Color changeable aqueous adhesive systems

• US 5,807,918 A
• Filed: 03/26/1996
• Issued: 09/15/1998
• Est. Priority Date: 03/26/1996
• Status: Expired due to Term

• Current Assignee: Patch Rubber Co. (Myers Industries Incorporated)
• Original Assignee: Patch Rubber Co. (Myers Industries Incorporated)
• Inventors: Carter, Marlo
• Primary Examiner(s): Szekely, Peter A.
• Application Number:
  US08/622,113
• Time in Patent Office: 903 Days
• Field of Search: 524/270, 524/271, 524/272, 524/273, 524/274, 524/495, 524/496
• US Class Current: 524/495
• CPC Class Codes: C08K 3/04 Carbon
• CPC Class Codes: C08L 21/02 Latex
• CPC Class Codes: C09J 121/02 Latex

Abstract

The invention describes both a method for bonding at least two elastomeric substrates together, wherein one of the substrates is a tire casing and another substrate is a tire tread, and an aqueous color changeable adhesive for effecting the bonding. The method includes the steps of buffing at least one surface of at least one of the substrates to an RMA 2 or RMA 3, applying the color changeable aqueous adhesive to the at least one surface, drying the adhesive for at least a period of time to permit an initial light grey color of the adhesive as applied to change to a flat black, and contacting the substrates under pressure to bond the substrates together. The color changeable aqueous adhesive includes at least a rubber latex emulsion, a tackifier, a pH adjustment agent, and a carbon black emulsion, wherein the carbon black functions both as a reinforcing agent and a visible color indicia means for evaluating the degree of dryness of the adhesive, which correlates to the degree of tack of the adhesive. The carbon black is a lampblack.

Claims

1. A color changeable initially tacky aqueous adhesive comprising on an active ingredients basis:

from 12 to 58 weight percent of a rubber latex;

from 1 to 20 weight percent of a tackifier;

from 0.01 to 0.06 weight percent of a pH adjustment agent; and

from 0.04 to 2 weight percent of a lampblack,

wherein the lampblack functions both as a reinforcing agent and a visible color indicia means for evaluating the degree of dryness of the adhesive, which correlates to the degree of tack of the adhesive, said adhesive being initially a gray when applied and changing to a black when dry.

2. The adhesive of claim 1 wherein the weight percent of active ingredients is

from 27 to 43 weight percent for the rubber latex,

from 5 to 15 weight percent for the tackifier,

from 0.02 to 0.2 weight percent for the pH adjustment agent and

from 0.12 to 0.68 weight percent for the lampblack,

with a balance of water.

3. The adhesive of claim 1 wherein the adhesive has essentially equal values of red, blue and green, essentially a zero value for saturation and a luminosity value which changes by at least 5% as the color changes from grey to black.

4. The adhesive of claim 3 wherein the luminosity value changes by at least 10%.

5. The adhesive of claim 4 wherein the luminosity value changes by at least 20%.

6. The adhesive of claim 1 which further comprises a thickening agent.

7. The adhesive of claim 5 wherein the thickening agent is a polyacrylate.

8. The adhesive of claim 1 wherein the rubber latex emulsion is selected from the group consisting of natural rubber and synthetic rubbers.

9. The adhesive of claim 8 wherein the synthetic rubbers are selected from the group consisting of polyisoprene, acrylonitrile-butadiene rubbers, styrene-butadiene rubbers, neoprene, butyl rubber, polybutadienes and ethylene-propylene-diene rubbery polymers.

10. The adhesive of claim 9 wherein

the diene contained in the ethylene-propylene-diene polymer is a non-conjugated diene.

11. The adhesive of claim 10 wherein the diene is selected from the group consisting of 1,4-hexadiene, ethylidene norbornene and dicyclopentadiene.

12. A color changeable initially tacky aqueous adhesive comprising on an active ingredients basis:

about 12 to 58 weight percent of a rubber latex;

about 5 to 15 weight percent of a tackifier;

about 0.02 to 0.2 weight percent of a pH adjustment agent; and

about 0.04 to 2 weight percent of a lampblack, wherein

the lampblack functions both as a reinforcing agent and a visible color indicia means for evaluating the degree of dryness of the adhesive, which correlates to the degree of tack of the adhesive,

said adhesive being initially grey when applied and changing to a black when dry,

said lampblack being added in an effective amount sufficient to change a luminosity value by at least 10% as the color changes from grey to black, and further wherein

said adhesive has essentially equal values of red, blue and green, essentially a zero value for saturation.

13. The adhesive of claim 12 wherein the luminosity value changes by at least 20%.

14. The adhesive of claim 12 which further comprises a thickening agent.

15. The adhesive of claim 14 wherein the thickening agent is a polyacrylate.

16. The adhesive of claim 12 wherein the rubber latex emulsion is selected from the group consisting of natural rubber and synthetic rubbers.

17. The adhesive of claim 16 wherein the synthetic rubbers are selected from the group consisting of polyisoprene, acrylonitrile-butadiene rubbers, styrene-butadiene rubbers, neoprene, butyl rubber, polybutadienes and ethylene-propylene-diene rubbery polymers.

18. The adhesive of claim 12 wherein

the diene contained in the ethylene-propylene-diene polymer is a non-conjugated diene.

19. The adhesive of claim 18 wherein the diene is selected from the group consisting of 1,4-hexadiene, ethylidene norbornene and dicyclopentadiene.

20. A color changeable initially tacky aqueous adhesive comprising on an active ingredients basis:

from 12 to 58 weight percent of a rubber latex,

said rubber latex being selected from the group consisting of natural rubber and synthetic rubbers and further wherein the synthetic rubbers are selected from the group consisting of polyisoprene, acrylonitrile-butadiene rubbers, styrene-butadiene rubbers, neoprene, butyl rubber, polybutadienes and ethylene-propylene-diene rubbery polymers;

from 1 to 20 weight percent of a tackifier;

from 0.01 to 0.06 weight percent of a pH adjustment agent; and

from 0.04 to 2 weight percent of a lampblack,

wherein the lampblack functions both as a reinforcing agent and a visible color indicia means for evaluating the degree of dryness of the adhesive, which correlates to the degree of tack of the adhesive, said adhesive being initially a gray when applied and changing to a black when dry.

21. The adhesive of claim 20 wherein the diene contained in the ethylene-propylene-diene polymer is a non-conjugated diene.

22. The adhesive of claim 21 wherein the diene is selected from the group consisting of 1,4-hexadiene, ethylidene norbornene and dicyclopentadiene.

23. The adhesive of claim 20 wherein the weight percent of active ingredients is

from 27 to 43 weight percent for the rubber latex,

from 5 to 15 weight percent for the tackifier,

from 0.02 to 0.2 weight percent for the pH adjustment agent and

from 0.12 to 0.68 weight percent for the lampblack,

with a balance of water.

24. The adhesive of claim 20 wherein the adhesive has essentially equal values of red, blue and green, essentially a zero value for saturation and a luminosity value which changes by at least 5% as the color changes from grey to black.

25. The adhesive of claim 24 wherein

the luminosity value changes by at least 10%.

26. The adhesive of claim 25 wherein

the luminosity value changes by at least 20%.

27. The adhesive of claim 20 which further comprises

a thickening agent.

28. The adhesive of claim 27 wherein

the thickening agent is a polyacrylate.