Magnetochemical sensor and method for remote interrogation

• US 5,821,129 A
• Filed: 02/12/1997
• Issued: 10/13/1998
• Est. Priority Date: 02/12/1997
• Status: Expired due to Fees

• Current Assignee: Grimes, Craig A., William R. Seitz
• Original Assignee: Grimes, Craig A., William R. Seitz
• Inventors: Grimes, Craig A., Seitz, William R.
• Primary Examiner(s): LUDLOW, JAN M
• Application Number:
  US08/799,607
• Time in Patent Office: 608 Days
• Field of Search: 436/148, 436/149, 436/150, 436/151, 422/68.1, 422/83, 422/57, 324/345, 324/204, 324/219, 324/229, 324/230, 73/DIG. 2
• US Class Current: 436/151
• CPC Class Codes: G01N 27/4167 pH electrodes therefor G01N27/302, G01N27/36
• CPC Class Codes: G01N 27/72 by investigating magnetic variables
• CPC Class Codes: Y10S 73/02 Magnetostrictive

Abstract

A magnetochemical sensor for continuous and in-situ sensing of a given chemical species/stimuli includes two magnetically-soft magnetic film layers and a chemical transduction layer that shrinks or swells in the presence of that given chemical species/stimuli. The magnetic switching characteristics of the sensor are dependent upon the thickness of the chemical transduction layer. A method for remotely interrogating the magnetic switching characteristics of the sensor is also provided. In the method, magnetic flux detecting coils are utilized to monitor the sensor.

Claims

1. A method for remotely monitoring the concentration of a chemical species in an environment comprising the steps of:

providing a magnetochemical sensing means having a magnetization vector;

said magnetochemical sensing means being constructed from at least two magnetically-soft magnetic film layers and at least one chemical transduction layer between said magnetically-soft magnetic film layers;

introducing said sensing means to said environment;

providing an alternating magnetic field generating means;

introducing said sensing means in said environment to an alternating magnetic field produced by said generating means; and

providing a magnetic flux detection means;

whereby a magnetic flux resulting from periodic reversal of the magnetization vector of said sensing means is detected by the detection means and the presence or concentration of said chemical species in said environment is determined based upon the magnitude of said magnetic flux; and

whereby changes in the thickness of said transduction layer alter said magnetic switching characteristics of said sensing means dependent upon the surrounding concentration of said chemical species in said environment.

2. The method of claim 1, including coating said magnetically-soft magnetic film layers with a bio-compatible coating whereby said sensing means can be placed within environmentally sensitive areas and said magnetically-soft magnetic film layers are protected from the environmental surroundings.

3. The method of claim 1, including selecting a chemically responsive polymer that selectively interacts with said selected chemical species to be detected for said chemical transduction layer.

4. A method for remotely monitoring the concentration of a chemical species in an environment comprising the steps of:

providing a magnetochemical sensing means having a magnetization vector;

said magnetochemical sensing means being constructed chemical transduction layer sensitive to a selected chemical species, said transduction layer having magnetically-soft magnetic particles interspersed throughout;

introducing said sensing means to said environment;

providing an alternating magnetic field generating means;

introducing said sensing means in said environment to an alternating magnetic field produced by said generating means; and

providing a magnetic flux detection means;

whereby a magnetic flux resulting from periodic reversal of the magnetization vector of said sensing means is detected by the detection means and the presence or concentration of said chemical species in said environment is determined based upon the magnitude of said magnetic flux; and

whereby changes in the thickness of said chemical transduction layer alter said magnetic switching characteristics of said sensing means dependent upon the concentration of said selected chemical species.

5. A magnetochemical sensing apparatus comprising:

a sensing means including at least two magnetically-soft magnetic film layers, and at least one chemical transduction layer sensitive to a selected chemical species disposed between said magnetically-soft magnetic film layers;

a generator means for generating an alternating magnetic field; and

a detector means for detecting magnetic flux;

whereby changes in the thickness of said chemical transduction layer alter magnetic switching characteristics of said sensing means exposed to said alternating magnetic field and measured by said detector means dependent upon surrounding concentration of a selected chemical species.

6. A magnetochemical sensor having predetermined magnetic switching characteristics including a magnetization vector, said magnetization vector periodically reversing directions when placed in an alternating magnetic field thereby generating a magnetic flux, said magnetic flux being detectable as a series of voltage spikes comprising:

at least two magnetically-soft magnetic film layers; and

at least one chemically responsive polymer layer having a thickness and sensitive to a selected chemical species, alternatingly disposed between said magnetically-soft magnetic film layers;

the thickness of said chemically responsive polymer layer varying dependent upon the surrounding selected chemical species,

whereby changes in the thickness of said chemically responsive polymer layer alter the magnetic switching characteristics of said sensor.

7. The magnetochemical sensor of claim 6, further comprising a bio-compatible coating substantially surrounding said magnetically-soft magnetic film layers whereby said sensing apparatus can be placed within environmentally sensitive areas and said magnetically-soft magnetic film layers are protected from the environmental surroundings.

8. The magnetochemical sensor of claim 7, wherein said bio-compatible coating is titanium.

9. The magnetochemical sensor of claim 6, wherein said chemically responsive polymer is a lightly crosslinked polymer.

10. The magnetochemical sensor of claim 6, wherein said chemically responsive polymer is a polyacrylate.

11. The magnetochemical sensor of claim 6, wherein said chemically responsive polymer is a derivatized polystyrene.

12. The magnetochemical sensor of claim 6, wherein said chemically responsive polymer is a copolymer of an acrylate and a derivatized styrene.

13. The magnetochemical sensor of claim 6, wherein said magnetically-soft magnetic film layers are a magnetically soft alloy of iron.

14. The magnetochemical sensor of claim 6, where in said magnetically-soft magnetic film layers are a magnetically soft alloy of nickel.

15. The magnetochemical sensor of claim 6, wherein said magnetically-soft magnetic film layers are a magnetically soft alloy of cobalt.

16. The magnetochemical sensor of claim 6, wherein said magnetically-soft magnetic film layers are a magnetically soft alloy of gadolinium.

17. The magnetochemical sensor of claim 6, wherein said chemically responsive polymer layer has a substantially uniform thickness.

18. The magnetochemical sensor of claim 6, wherein said chemically responsive polymer layer is irreversibly sensitive to said selected chemical species;

whereby said sensor acts as a dosimeter and changes in the thickness of said chemical transduction layer alter said magnetic switching characteristics of said sensor dependent upon surrounding concentration of said selected chemical species.