Automated, on-demand ion mobility spectrometry analysis of gas chromatograph effluents

• US 5,811,059 A
• Filed: 10/16/1995
• Issued: 09/22/1998
• Est. Priority Date: 10/16/1995
• Status: Expired due to Fees

• Current Assignee: The United States of America As Represented By The Secretary of Agriculture
• Original Assignee: The United States Of America As Represented By The Secretary Of The Army
• Inventors: Harden, Charles S., Genovese, James A., Snyder, A. Peter
• Primary Examiner(s): LUDLOW, JAN M
• Application Number:
  US08/544,241
• Time in Patent Office: 1,072 Days
• Field of Search: 436/161, 436/173, 436/153, 422/70, 422/89, 422/98, 73/23.37, 73/23.4, 73/23.42, 95/82, 96/101, 96/102, 96/103, 96/106, 250/287, 250/288
• US Class Current: 422/89
• CPC Class Codes: G01N 2030/383 by using auxiliary fluid
• CPC Class Codes: G01N 2030/6013 interfaces to detectors
• CPC Class Codes: G01N 27/622 Ion mobility spectrometry
• CPC Class Codes: G01N 30/10 using a splitter
• CPC Class Codes: G01N 30/16 Injection G01N30/24 takes precedence
• CPC Class Codes: G01N 30/32 of pressure or speed G01N30/36 takes precedence
• CPC Class Codes: G01N 30/6095 Micromachined or nanomachined, e.g. micro- or nanosize
• CPC Class Codes: Y10T 436/24 Nuclear magnetic resonance, electron spin resonance or other spin effects or mass spectrometry

Abstract

A chemical sampling apparatus including an interface between a miniature mobility spectrometer and a gas chromatography system. The apparatus has a gas chromatography an ion mobility spectrometer and an input for inputting a regulated flow of a gas to be analyzed to the gas chromatograph. An interface is positioned between the gas chromatograph and the ion mobility spectrometer. The interface accepts and analyzes eluted gas from the gas chromatograph and selectively inputs the eluted gas to the ion mobility spectrometer only when an eluted gas condition to be analyzed is detected.

Claims

1. An apparatus for detecting the presence of and analyzing a component in a gas which comprises,

(a) a gas chromatography;

(b) an ion mobility spectrometer;

(c) means for inputting a regulated flow of a gas to be analyzed to the gas chromatograph; and

(d) an interface positioned between the gas chromatograph and the ion mobility spectrometer;

(e) said interface including a detector for analyzing eluted gas from the gas chromatography, valve means directly connected to the ion mobility spectrometer for normally exhausting the analyzed eluted gas from said detector to preclude the analyzed eluted gas from entering the ion mobility spectrometer, and control means operatively connected to said detector and said valve means for selectively inputting a portion of the analyzed eluted gas to the ion mobility spectrometer for analysis in response to a detection signal from the detector corresponding to a component to be analyzed in the eluted gas.

2. The apparatus of claim 1 wherein the detection signal is the quantity by weight of a sample in the gas eluting from the gas chromatograph as determined by a gas chromatograph peak.

3. The apparatus of claim 1 wherein the detector comprises a one dimensional or non-dimensional detector.

4. The apparatus of claim 1 wherein the detector comprises one or more components selected from the group consisting of a thermal conductivity detector, surface acoustic wave detector, mass spectrometer, Fourier transform infrared spectrometer, flame photometric detector and an electron capture detector.

5. The apparatus of claim 1 wherein the control means comprises computer means and is operatively connected to the means for inputting.

6. The apparatus of claim 1 wherein the detector comprises a one dimensional or non-dimensional detector and the valve means comprises a shutoff valve.

7. The apparatus of claim 6 wherein the detector comprises one or more components selected from the group consisting of a thermal conductivity detector, surface acoustic wave detector, mass spectrometer, Fourier transform infrared spectrometer, flame photometric detector and an electron capture detector.