Optical lens blank with polarizer aligned between plastic birefringent sheets

• US 5,805,336 A
• Filed: 04/05/1996
• Issued: 09/08/1998
• Est. Priority Date: 04/05/1996
• Status: Expired due to Term

• Current Assignee: Safilo USA Incorporated (Safilo Group SPA)
• Original Assignee: Polaroid Corporation (PLR IP Holdings LLC)
• Inventors: Dalzell, William H., Loshak, Igor
• Primary Examiner(s): Dzierzynski, Paul M.
• Assistant Examiner(s): Schuberg, Darren E.
• Application Number:
  US08/628,781
• Time in Patent Office: 886 Days
• Field of Search: 359/483, 359/485, 359/490, 359/491, 359/493, 359/494, 359/497, 359/614, 65/37, 65/38, 264/1.31, 264/1.32, 351/49, 425/808
• US Class Current: 359/487.02
• CPC Class Codes: B29C 51/082 by shaping between complementary mould parts
• CPC Class Codes: B29D 11/0073 Optical laminates
• CPC Class Codes: B29D 11/00951 Measuring, controlling or regulating
• CPC Class Codes: B29L 2009/00 Layered products
• CPC Class Codes: B29L 2011/0016 Lenses
• CPC Class Codes: G02B 5/3083 Birefringent or phase retarding elements G02B5/3008, G02B5/3016 take precedence; systems for polarisation control G02B27/286; manufacturing phase modulating patterns by lithographic processes G03F7/001
• CPC Class Codes: G02C 2202/16 Laminated or compound lenses
• CPC Class Codes: G02C 7/12 Polarisers

Abstract

A thermoformed plastic laminar light-polarizing composite lens blank is produced from a laminate comprising a light-polarizing layer between polymeric layers. The absorption axis of the light-polarizing layer of the laminate is aligned to substantial parallelism with a principal index of refraction of the polymeric layer which forms the convex surface of the lens blank and which is birefringent, thereby to minimize retardation effects of the birefringent material on plane polarized light. The polymeric layer which forms the concave surface of the lens blank is substantially thicker than the opposed polymeric layer in order to accommodate grinding of the surface thereof to an ophthalmic prescription. Thermoforming of unitary portions cut from a supply of the laminate is performed under heat and pressure.

Claims

1. A unitary laminar curved composite lens blank for the production of a light-polarizing optical lens, the lens blank comprising in order:

a first light-transmissive birefringent polymeric layer;

a light-polarizing layer;

and a second light-transmissive polymeric layer;

said first light-transmissive birefringent layer defining a convex surface of said lens blank and being a thin layer relative to said second light-transmissive layer;

said second light-transmissive layer defining a concave surface of the lens blank and being substantially thicker than the first light-transmissive layer and having a thickness sufficient to permit grinding of the concave surface thereof for production of optical properties desired in said light-polarizing optical lens;

said convex surface of said unitary laminar curved composite lens blank providing at least substantially the optical properties desired in said light-polarizing optical lens and said concave surface thereof being grindable to a surface providing said light-polarizing optical lens with said desired optical properties;

said light-polarizing layer and at least the first of said first and second light-transmissive layers being aligned such that a principal index of refraction direction of the light-transmissive layer is in substantial parallelism with a light absorption axis of the light-polarizing layer.

2. The lens blank of claim 1 wherein said first light-transmissive birefringent polymeric layer is a uniaxially stretched polymeric sheet material exhibiting a major index of refraction along the uniaxial stretch direction.

3. The lens blank of claim 2 wherein said stretch direction of said first light-transmissive birefringent polymeric layer is in substantial alignment with said absorption axis of said light-polarizing layer.

4. The lens blank of claim 3 wherein said stretch direction and said absorption axis of said light-polarizing layer subtend an angle of ±

one degree.

5. The lens blank of claim 3 wherein each of said first and second light-transmissive polymeric layers is a uniaxially stretched birefringent polymeric sheet exhibiting a major index of refraction along the stretch direction.

6. The lens blank of claim 5 wherein each of said first and second light-transmissive birefringent polymeric sheets comprises an acrylic polymer.

7. The lens blank of claim 6 wherein each of said sheets of acrylic polymer comprises an extruded poly(methylmethacrylate) sheet.

8. The lens blank of claim 2 wherein said light-polarizing layer comprises a sheet of polyvinyl alcohol stained with a dichroic dye or a sheet of polyvinyl alcohol containing polyvinylene light-polarizing species.

9. The lens blank of claim 2 wherein said first light-transmissive polymeric layer has a thickness in the range of 0.127 mm. to 1.91 mm. and said second light-transmissive polymeric layer has a thickness from 3 to 100 times the thickness of said first light-transmissive polymeric layer.

