Integrated soil and fluid decontamination system

• US 5,814,234 A
• Filed: 08/14/1996
• Issued: 09/29/1998
• Est. Priority Date: 08/14/1996
• Status: Expired due to Fees

• Current Assignee: Bower C. George
• Original Assignee: Prosys Corporation
• Inventors: Bower, C. George, Bernat, Allan W.
• Primary Examiner(s): POPOVICS, ROBERT J
• Application Number:
  US08/696,499
• Time in Patent Office: 776 Days
• Field of Search: 210/747, 210/774, 210/804, 210/805, 210/806, 210/175, 210/177, 210/768, 210/770, 210/771, 210/779, 210/DIG. 5, 210/176, 110/236, 110/246, 110/346, 134/25.1, 134/26, 405/128, 34/376, 34/377, 34/378, 34/379
• US Class Current: 210/770
• CPC Class Codes: B09C 1/00 Reclamation of contaminated soil
• CPC Class Codes: B09C 1/002 involving in-situ ground water treatment
• CPC Class Codes: B09C 1/06 thermally
• CPC Class Codes: F23G 2201/20 Dewatering by mechanical means
• CPC Class Codes: F23G 2201/60 Separating
• CPC Class Codes: F23G 2206/10 reintroducing the heat in the same process, e.g. for predrying
• CPC Class Codes: F23G 2209/12 Sludge, slurries or mixtures of liquids
• CPC Class Codes: F23G 5/006 General arrangement of incineration plant, e.g. flow sheets
• CPC Class Codes: F23G 7/14 of contaminated soil, e.g. by oil
• CPC Class Codes: Y10S 210/05 Coalescer

Abstract

A method for decontaminating both soil and mixed waste water polluted by hydrocarbons in a single integrated process is disclosed. Contaminated mixed waste fluid is separated into water and hydrocarbons which are then used in the thermal decontamination of polluted soil through the volatilization of hydrocarbon contaminants. Flue gases containing the volatilized hydrocarbons from the thermal soil decontamination undergo oxidation. Thermal energy from the soil decontamination process and the thermal oxidization of the flue gases can be recovered and used to facilitate the separation of hydrocarbons and water. In this integrated system, every by-product of each step is either decontaminated or consumed in another operation of the system. Energy conservation within this system is also realized by the use of heat exchangers to transfer energy from where it is created by the process to where it is used elsewhere to enhance efficiency within the process. It is possible to run this apparatus and process so that the only outputs of this system are decontaminated soil and clean exhaust gases.

Claims

1. An integrated soil and fluid decontamination process including a coalescer, a thermal desorption unit having a contaminated soil input, and an oxidizer, said method comprising the steps of:

separating waste fluid comprising mixed water and oil into water, sludge and hydrocarbons;

further separating the water in the coalescer to remove remaining hydrocarbons from the water;

heating contaminated soil in the thermal desorption unit to volatilize the contaminant hydrocarbons in the soil thereby producing decontaminated soil;

adding water from the coalescer to the decontaminated soil to cool the decontaminated soil following said step of heating; and

combusting in the oxidizer, volatilized hydrocarbons produced in said step of heating, to produce flue gases.

2. An integrated soil and fluid decontamination process as defined in claim 1, further comprising the steps of:

selectively removing sludge obtained during said step of separating the waste fluid; and

adding the sludge to the contaminated soil input of the thermal desorption unit prior to said step of heating contaminated soil.

3. An integrated soil and fluid decontamination process as defined in claim 1, wherein said step of separating mixed waste fluid includes using an oil/water separator, said process further comprising the steps of:

scavenging hydrocarbon vapors from the oil/water separator; and

adding the hydrocarbon vapors to the oxidizer prior to said step of combusting in the oxidizer.

4. An integrated soil and fluid decontamination process as defined in claim 1, further comprising the steps of:

extracting thermal energy with a heat exchanger from the flue gases generated in said step of combusting in the oxidizer; and

transferring the thermal energy to the waste fluid with a preheat heat exchanger prior to said step of separating mixed waste fluid.

5. An integrated soil and fluid decontamination process as defined in claim 1, further comprising the steps of:

periodically backwashing the coalescer with water; and

combining used backwash water with the waste fluid prior to said step of separating waste fluid.

6. An integrated soil and fluid decontamination process as defined in claim 5, further comprising the steps of:

extracting thermal energy with a heat exchanger from the flue gases generated in said step of combusting in the oxidizer; and

transferring the thermal energy with a preheat backwash water heat exchanger to water to be used in said step of periodically backwashing the coalescer.

7. An integrated soil and fluid decontamination process as defined in claim 1, further comprising the steps of:

separating any remaining particulate matter out of the flue gases after said step of combusting in the oxidizer volatilized hydrocarbons; and

transferring the separated particulate matter to the contaminated soil input of the thermal desorption unit prior to said step of heating the contaminated soil.

8. An integrated soil and fluid decontamination process as defined in claim 1, further comprising the steps of:

transferring hydrocarbons produced by said step of separating waste fluid to the thermal desorption unit; and

burning the hydrocarbons as supplemental fuel for the thermal desorption unit during said step of heating the soil, said step of burning producing an exhaust gas.

9. An integrated soil and fluid decontamination process as defined in claim 8, further comprising the steps of:

combining prior to said step of combusting in an oxidizer, the exhaust gas created by said step of burning the hydrocarbons as supplemental fuel, and the volatilized hydrocarbons produced by said step of heating the soil; and

combusting both exhaust and volatilized hydrocarbons during said step of combusting in an oxidizer.

