of flame-lifting from the burner internal tips, the velocities and mass flows of the fuel and/or oxidizer and/or moderator gas are re-adjusted in such a manner that the flame is restabilized on the burner internal tips.

Claims

1. A method for stabilizing a flame on tips of burner internals in a process for preparing synthesis gas by partial oxidation of a gaseous hydrocarbon-containing fuel comprising the steps of:

a) supplying a gaseous hydrocarbon-containing fuel, a moderator gas and an oxidizer through a burner to a reactor, wherein each of said fuel, moderator gas and oxidizer is supplied at a velocity and mass flow, and wherein the mass flow of the moderator gas is adjusted such that the moderator gas concentration does not exceed a predetermined limit;

b) effecting process conditions such that the flame is contacting the burner internal tips; and

c) re-adjusting the velocity and mass flow of the fuel and/or oxidizer and/or moderator gas in case of flame-lifting from the burner internal tips in such a manner that the flame is restabilized on the burner internal tips, wherein the re-adjusted mass flow of the moderator gas does not cause the moderator gas concentration to exceed said predetermined limit of step a).

2. The method of claim 1, wherein the burner is a multi-orifice (co-annular) burner comprising a concentric arrangement of n passages or channels coaxial with a longitudinal axis of said burner, wherein n is an integer greater than 2.

3. The method of claim 2, wherein the moderator gas is passed through a channel or slit between a gaseous hydrocarbon-containing fuel channel and an oxidizer channel.

4. The method of claim 1, wherein the flame is monitored.

5. The method of claim 4, wherein the flame is monitored by noise detection.

6. The method of claim 5 wherein the noise detection comprises pressure transducers.

7. The method of claim 4, wherein the flame is monitored optically.

8. The method of claim 7, wherein the flame is monitored by an optical probe inserted in a burner channel.

9. The method of claim 8, wherein the optical probe is inserted in a central channel of the burner.

10. The method of claim 1 wherein the burner internal tips are made from a material selected from the group consisting of ceramics, noble metals, and alloys thereof.

11. The method of claim 1, wherein the moderator gas is supplied with the gaseous hydrocarbon-containing fuel.

12. The method of claim 1 wherein the moderator gas is supplied with the oxidizer.

13. The method of claim 1, wherein the moderator gas is selected from the group consisting of aqueous steam, carbon dioxide, and a combination thereof.

14. The method of claim 1, wherein the fuel velocity is higher than the oxidizer velocity and the mass flow of the moderator gas is adjusted such that the concentration of moderator gas in the oxidizer is less than about 30 vol %.

15. The method of claim 1, wherein the oxidizer velocity is higher than the fuel velocity and the mass flow of the moderator gas is adjusted such that the concentration of moderator gas in the oxidizer is less than about 20 vol %.