Sintered friction material, composite copper alloy powder used therefor and manufacturing method thereof

• US 5,824,923 A
• Filed: 09/28/1995
• Issued: 10/20/1998
• Est. Priority Date: 10/19/1994
• Status: Expired due to Fees

• Current Assignee: Sumitomo Electric Industries Limited (Sumitomo Corporation)
• Original Assignee: Sumitomo Electric Industries Limited (Sumitomo Corporation)
• Inventors: Kondoh, Katsuyoshi, Takano, Yoshishige
• Primary Examiner(s): Jenkins, Daniel J.
• Application Number:
  US08/535,458
• Time in Patent Office: 1,118 Days
• Field of Search: 75/231, 75/235, 75/247, 419/2, 419/11, 419/19, 419/13, 419/33, 419/38, 419/28, 419/29, 419/32, 419/56
• US Class Current: 75/247
• CPC Class Codes: B22F 1/09 Mixtures of metallic powders
• CPC Class Codes: B22F 1/148 Agglomerating
• CPC Class Codes: B22F 2009/041 by mechanical alloying, e.g. blending, milling
• CPC Class Codes: B22F 2999/00 Aspects linked to processes or compositions used in powder metallurgy
• CPC Class Codes: B22F 9/04 starting from solid material, e.g. by crushing, grinding or milling C22C1/1084 takes precedence; crushing, grinding or milling, in general, see the relevant subclasses, e.g. B02C
• CPC Class Codes: C22C 1/0425 Copper-based alloys
• CPC Class Codes: C22C 1/059 Making alloys comprising less than 5% by weight of dispersed reinforcing phases
• CPC Class Codes: C22C 32/0089 with other, not previously mentioned inorganic compounds as the main non-metallic constituent, e.g. sulfides, glass
• CPC Class Codes: F16D 69/027 Compositions based on metals or inorganic oxides

Abstract

A sintered friction material includes a copper alloy base and hard particles. The copper alloy base includes copper and at least one of, and preferably both, Zn and Ni within a total range of 5 to 40 wt % of the copper alloy base. The hard particles are uniformly dispersed in a matrix formed by the original composite copper alloy powder constituting the base, in a content amount within a range of 10 to 30 wt % of the friction material.

Claims

1. A sintered friction material comprising:

a copper alloy base material including copper alloy powder grains, and Cu, Zn, and Ni, wherein a content of said Zn and Ni together is within a range of 5 to 40 wt % of said base material; and

hard particles uniformly dispersed in said copper alloy powder grains of said base material, wherein a content of said hard particles is within a range of 10 to 30 wt % of said friction material.

2. The sintered friction material according to claim 1, wherein

said base material further comprises Sn within a range of 3 to 20 wt %.

3. The sintered friction material according to claim 2, wherein

said base material further comprises at least one of 1 to 5 wt % of Si, 0.1 to 5 wt % of Al and 0.5 to 3 wt % of Pb.

4. The sintered friction material according to claim 3, having a coefficient of friction not lower than 0.2 when friction sliding on a steel counterpart in oil.

5. The sintered friction material according to claim 1, wherein

said hard particles have a maximum grain diameter of at most 25 μ

m and an average grain diameter of at most 10 μ

m.

6. The sintered friction material according to claim 5, wherein

said hard particles comprise at least one intermetallic iron alloy selected from the group consisting of FeMo, FeCr, FeTi, FeW and FeB.

7. The sintered friction material according to claim 6, wherein said hard particles further include up to 5 wt % of Al₂ O₃ particles.

8. The sintered friction material according to claim 1, including uniformly dispersed pores having an average diameter of at most 30 μ

m in a pore ratio of at most 20% by volume.

9. The sintered friction material according to claim 1, further comprising a solid lubricant in a proportional amount of at most 3 wt. %.

10. The sintered friction material according to claim 9, wherein

said solid lubricant includes at least one of graphite, MoS₂, CaF₂ and BN.

11. The sintered friction material according to claim 1, further comprising a solid lubricant comprising at least one of natural flaky graphite powder and expanded graphite powder which is natural flaky graphite powder expanded in a thickness direction, in a proportional amount of at most 15 wt %.

12. The sintered friction material according to claim 1, having a tensile strength of at least 400 MPa.

13. The sintered friction material according to claim 12, wherein said tensile strength is at least 500 MPa as a result of at least one hot plastic deformation process selected from hot extrusion, hot forging, hot pressing and hot isostatic pressing after sintering.

14. A method of manufacturing the sintered friction material of claim 1, said method comprising the steps of:

preparing a mixed powder including a copper alloy powder and hard particles, wherein said copper alloy powder comprises Cu, Zn and Ni with a total content of said Zn and Ni being within a range of 5 to 40 wt % of said copper alloy powder, and wherein a content of said hard particles included in said mixed powder is within a range of 10 to 30 wt % of said mixed powder;

mixing and pulverizing said mixed powder by at least one of mechanical alloying, mechanical grinding and granulation to form a composite copper alloy powder, whereby said hard particles are pulverized to have a maximum grain diameter of at most 25 μ

m and an average grain diameter of at most 10 μ

m, and simultaneously said hard particles are uniformly dispersed in said composite copper alloy powder; and

molding and sintering said composite copper alloy powder.

15. A method of manufacturing the sintered friction material of claim 1, said method comprising the steps of:

preparing a mixed powder including metal powder group and hard particles, wherein said metal powder group comprises Cu powder, Zn powder and Ni powder with a total content of said Zn powder and said Ni powder being within a range of 5 to 40 wt % of said metal powder group, and wherein a content of said hard particles included in said mixed powder is within a range of 10 to 30 wt % of said mixed powder,

mixing and pulverizing said mixed powder by at least one of mechanical alloying, mechanical grinding and granulation to form a composite copper alloy powder, whereby said hard particles are pulverized to have a maximum grain diameter of at most 25 μ

m and an average grain diameter of at most 10 μ

m, and simultaneously said hard particles are uniformly dispersed in said composite copper alloy powder, and

molding and sintering said composite copper alloy powder.

