Adsorbents for ozone recovery from gas mixtures

• US 5,810,910 A
• Filed: 10/06/1995
• Issued: 09/22/1998
• Est. Priority Date: 10/06/1995
• Status: Expired due to Term

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Baumgartl, Arne, Coe, Charles Gardner, MacDougall, James Edward, Ludwig, Keith Alan
• Primary Examiner(s): SPITZER, ROBERT H
• Application Number:
  US08/540,110
• Time in Patent Office: 1,082 Days
• Field of Search: 95/96-105, 95/138, 95/902, 96/108, 96/130, 96/143, 96/144
• US Class Current: 95/138
• CPC Class Codes: B01D 2253/108 Zeolites
• CPC Class Codes: B01D 2253/1085 characterized by a silicon-aluminium ratio
• CPC Class Codes: B01D 2256/14 Ozone
• CPC Class Codes: B01D 2256/18 Noble gases
• CPC Class Codes: B01D 2257/106 Ozone
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2257/80 Water
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: B01J 20/186 Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
• CPC Class Codes: C01B 13/10 Preparation of ozone
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02P 20/151 Reduction of greenhouse gas [GHG] emissions, e.g. CO2
• CPC Class Codes: Y10S 95/902 Molecular sieve

Abstract

An improved adsorbent for ozone comprises a crystalline aluminosilicate in which at least 90% of the exchangeable cation content is in the acid form and further which contains between 0.5 and 20 wt % of one or more adsorbed components which are non-reactive with ozone. Preferably the adsorbed component is water, and the total non-framework metal content expressed as metal oxide is less than 0.4 mole %.

Claims

1. A method for recovering ozone from an ozone-containing gas mixture which comprises contacting said gas mixture with an ozone-selective adsorbent whereby said ozone is selectively adsorbed by said adsorbent, and recovering said ozone by desorption from said adsorbent, wherein said adsorbent comprises a crystalline aluminosilicate in which at least 90% of the exchangeable cation content is in the acid form and further which contains between 0.5 and 20 wt % of one or more adsorbed components which are non-reactive with ozone.

2. The method of claim 1 wherein the total non-framework metal content of said adsorbent expressed as metal oxide is less than 0.4 mole %.

3. The method of claim 1 wherein said crystalline aluminosilicate has a framework in which the molar Si/Al ratio is at least 3.0.

4. The adsorbent of claim 1 wherein said crystalline aluminosilicate is a zeolite selected from the group consisting of mordenite, ZSM-5, and Y-type zeolite.

5. The method of claim 1 wherein said one or more adsorbed components are selected from the group consisting of water, carbon dioxide, argon, and sulfur hexafluoride.

6. The method of claim 5 wherein one of said one or more adsorbed components is water and wherein said adsorbent contains between about 0.5 and 15 wt % of said water (based on dry adsorbent).

7. The method of claim 1 wherein said gas mixture is contacted with said adsorbent at a temperature between -173°

C. and +100°

C.

8. The method of claim 1 wherein less than 15% of the ozone selectively adsorbed by said adsorbent decomposes to oxygen prior to said desorption.

12. The method of claim 1 wherein one of said one or more components is water and wherein said zeolite adsorbent contains between about 0.5 and 15 wt % of said water (based on dry adsorbent).

9. A method for reducing the decomposition rate of ozone adsorbed on an adsorbent which comprises adsorbing on a zeolite adsorbent, prior to ozone adsorption, one or more components which are non-reactive with ozone, wherein the total non-framework metal content of said zeolite adsorbent is less than 0.4 mole % expressed as metal oxide.

10. The method of claim 9 wherein said zeolite adsorbent comprises a crystalline aluminosilicate in which at least 90% of the exchangeable cation content is in the acid form and further which contains between 0.5 and 20 wt % of said one or more components which are non-reactive with ozone.

11. The method of claim 10 wherein said one or more components are selected from the group consisting of water, carbon dioxide, argon, and sulfur hexafluoride.

13. An adsorbent for the recovery of ozone from ozone-containing gas mixtures which comprises a crystalline aluminosilicate in which at least 90% of the exchangeable cation content is in the acid form and further which contains between 0.5 and 20 wt % of one or more adsorbed components which are non-reactive with ozone.

14. The adsorbent of claim 13 wherein the total non-framework metal content expressed as metal oxide is less than 0.4 mole %.

15. The adsorbent of claim 13 wherein said crystalline aluminosilicate has a framework in which the molar Si/Al ratio is at least 3.0.

16. The adsorbent of claim 13 wherein said crystalline aluminosilicate is a zeolite selected from the group consisting of mordenite, ZSM-5, and Y-type zeolite.

17. The adsorbent of claim 13 wherein said one or more adsorbed components are selected from the group consisting of water, carbon dioxide, argon, and sulfur hexafluoride.

18. The adsorbent of claim 17 wherein one of said one or more adsorbed components is water and wherein said adsorbent contains between about 0.5 and 15 wt % of said water (based on dry adsorbent).