Reduced residue hard surface cleaner

• US 5,817,615 A
• Filed: 06/03/1996
• Issued: 10/06/1998
• Est. Priority Date: 02/07/1992
• Status: Expired due to Term

• Current Assignee: Clorox Company
• Original Assignee: Clorox Company
• Inventors: Garabedian, Aram Jr., Mills, Scott C., Choy, Clement K., Sibert, William P.
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): BOYER, CHARLES I
• Application Number:
  US08/657,075
• Time in Patent Office: 855 Days
• Field of Search: 510/180, 510/181, 510/182, 510/245, 510/235, 510/237, 510/252, 510/405, 510/409, 510/410, 510/411, 510/435, 510/499, 510/373, 510/503, 510/501
• US Class Current: 510/503
• CPC Class Codes: C11D 1/146 Sulfuric acid esters
• CPC Class Codes: C11D 1/58 Heterocyclic compounds
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/75 Amino oxides
• CPC Class Codes: C11D 1/825 Mixtures of compounds all of which are non-ionic
• CPC Class Codes: C11D 1/94 Mixtures with anionic, cationic or non-ionic compounds
• CPC Class Codes: C11D 3/044 Hydroxides or bases
• CPC Class Codes: C11D 3/046 Salts
• CPC Class Codes: C11D 3/10 Carbonates ; Bicarbonates
• CPC Class Codes: C11D 3/201 linear
• CPC Class Codes: C11D 3/2068 Ethers
• CPC Class Codes: C11D 3/30 Amines; Substituted amines ; Quaternized amines
• CPC Class Codes: C11D 3/32 Amides; Substituted amides
• CPC Class Codes: C11D 3/323 urea or derivatives thereof
• CPC Class Codes: C11D 3/33 Amino carboxylic acids
• CPC Class Codes: C11D 3/43 Solvents

Abstract

The invention provides an aqueous, hard surface cleaner with significantly improved residue removal and substantially reduced filming/streaking, said cleaner comprising:

(a) an effective amount of at least one organic solvent with a vapor pressure of at least 0.001 mm Hg at 25° C., and mixtures of such solvents;

(b) an effective amount of at least one semi-polar nonionic surfactant, said surfactant having the structure: ##STR1## wherein R¹ is C_5-20 alkyl, R² and R³ are both C_1-4 alkyl, or --(CH₂)_p --OH, although R² and R³ do not have to be equal, and p is 1-6;

(c) an effective amount of a buffering system which comprises a nitrogenous buffer which will result in a pH of greater than 6.5; and

(d) the remainder as substantially all water.

Claims

1. An aqueous, all temperature hard surface cleaner with significantly improved residue removal and substantially reduced filming/streaking, said cleaner consisting essentially of:

(a) about 1-50% of at least one water soluble or water-miscible organic solvent with a vapor pressure of at least 0.001 mm Hg at 25°

C., and mixtures of such solvents;

(b) about 0.001-10% of at least one semi-polar nonionic surfactant, said surfactant having the structure;

##STR9## wherein R¹ is C_5-20 alkyl, R² and R³ are both C_1-4 alkyl or --(CH₂)_p --OH, although R² and R³ do not have to be equal, and p is 1-6;

(c) an effective amount of a buffering system which comprises a nitrogenous buffer which will result in a pH of greater than 6.5, said buffer selected from the group consisting of monoethanolamine, ammonitan bicarbonate, ammonium carbonate and ammonium hydroxide, in the absence of inorganic builders, such as silicates and phosphates, which leave a residue; and

(d) the remainder as substantially all water.

3. The hard surface cleaner of claim 1 wherein said solvent is an alkanol which is selected from the group consisting of methanol, ethanol, n-propanol, isopropanol, butanol, pentanol, hexanol, their various positional isomers, and mixtures of the foregoing.

4. The hard surface cleaner of claim 1 wherein said solvent is an alkylene glycol ether which is selected from the group consisting of ethylene glycol monobutyl ether, ethylene glycol monopropyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, and mixtures thereof.

5. The hard surface cleaner of claim 4 wherein said solvent is ethylene glycol monobutyl ether.

6. The hard surface cleaner of claim 4 wherein said solvent is propylene glycol n-butyl ether.

7. The hard surface cleaner of claim 4 wherein said solvent is propylene glycol t-butyl ether.

8. The hard surface cleaner of claim 1 wherein said buffer is ammonium hydroxide.

9. The hard surface cleaner of claim 1 wherein said buffer is monoethanolamine.

10. The hard surface cleaner of claim 1 wherein said buffer is ammonium carbonate.

11. The hard surface cleaner of claim 1 wherein said buffer is ammonium bicarbonate.

12. A method of cleaning soil, without substantial residue remaining, from a hard surface comprising applying the cleaner of claim 1 to said soil and removing said soil and said cleaner.

13. The method of claim 12 wherein said applying step further comprises the metered delivery of said cleaner from a trigger sprayer.

14. The method of claim 12 wherein said applying step further comprises the metered delivery of said cleaner from a pump sprayer.

2. An aqueous hard surface cleaner with significantly improved residue removal and substantially reduced filming/streaking in challenging environmental conditions (high and low temperature), said cleaner consisting essentially of:

(a) about 1-50% of at least one water soluble or water-miscible organic solvent with a vapor pressure of at least 0.001 mm Hg at 25°

C., and mixtures of such solvents;

(b) about 0.001-10% of at least one semi-polar nonionic surfactant, said surfactant having the structure;

##STR10## wherein R¹ is C_5-20 alkyl, R² and R³ are both C_1-4 alkyl, or --(CH₂)_p --OH, although R² and R³ do not have to be equal, and p is 1-6;

(c) an effective amount of a buffering system which comprises a nitrogenous buffer which will result in a pH of greater than 6.5, said buffer selected from the group consisting of ammonium carbamate, monoethanolamine, ammonium bicarbonate, ammonium carbonate and ammonium hydroxide, in the absence of inorganic builders, such as silicates and phosphates, which leave a residue; and

(d) the remainder as substantially all water.