Waste processing

• US 5,821,395 A
• Filed: 06/05/1995
• Issued: 10/13/1998
• Est. Priority Date: 06/16/1994
• Status: Expired due to Fees

• Current Assignee: BP Chemicals Ltd. (BP PLC)
• Original Assignee: BP Chemicals Ltd. (BP PLC)
• Inventors: Price, Alan George, Wilson, David Charles
• Primary Examiner(s): Yildirim, Bekir L.
• Application Number:
  US08/462,848
• Time in Patent Office: 1,226 Days
• Field of Search: 585/241, 585/648, 201/25, 208/460, 423/240 R, 423/240 S, 423/241
• US Class Current: 585/241
• CPC Class Codes: C08F 110/02 Ethene
• CPC Class Codes: C08F 110/06 Propene
• CPC Class Codes: C08F 112/08 Styrene
• CPC Class Codes: C08F 114/06 Vinyl chloride
• CPC Class Codes: C08F 2810/10 including a reactive processing step which leads, inter alia, to morphological and/or rheological modifications, e.g. visbreaking
• CPC Class Codes: C08F 8/26 Removing halogen atoms or halogen-containing groups from the molecule
• CPC Class Codes: C08F 8/50 Partial depolymerisation
• CPC Class Codes: C10G 1/10 from rubber or rubber waste

Abstract

This invention relates to a process for thermally cracking waste polymer(s) comprising chlorinated polymers in a reactor in the presence of a fluidizing gas and a fluidized bed of solid, particulate fluidizable material at a temperature from 350°-600° C. to cracked products comprising a mixed vapor of lower hydrocarbons which have a chlorine content of less than 50 ppm. In the process, the cracked products emerging from the fluidized bed are passed through one or more guard beds comprising calcium oxide or a compound capable of giving rise to calcium oxide under the reaction conditions maintained at a temperature in the range from 400°-600° C. in such a way that the chlorine content of the product is less than 50 ppm.

Claims

1. A process for preparing a mixed vapor of lower hydrocarbons having a chlorine content of less than 50 ppm which comprises thermally cracking at a temperature of from 350°

-600°

C. waste polymers containing chlorinated polymers in a reactor in the presence of a fluidizing gas and a fluidized bed of solid particulate fluidizable materials, and passing at a temperature of from 400°

-600°

C. the cracked products emerging from the fluidized bed through one or more guard beds comprising calcium oxide or a compound capable of giving rise to calcium oxide under the reaction conditions, the calcium oxide being of medium to high reactivity defined as >

40°

C. at 2 mins by BSS 6463;

Part 3 (1987), Method 4;

wherein the residence time of the cracked products in the guard beds is at least 0.3 seconds calculated on the basis of the volume of the calcium oxide reactor divided by the total gaseous flow through the reactor.

2. A process according to claim 1 wherein the fluidized bed is of a material selected from one or more of quartz sand, silica, ceramics, carbon black, refractory oxides.

3. A process according to claim 1 wherein the fluidizing gas is incapable of oxidising the hydrocarbons in the cracked products under the reaction conditions.

4. A process according to claim 1, claim 2 or claim 3 wherein the fluidized bed is operated at 400°

-550°

C.

5. A process according to claim 1 wherein the waste polymer is pre-conditioned in a preliminary stage to remove the bulk of chlorine prior to the introduction thereof into the fluidized bed for thermal cracking.

6. A process according to claim 5 wherein the pre-conditioning stage consists of the waste polymer being heated to a temperature from 250°

-450°

C. for a duration ranging from 30 seconds to 4 hours.

7. A process according to claim 6 wherein the pre-conditioning stage consists of the waste polymer being heated to a temperature from 250°

-350°

C. for a duration ranging from 10 minutes to 4 hours.

8. A process according to claim 6 wherein the pre-conditioning stage consists of the waste polymer being heated to a temperature from 300°

-450°

C. for 5 to 60 minutes.

9. A process according to claim 6 wherein the pre-conditioning stage consists of heating the waste polymer in an extruder of the type used in plastics processing operated at 300°

-450°

C.

10. A process according to claim 5 wherein one or more of the following products are introduced along with the waste polymer feed into the pre-conditioning stage:

i) some of the thermally cracked products recycled from the fluidized bed

ii) residue from the distillation of the thermally cracked product from the fluidized bed; and

iii) refinery product streams which arc substantially liquid at the temperature chosen for the pre-conditioning stage.

11. A process according to claim 1 wherein a solid absorbent capable of absorbing acid gases is admixed with the solid particulate material of the fluidized bed.

12. A process according to claim 11 wherein the solid absorbent is selected from the group consisting of one or more of calcium oxide, calcium carbonate, calcium hydroxide, magnesium oxide, magnesium hydroxide, magnesium carbonate, sodium carbonate and potassium carbonate.

13. A process according to claim 1 wherein the cracked products emerging from the fluidized bed is passed through a guard bed which comprises in addition to calcium oxide one or more alkaline materials selected from the group consisting of magnesium oxide, magnesium hydroxide, magnesium carbonate, sodium carbonate and potassium carbonate.

14. A process according to claim 1 wherein the calcium oxide in the guard bed has a mean particle diameter of 0.05-100 mm.

15. A process according to claim 1 wherein the guard bed is in the form of a fixed bed, a fluidized bed or a moving bed.

16. A process according to claim 1 wherein the guard bed is operated at a temperature in the range from 450°

-575°

C.

17. A process according to claim 1 wherein the products emerging from the guard bed have a chlorine content of less than 20 ppm.