Ceramic composites and methods for producing same

• US 5,818,149 A
• Filed: 03/25/1996
• Issued: 10/06/1998
• Est. Priority Date: 03/25/1996
• Status: Expired due to Term

• Current Assignee: Grove Hydrogen Cells LLC (Intellectual Ventures LLC)
• Original Assignee: Rutgers University
• Inventors: Safari, Ahmad, Janas, Victor F., Bandyopadhyay, Amit, Danforth, Stephen C., Panda, Rajesh K., Agarwala, Mukesh
• Primary Examiner(s): Dougherty, Thomas M.
• Application Number:
  US08/622,510
• Time in Patent Office: 925 Days
• Field of Search: 310/357, 310/358, 310/322, 310/334
• US Class Current: 310/358
• CPC Class Codes: B33Y 70/10 Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
• CPC Class Codes: B33Y 80/00 Products made by additive manufacturing
• CPC Class Codes: H10N 30/092 Forming composite materials
• CPC Class Codes: H10N 30/852 Composite materials, e.g. having 1-3 or 2-2 type connectivity

Abstract

A process for forming novel ceramic composites is described. The disclosed process allows for novel composite designs, including composites with regions containing different materials. Moreover, the disclosed process allows for the manufacture of composites with volume fraction gradients of different types of material. Composites with fine-scale microstructures may be formed.

Claims

1. A piezoelectric composite comprising more than one piezoelectric phase and at least one non-piezoelectric phase wherein the phase geometry and structure of said piezoelectric phase and said non-piezoelectric phase is controlled and wherein at least one said piezoelectric phase and at least one said non-piezoelectric phase are continuously self-connected in the x, y, and z directions.

2. A piezoelectric composite of claim 1 wherein the said piezoelectric phase is selected from the group consisting of Pb(Zr,Ti)O₃, BaTiO₃, PbZrO₃, PbTiO₃, PbNb₂ O₆, (Pb,Ca)TiO₃, (Pb,Sm)TiO₃, Pb(NbO₂)₂ /PbTiO₃, (1--x)Pb(Mg_1/3 Nb_2/3)O₃ --xPbTiO₃, (1-x-y)Pb(Zn_1/3 Nb_2/3)O₃ --xPbTiO₃ --yBaTiO₃, and (1-x-y)Pb(Zn_1/3 Nb_2/3)O₃ --xBaTiO₃ --yPbTiO₃, xPZN--(1-x)PMN, xPMN--(1-x)PZT, xPZN--(1--x)PZT, Poly(vinyldene fluoride), copolymers of Poly(vinylidene flouride), polyvinylchloride, or polyvinylflouride.

3. A piezoelectric composite of claim 1 having more than one non-piezoelectric phase.

4. A piezoelectric composite of claim 1 having more than one piezoelectric phase and more than one non-piezoelectric phase.

5. A piezoelectric composite of claim 4 wherein at least one piezoelectric phase is continously self-connected only in two dimensions.

6. A piezoelectric composite of claim 4 wherein at least one non-piezoelectric phase is continously self-connected only in two dimensions.

7. A piezoelectric composite of claim 4 wherein at least one non-piezoelectric phase is continously self-connected only in one dimension.

8. A piezoelectric composite of claim 4 wherein at least one piezoelectric phase is continously self-connected only in one dimension.

9. A piezoelectric composite of claim 5 wherein at least one non-piezoelectric phase is continously self-connected only in one dimension.

10. A piezoelectric composite of claim 5 wherein at least one piezoelectric phase is continously self-connected only in one dimension.

11. A piezoelectric composite of claim 6 wherein at least one non-piezoelectric phase is continously self-connected only in one dimension.

12. A piezoelectric composite of claim 6 wherein at least one piezoelectric phase is continously self-connected only in one dimension.

13. A piezoelectric composite of claim 7 wherein at least one non-piezoelectric phase is continously self-connected only in two dimensions.

14. A piezoelectric composite of claim 7 wherein at least one piezoelectric phase is continously self-connected only in two dimensions.

15. A piezoelectric composite of claim 8 wherein at least one non-piezoelectric phase is continously self-connected only in two dimensions.

16. A piezoelectric composite of claim 8 wherein at least one piezoelectric phase is continously self-connected only in two dimensions.