10. A method of preparing a curved optical lens blank which comprises the steps of:

providing a supply of a composite light-polarizing laminate, said laminate comprising, in order and in superposed relation, a first light-transmissive birefringent polymeric layer, a light-polarizing layer, and a second light-transmissive polymeric layer, said first light-transmissive layer being a thin layer relative to said second light-transmissive layer, said second light-transmissive layer being substantially thicker than said first light-transmissive layer and having a thickness sufficient to permit the grinding of material therefrom in the optical grinding of a concave surface of a lens to be formed from said laminar composite structure, said light-polarizing layer and at least the first of said first and second light-transmissive layers being aligned such that a principal index of refraction direction of the light-transmissive layer is in substantial parallelism with a light-absorption axis of the light-polarizing layer;

cutting and removing from said supply of said light-polarizing laminate, a unitary portion of a size sufficient for the production therefrom of a curved lens;

placing said unitary portion between opposed concave and convex platens, with the first light-transmissive layer of said portion positioned for shaping by said concave platen;

heating and pressing said platens together, said pressing being sufficient to shape said unitary portion into a curved lens having a convex surface defined by the first light-transmissive layer thereof, and a concave surface defined by the second light-transmissive layer thereof, each said surface having a radius of curvature corresponding substantially to the radius of curvature of the respective platen forming said surface; and

removing the resulting curved lens from between said platens.

11. The method of claim 10 wherein said first light-transmissive birefringent polymeric layer is a uniaxially stretched polymeric sheet material exhibiting a major index of refraction along the uniaxial stretch direction.

12. The method of claim 11 wherein said stretch direction of said first light-transmissive birefringent polymeric layer is in substantial alignment with said absorption axis of said light-polarizing layer.

13. The method of claim 12 wherein said stretch direction and said absorption axis of said light-polarizing layer subtend an angle of less than ±

one degree.

14. The method of claim 11 wherein each of said first and second light-transmissive polymeric layers is a uniaxially stretched birefringent polymeric sheet exhibiting a major index of refraction along the stretch direction.

15. The method of claim 14 wherein each of said first and second light-transmissive birefringent polymeric sheets comprises an acrylic polymer.

16. The method of claim 15 wherein said acrylic polymer comprises polymethylmethacrylate.

17. The method of claim 11 wherein said light-polarizing layer comprises a sheet of polyvinyl alcohol stained with a dichroic dye or a sheet of polyvinyl alcohol containing polyvinylene light-polarizing species.

18. The method of claim 11 wherein said first light-transmissive polymeric layer has a thickness in the range of 0.025 mm. to 1.91 mm. and said second light-transmissive polymeric layer has a thickness from 3 to 100 times the thickness of said first light-transmissive polymeric layer.

19. The method of claim 11 comprising the step of grinding said concave surface defined by said second light-transmissive layer to an ophthalmic prescription.

20. A method of preparing a series of lens blanks for the production of prescription ophthalmic lenses therefrom which comprises the steps of:

providing a supply of a composite light-polarizing laminate, said laminate comprising, in order and in superposed relation, a first light-transmissive birefringent polymeric layer, a light-polarizing layer, and a second light-transmissive polymeric layer, said first light-transmissive layer being a thin layer relative to said second light-transmissive layer, said second light-transmissive layer being substantially thicker than said first light-transmissive layer and having a thickness sufficient to permit the grinding of material therefrom in the optical grinding of a concave surface of a lens to be formed from said laminar composite structure, said light-polarizing layer and at least the first of said first and second light-transmissive layers being aligned such that a principal index of refraction direction of the light-transmissive layer is in substantial parallelism with a light-absorption axis of the light-polarizing layer;

cutting and removing from said supply of said light-polarizing laminate, a unitary lens-blank of a size sufficient for the production therefrom of a curved lens;

placing said unitary portion between opposed concave and convex platens, with the first light-transmissive layer of said portion positioned for shaping by said concave platen to a first convex lens surface having a refractive power in the range of from two to ten diopters;

heating and pressing said platens together, said pressing being sufficient to shape said first unitary portion into a curved lens having said first convex lens surface and a concave surface defined by the second light-transmissive layer thereof, each said surface having a radius of curvature corresponding substantially to the radius of curvature of the respective platen forming said surface;

removing the resulting curved lens blank from between said platens; and

repeating each of said placing, heating-and-pressing and removing steps, using a series of concave platens for the shaping of unitary portions to each of a series of convex lens surfaces, each such surface having a different one of the remaining said refractive powers within said range of refractive powers;

thereby to provide a series of lens blanks, each of which, has a convex lens surface within said range.