UV-curable fresnel lens resin composition, fresnel lens, and back projection screen

• US 5,805,358 A
• Filed: 07/29/1996
• Issued: 09/08/1998
• Est. Priority Date: 07/29/1995
• Status: Expired due to Term

• Current Assignee: Dai Nippon Printing Company Limited, Sanyo Chemical Industries Limited
• Original Assignee: Dai Nippon Printing Company Limited, Sanyo Chemical Industries Limited
• Inventors: Honda, Makoto, Yamashita, Tsutomu, Osawa, Futoshi, Okubo, Michiharu
• Primary Examiner(s): Rodee, Christopher D.
• Assistant Examiner(s): VERSTEEG, STEVEN H
• Application Number:
  US08/688,260
• Time in Patent Office: 771 Days
• Field of Search: 522/96, 522/104, 522/107, 522/171, 522/93, 522/174, 522/182, 359/742, 359/743
• US Class Current: 359/742
• CPC Class Codes: C08L 33/14 of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
• CPC Class Codes: G02B 1/041 Lenses
• CPC Class Codes: G02B 3/08 with discontinuous faces, e.g. Fresnel lens diffractive Fresnel lenses G02B5/1876
• CPC Class Codes: G03B 21/602 Lenticular screens G03B21/625 takes precedence
• CPC Class Codes: Y10T 428/31573 Next to addition polymer of ethylenically unsaturated monomer

Abstract

UV-curable Fresnel lens resin compositions 1a! comprising a (meth)acrylate containing hydroxyl group and aromatic ring (A1), a urethane group-containing (meth)acrylate (A2) comprising an aromatic diol, an aromatic ring-containing monofunctional (meth)acrylate (A3), and a photopolymerization initiator (B) and 1b! comprising (A1), a mono- or di(meth)acrylate monomer (A4), and (B), further supplemented with a polyester (C1) comprising an aromatic diol and a phosphate (C2) for the formation of a Fresnel lens on a sheet or plate made of a methyl methacrylate (co)polymer; a Fresnel lens formed by UV cure of composition 1a! or 1b!; and a rear projection screen including a sheet or plate carrying said Fresnel lens. The Fresnel lens has high refractive index, antistatic properties and is satisfactory in adhesion to a sheet or plate.

Claims

1. A Fresnel lens comprising a resin formed by UV cure of a resin composition in situ on a sheet or plate made of a methyl methacrylate polymer or copolymer, wherein said resin composition comprises:

(A1) an acrylate or methacrylate containing hydroxyl group and aromatic ring;

(A2) a urethane group-containing acrylate or methacrylate having a moiety of an aromatic diol (a1) represented by the following general formula;

##STR3## wherein Ph represents 1,4-phenylene group R¹, R² and R³ each represents a hydrogen atom or methyl group, m and n each represents an integer of 1 to 15, and (m+n) is equal to 2 to 20;

(A3) an aromatic ring-containing monofunctional acrylate or methacrylate;

(B) a photopolymerization initiator; and

(C3) a plasticizer with a solubility parameter in the range of 10.0 to 11.5.

2. The Fresnel lens according to claim 1 which contains 20 to 60 weight % of (A1), 10 to 50 weight % of (A2), 5 to 50 weight % of (A3), 0.1 to 10 weight % of (B) and 1 to 20 weight % of (C3).

3. The Fresnel lens according to claim 1 wherein (A2) is a reaction product of an organic isocyanate (b2) with a hydroxyl group-containing acrylate or methacrylate (b3) and a polyester polyol (b1) derived from (a1) and a dicarboxylic acid (a2).

4. The Fresnel lens according to claim 3 wherein (a2) is at least one dicarboxylic acid selected from the group consisting of maleic acid, fumaric acid, succinic acid, adipic acid and the acid anhydrides thereof.

5. The Fresnel lens according to claim 1 wherein (A1) is an acrylate containing hydroxyl group and aromatic ring;

R² and R³ in formula (1) each represent methyl; and

a dicarboxylic acid (a2) being maleic acid or fumaric acid.

6. The Fresnel lens according to claim 5 wherein R¹ in formula (1) is a methyl group, and said dicarboxylic acid (a2) is maleic acid.

7. A Fresnel lens comprising a resin formed by UV cure of a resin composition in situ on a sheet or plate made of a methyl methacrylate polymer or copolymer, wherein said resin composition comprises:

(A1) an acrylate or methacrylate containing hydroxyl group and aromatic ring;

(A2) a urethane group-containing acrylate or methacrylate having a moiety of an aromatic diol (a1) represented by the following general formula;

##STR4## wherein Ph represents 1,4-phenylene group, R¹, R² and R³ each represents a hydrogen atom or methyl group, m and n each represents an integer of 1 to 15, and (m+n) is equal to 2 to 20;

(A3) an aromatic ring-containing monofunctional acrylate or methacrylate;

(B), a photopolymerization initiator; and

(C2) a phosphate of the following general formula (2);

space="preserve" listing-type="equation"> R(OCH.sub.2 CH.sub.2).sub.S O!.sub.t PO(OH).sub.(3-t) (

     2)

wherein R represents an alkyl group containing 5 to 16 carbon atoms, s represents an integer of 1 to 4, and t represents an integer of 1 or 2.

8. The Fresnel lens according to claim 7 which contains 20-50 weight % of (A1) 10 to 50 weight % of (A2), 5 to 50 weight % of (A3), 0.1 to 10 weight % of (B) and 0.1 to 2.0 weight % of (C2).

9. The Fresnel lens according to claim 7 wherein (A2) is a reaction product or an organic isocyanate (b2) with a hydroxyl group-containing acrylate or methacrylate (b3) and a polyester polyol (b1) derived from (a1) and a dicarboxylic acid (a2).

10. The Fresnel lens according to claim 9 wherein (a2) is at least one dicarboxylic acid selected from the group consisting of maleic acid, fumaric acid, succinic acid, adipic acid and the acid anhydrides thereof.

11. The Fresnel lens according to claim 7 wherein (A1) is an acrylate containing hydroxyl group and aromatic ring;

R² and R³ in formula (1) each represents methyl; and

a dicarboxylic acid (a2) being maleic acid or fumaric acid.

12. The Fresnel lens according to claim 11 wherein R¹ in formula (1) is a methyl group, and said dicarboxylic acid (a2) is maleic acid.