Methods and apparatus for osmotic distillation

• US 5,824,223 A
• Filed: 11/08/1995
• Issued: 10/20/1998
• Est. Priority Date: 11/08/1995
• Status: Expired due to Fees

• Current Assignee: Rentiers Machinery Pty Limited
• Original Assignee: Rentiers Machinery Pty Limited
• Inventors: Johnson, Robert, Michaels, Alan Sherman
• Primary Examiner(s): FORTUNA, ANA M
• Application Number:
  US08/555,209
• Time in Patent Office: 1,077 Days
• Field of Search: 210/642, 210/644, 210/645, 210/640, 210/257.2, 426/13, 426/14, 426/239, 426/455
• US Class Current: 210/642
• CPC Class Codes: B01D 61/0022 Apparatus therefor
• CPC Class Codes: B01D 61/364 Membrane distillation

Abstract

Methods and apparatus are provided for osmotic distillation employing dehydrating aqueous solutions of potassium salts of phosphoric acid, pyrophosphoric acid, acetate, and blends thereof. Methods are also provided for the simultaneous osmotic distillation and removal of carbon dioxide from a sample of relatively low osmotic pressure employing alkaline potassium orthophosphate and pyrophosphate dehydrating solutions.

Claims

1. A method of osmotic distillation for the concentration of a sample of relatively low osmotic pressure comprising:

providing a sample to be concentrated having first osmotic pressure;

providing a solution having a higher osmotic pressure than said sample, said solution comprising a saturated or near-saturated aqueous solution containing one or more nonhalide salts, wherein said salts are chemically stable at temperatures up to the normal boiling point of the saturated solution of said salts, non-toxic to humans and animals, odorless and tasteless in aqueous solution, substantially incapable of forming precipitates when exposed to volatile components of feed solutions to be concentrated, non-corrosive to process equipment, and have large positive temperature coefficients of solubility in aqueous solution; and

placing said sample and said solution on opposite sides of a hydrophobic microporous membrane;

wherein said nonhalide salts are selected from the group consisting of tripotassium orthophosphate (K₃ PO₄), dipotassium monohydrogen orthophosphate (K₂ HPO₄), potassium dihydrogen orthophosphate (KH₂ PO₄), tetrapotassium pyrophosphate (K₄ P₂ O₇), tripotassium monohydrogen pyrophosphate (K₃ HP₂ O₇), dipotassium dihydrogen pyrophosphate (K₂ H₂ P₂ O₇), monopotassium trihydrogen pyrophosphate (KH₃ P₂ O₇), and blends thereof.

2. The method of claim 1 wherein said sample is a liquid.

3. The method of claim 2 wherein said liquid is a fruit juice, a vegetable juice, a liquid dairy product, a plant extract, or animal-extract.

4. The method of claim 2 wherein said liquid is a solution of a pharmaceutical or biological product.

5. The method of claim 4 wherein said liquid is a solution of a vaccine, an antibiotic, a peptide hormone, a regulatory peptide, or a vitamin.

6. A method of osmotic distillation for the concentration of a sample of relatively low osmotic pressure comprising:

providing a sample to be concentrated having a first osmotic pressure;

providing a solution having a higher osmotic pressure than said sample, said solution comprising a saturated or near-saturated aqueous solution containing one or more nonhalide salts, wherein said salts are chemically stable at temperatures up to the normal boiling point of the saturated solution of said salts, non-toxic to humans and animals, odorless and tasteless in aqueous solution, substantially incapable of forming precipitates when exposed to volatile components of feed solutions to be concentrated, non-corrosive to process equipment, and have large positive temperature coefficients of solubility in aqueous solution; and

placing said sample and said solution on opposite sides of a hydrophobic microporous membrane;

wherein said nonhalide salt is selected from the group consisting of tripotassium orthophosphate, dipotassium hydrogen orthophosphate, potassium dihydrogen orthophosphate, and blends thereof.

7. A method of osmotic distillation for the concentration of a sample of relatively low osmotic pressure comprising:

providing a sample to be concentrated having a first osmotic pressure;

providing a solution having a higher osmotic pressure than said sample, said solution comprising a saturated or near-saturated aqueous solution containing one or more nonhalide salts, wherein said salts are chemically stable at temperatures up to the normal boiling point of the saturated solution of said salts, non-toxic to humans and animals, odorless and tasteless in aqueous solution, substantially incapable of forming precipitates when exposed to volatile components of feed solutions to be concentrated, non-corrosive to process equipment, and have large positive temperature coefficients of solubility in aqueous solution; and

placing said sample and said solution on opposite sides of a hydrophobic microporous membrane;

wherein said nonhalide salt is selected from the group consisting of tetrapotassium pyrophosphate, tripotassium monohydrogen pyrophosphate, dipotassium dihydrogen pyrophosphate, monopotassium trihydrogen pyrophosphate, and blends thereof.

8. A method for the simultaneous osmotic distillation and removal of carbon dioxide from a sample of relatively low osmotic pressure comprising:

providing a sample to be concentrated having a first osmotic pressure and dissolved carbon dioxide;

providing a solution having a higher osmotic pressure than said sample, said solution comprising an aqueous alkaline solution of a nonhalide salt, wherein said salt is selected from the group consisting of tripotassium orthophosphate, dipotassium hydrogen orthophosphate, tetrapotassium pyrophosphate, tripotassium hydrogen pyrophosphate, dipotassium dihydrogen pyrophosphate, and blends thereof; and

placing said sample and said solution on opposite sides of a hydrophobic microporous membrane.

9. An osmotic distillation apparatus comprising a hydrophobic microporous membrane having opposing surfaces;

a sample to be concentrated contacting one of said surfaces; and

a strip solution contacting the other of said surfaces, said strip solution comprising a saturated or near saturated solution of one or more aqueous salts selected from the group consisting of tripotassium orthophosphate (K₃ PO₄), dipotassium monohydrogen orthophosphate (K₂ HPO₄), potassium dihydrogen orthophosphate (KH₂ PO₄), tetrapotassium pyrophosphate (K₄ P₂ O₇), tripotassium monohydrogen pyrophosphate (K₃ HP₂ O₇), dipotassium dihydrogen pyrophosphate (K₂ H₂ P₂ O₇), monopotassium trihydrogen pyrophosphate (KH₃ P₂ O₇), and blends thereof.