16. The method according to claim 14, wherein

said copper alloy powder further comprises Sn within a range of 3 to 20 wt %.

17. The method according to claim 15, wherein

said metal powder group further comprises Sn powder within a range of 3 to 20 wt %.

18. The method according to claim 16, wherein

said copper alloy powder further comprises at least one of 1 to 5 wt % of Si, 0.1 to 5 wt % of Al and 0.5 to 3 wt % of Pb.

19. The method according to claim 17, wherein

said metal powder group further comprises at least one of 1 to 5 wt % of Si powder, 0.1 to 5 wt % of Al powder and 0.5 to 3 wt % of Pb powder.

20. The method according to claim 14, including carrying out said mixing, pulverizing, molding and sintering such that said sintered friction material includes uniformly dispersed pores having an average diameter of at most 30 μ

m in a pore ratio of at most 20% by volume.

21. The method according to claim 15, including carrying out said mixing, pulverizing, molding and sintering such that said sintered friction material includes uniformly dispersed pores having an average diameter of at most 30 μ

m in a pore ratio of at most 20% by volume.

22. The method according to claim 14, wherein

said hard particles include at least one intermetallic iron alloy selected from the group consisting of FeMo, FeCr, FeTi, FeW and FeB.

23. The method according to claim 15, wherein

said hard particles include at least one intermetallic iron alloy selected from the group consisting of FeMo, FeCr, FeTi, FeW and FeB.

24. The method according to claim 22, wherein

said hard particles further include Al₂ O₃ particles in a proportional amount of up to 5 wt % of said mixed powder.

25. The method according to claim 23, wherein

said hard particles further include Al₂ O₃ particles in a proportional amount of up to 5 wt % of said mixed powder.

26. The method according to claim 14, wherein

said mixed powder further includes at least one solid lubricant selected from the group consisting of graphite, MoS₂, CaF₂ and BN in a proportional amount of at most 3 wt %.

27. The method according to claim 15, wherein

said mixed powder further includes at least one solid lubricant selected from the group consisting of graphite, MoS₂, CaF₂ and BN in a proportional amount of up to 3 wt %.

28. The method according to claim 14, wherein

said mixed powder further includes a solid lubricant comprising at least one of natural flaky graphite powder and expanded graphite powder which is natural flaky graphite powder expanded in a thickness direction, in a proportional amount of at most 15 wt %.

29. The method according to claim 15, wherein

said mixed powder further includes a solid lubricant comprising at least one of natural flaky graphite powder and expanded graphite powder which is natural flaky graphite expanded in a thickness direction, in a proportional amount of at most 15 wt. %.

30. The method according to claim 14, wherein

said composite copper alloy powder comprises powder particles, each of which has a longer diameter DL and a shorter diameter DS, wherein DL is within a range of 50 to 300 μ

m and an aspect ratio DL/DS is within a range of 1 to 5.

31. The method according to claim 15, wherein

said composite copper alloy powder comprises powder particles, each of which has a longer diameter DL and a shorter diameter DS, wherein DL is within a range of 50 to 300 μ

m and an aspect ratio DL/DS is within a range of 1 to 5.

32. The method according to claim 14, wherein

said composite copper alloy powder has a fluidity sufficient for flowing 50 g of said composite copper alloy powder down through an orifice tube having a diameter of 2.5 mm within 30 seconds.

33. The method according to claim 15, wherein

said composite copper alloy powder has a fluidity sufficient for flowing to 50 g of said composite copper alloy powder down through an orifice tube having a diameter of 2.5 mm within 30 seconds.

34. The method according to claim 14, wherein

said molding step comprises molding said composite copper alloy powder so as to form a molded powder body having a true density ratio of at least 70%, and said sintering step comprises sintering said molded powder body in an atmosphere including at least one of an inert gas and a reducing gas within a temperature range of 800°

C. to 1200°

C. for 30 minutes to form a sintered body.

35. The method according to claim 15, wherein

said molding step comprises molding said composite copper alloy powder so as to form a molded powder body having a true density ratio of at least 70%, and said sintering step comprises sintering said molded powder body in an atmosphere including at least one of an inert gas and a reducing gas within a temperature range of from 800°

C. to 1200°

C. for at least 30 minutes to form a sintered body.

36. The method according to claim 34, wherein

said sintering step is carried out at a sintering temperature Ts within said temperature range, and further comprising heating said sintered body to a temperature not lower than 500°

C. and not higher than said sintering temperature Ts in a reducing gas atmosphere, and then immediately subsequently hot forging or hot extruding said sintered body, whereby a mechanical property of said sintered body is improved.

37. The method according to claim 35, wherein

said sintering step is carried out at a sintering temperature Ts within said temperature range, and further comprising heating said sintered body to a temperature not lower than 500°

C. and not higher than said sintering temperature Ts in a reducing gas atmosphere, and then immediately subsequently hot forging or hot extruding said sintered body, whereby a mechanical property of said sintered body is improved.

38. The method according to claim 36, wherein

a forging pressure in said hot forging is within a range of 5 to 8 t/cm², and an extrusion ratio of said hot extruding is at least 10.

39. The method according to claim 37, wherein

a forging pressure in said hot forging is within a range of 5 to 8 t/cm², and an extrusion ratio of said hot extruding is at least 10.