10. An integrated soil and fluid decontamination process including a coalescer, a thermal desorption unit having a contaminated soil input, and an oxidizer, said method comprising the steps of:

separating waste fluid comprising mixed water and oil into water, sludge and hydrocarbons;

further separating the water in the coalescer to remove remaining hydrocarbons from the water;

heating contaminated soil in the thermal desorption unit to volatilize the contaminant hydrocarbons in the soil thereby producing decontaminated soil, wherein said step of heating includes burning the hydrocarbons produced in said step of separating waste fluid, said step of burning producing an exhaust gas; and

combusting in the oxidizer, volatilized hydrocarbons produced in said step of heating, to produce flue gases.

11. An integrated soil and fluid decontamination process as defined in claim 10, further comprising the steps of:

selectively removing sludge obtained during said step of separating the waste fluid; and

adding the sludge to the contaminated soil input of the thermal desorption unit prior to said step of heating contaminated soil.

12. An integrated soil and fluid decontamination process as defined in claim 10, further comprising the steps of:

combining the exhaust gas created in said step burning hydrocarbons and the volatilized hydrocarbons produced by said step of heating the soil, prior to said step of combusting in the oxidizer; and

said step of combusting in the oxidizer includes combusting the combined exhaust gas and volatilized hydrocarbons combined in said step of combining.

13. An integrated soil and fluid decontamination process as defined in claim 10, further comprising the steps of;

extracting thermal energy with a heat exchanger from the flue gases generated in said step of combusting in the oxidizer; and

transferring the thermal energy to the waste fluid with a preheat heat exchanger prior to said step of separating waste fluid.

14. An integrated soil and fluid decontamination process as defined in claim 10, further comprising the steps of:

periodically backwashing the coalescer with water; and

combining used backwash water with the waste fluid prior to said step of separating waste fluid.

15. An integrated soil and fluid decontamination process as defined in claim 14, further comprising the steps of:

extracting thermal energy with a heat exchanger from the flue gases generated in said step of combusting in the oxidizer; and

transferring the thermal energy with a preheat backwash water heat exchanger to water to be used in said step of periodically backwashing the coalescer.

16. An integrated soil and fluid decontamination process as defined in claim 10, further comprising the steps of:

separating any remaining particulate matter out of the flue gases after said step of combusting in the oxidizer volatilized hydrocarbons; and

transferring the separated particulate matter to the contaminated soil input of the thermal desorption unit prior to said step of heating the contaminated soil.

17. An integrated soil and fluid decontamination process as defined in claim 10, further comprising the step of:

adding water from the coalescer to the decontaminated soil to cool the decontaminated soil following said step of heating.

18. An integrated soil and fluid decontamination process as defined in claim 10, wherein said step of separating waste fluid includes using an oil/water separator;

said process further comprising the following steps;

scavenging hydrocarbon vapors from the oil/water separator; and

adding the hydrocarbon vapors scavenged in said step of scavenging to the oxidizer prior to said step of combusting in the oxidizer.

19. An integrated soil and fluid decontamination process including a coalescer, a thermal desorption unit having a contaminated soil input, and an oxidizer, said method comprising the steps of:

separating waste fluid comprising mixed water and oil into water, sludge and hydrocarbons;

further separating the water in the coalescer to remove remaining hydrocarbons from the water;

heating contaminated soil in the thermal desorption unit to volatilize the contaminant hydrocarbons in the soil thereby producing decontaminated soil;

adding water from the coalescer to the decontaminated soil to cool the decontaminated soil following said step of heating;

combusting in the oxidizer, volatilized hydrocarbons produced in said step of heating to produce flue gases;

extracting thermal energy using a heat exchanger during said step of combusting; and

transferring the thermal energy using a preheat heat exchanger to preheat the waste fluid being used in said step of separating.

20. An integrated soil and fluid decontamination process as defined in claim 19, further comprising the steps of:

selectively removing the sludge obtained during said step of separating the waste fluid; and

adding the sludge, obtained in said step of selectively removing the sludge, to the contaminated soil input of the thermal desorption unit prior to said step of heating contaminated soil.

21. An integrated soil and fluid decontamination process as defined in claim 19, wherein said step of heating includes burning the hydrocarbons produced in said step of separating waste fluid, said step of burning producing an exhaust gas.

22. An integrated soil and fluid decontamination process as defined in claim 19, further comprising the steps of:

combining the exhaust gas created in said step burning hydrocarbons and the volatilized hydrocarbons produced by said step of heating the soil, prior to said step of combusting in the oxidizer; and

said step of combusting in the oxidizer includes combusting the combined exhaust gas and volatilized hydrocarbons combined in said step of combining.

23. An integrated soil and fluid decontamination process as defined in claim 19, wherein said step of separating waste fluid includes using an oil/water separator;

said process further comprising the following steps;

scavenging hydrocarbon vapors from the oil/water separator; and

adding the hydrocarbon vapors scavenged in said step of scavenging to the oxidizer prior to said step of combusting in the oxidizer.

24. An integrated soil and fluid decontamination process as defined in claim 19, further comprising the steps of:

periodically backwashing the coalescer with water; and

combining used backwash water with the waste fluid prior to said step of separating waste fluid.

25. An integrated soil and fluid decontamination process as defined in claim 24, further comprising the steps of:

extracting thermal energy with a heat exchanger from the flue gases generated in said step of combusting in the oxidizer; and

transferring the thermal energy with a preheat backwash water heat exchanger to water to be used in said step of periodically backwashing the coalescer.

26. An integrated soil and fluid decontamination process as defined in claim 19, further comprising the steps of:

separating any remaining particulate matter out of the flue gases after said step of combusting in the oxidizer volatilized hydrocarbons; and

transferring the separated particulate matter to the contaminated soil input of the thermal desorption unit prior to said step of heating the contaminated soil.