Method for converting urea to ammonia
First Claim
1. A process for converting an aqueous solution of urea to ammonia, the process comprising:
- a. heating an aqueous urea solution to a temperature of from 350°
to 650°
F. for producing urea reaction products;
b. pressurizing the urea solution to a pressure of at least 300 psig, said pressure being sufficient to maintain the reaction products in the liquid phase; and
c. while maintaining the temperature defined in part (a) and the pressure defined in part (b), contacting the urea solution for less than 10 minutes with a conversion catalyst selected from the group consisting of chromium, chromium oxide, chromium compounds, molybdenum, molybdenum oxide, and molybdenum compounds.
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Abstract
A method for reducing NOx in a combustion exhaust gas stream from a boiler. The method includes the steps of converting an aqueous solution of urea to ammonia by heating the urea solution to a temperature of 350°-650° F. The urea solution is pressurized to the pressure required to keep urea solution is pressurized to the pressure required to keep urea reaction products in the liquid phase and is contacted for a selected time with a conversion catalyst selected from the group of metals, metal oxides, or metal compounds comprising aluminum, chromium, cobalt, molybdenum, niobium, titanium, tungsten, and vanadium to provide a converted area solution. The converted area solution is injected into the combustion exhaust gas for reducing NOx.
76 Citations
18 Claims
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1. A process for converting an aqueous solution of urea to ammonia, the process comprising:
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a. heating an aqueous urea solution to a temperature of from 350°
to 650°
F. for producing urea reaction products;b. pressurizing the urea solution to a pressure of at least 300 psig, said pressure being sufficient to maintain the reaction products in the liquid phase; and c. while maintaining the temperature defined in part (a) and the pressure defined in part (b), contacting the urea solution for less than 10 minutes with a conversion catalyst selected from the group consisting of chromium, chromium oxide, chromium compounds, molybdenum, molybdenum oxide, and molybdenum compounds. - View Dependent Claims (2, 3)
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4. A process for reducing N2 O and CO byproducts normally observed when an aqueous urea injection system is used for SNCR NOx reduction in combustion exhaust gas, the process comprising:
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a. heating an aqueous urea solution to a temperature of from 350°
to 650°
F. using a heat exchanger means, for producing urea reaction products;b. pressurizing the urea solution to a pressure of at least 300 psig, said pressure being sufficient to maintain the reaction products in the liquid phase; c. while maintaining the temperature defined in part (a) and the pressure defined in part (b), contacting the urea solution for a selected time with a conversion catalyst selected from the group consisting of chromium, chromium oxide, chromium compounds, molybdenum, molybdenum oxide, and molybdenum compounds, to provide a converted urea solution containing said urea reaction products; and d. injecting the converted urea solution into said combustion exhaust gas stream at temperatures from 1600°
to 2000°
F.
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5. A process for recovering ammonia from an aqueous solution of urea, wherein more than 90% of the urea is converted to ammonia in a reaction time of less than 10 minutes, the process comprising:
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a. heating an aqueous urea solution to a temperature of from 350°
to 650°
F. using a heat exchanger means for producing urea reaction products, including ammonia;b. pressurizing the urea solution to a pressure of at least 300 psig, said pressure being sufficient to maintain the reaction products in the liquid phase; c. while maintaining the temperature defined in part (a) and the pressure defined in part (b), contacting the urea solution for less than 10 minutes with a conversion catalyst selected from the group consisting of chromium, chromium oxide, chromium compounds, molybdenum, molybdenum oxide, and molybdenum compounds, to thereby convert urea to ammonia; and d. recovering the ammonia. - View Dependent Claims (6, 7)
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8. A process for reducing NOx in a combustion exhaust gas stream from a boiler, the process comprising the steps of:
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a. in a heat exchanger, heating an aqueous urea solution to a temperature of from 350°
to 650°
F.;b. pressurizing the urea solution to the pressure required to keep urea reaction products in the liquid phase; c. contacting the urea solution for a selected time with a conversion catalyst selected from the group consisting of chromium, chromium oxide, chromium compounds, molybdenum, molybdenum oxide, and molybdenum compounds, to provide a converted urea solution; and d. injecting the converted urea solution into the boiler combustion exhaust gas. - View Dependent Claims (9)
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10. A process for reducing NOx in a combustion exhaust gas stream from a boiler, the process comprising the steps of:
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a. heating an aqueous urea solution to a temperature of from 250°
C. to 650°
F.;b. pressurizing the urea solution to a pressure required to keep urea reaction products in the liquid phase; c. contacting the urea solution for a selected time with a conversion catalyst selected from the group consisting of chromium, chromium oxide, chromium compounds, molybdenum, molybdenum oxide, and molybdenum compounds, to convert urea to ammonia; and d. injecting the ammonia into the boiler combustion exhaust gas. - View Dependent Claims (11, 12)
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13. A process for converting an aqueous solution of urea to ammonia, the process comprising:
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a. heating an aqueous urea solution in a heat exchanger comprising nonretractable heat exchanger tubes located in a hot flue gas or combustion exhaust gas stream to a temperature of from 350°
F. to 650°
F. in order to produce urea reaction products, including ammonia;b. pressurizing the urea solution to a pressure of at least 300 psig, said pressure being sufficient to maintain such urea reaction products in the liquid phase; and c. while maintaining the temperature defined in part (a) and the pressure defined in part (b), contacting the urea solution for less than 10 minutes with a conversion catalyst selected from the group consisting of chromium, chromium oxide, chromium compounds, molybdenum, molybdenum oxide, and molybdenum compounds, thereby producing said urea reaction products.
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14. A process for converting an aqueous solution of urea to ammonia, the process comprising:
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a. heating an aqueous urea solution in a heat exchanger to a temperature of from 350°
F. to 650°
F. in order to produce urea reaction products, including ammonia, wherein such heating is provided by steam which has been heated in a hot flue gas stream;b. pressurizing the urea solution to a pressure of at least 300 psig, said pressure being sufficient to maintain such urea reaction products in the liquid phase; and c. while maintaining the temperature defined in part (a) and the pressure defined in part (b), contacting the urea solution for less than 10 minutes with a conversion catalyst selected from the group consisting of chromium, chromium oxide, chromium compounds, molybdenum, molybdenum oxide, and molybdenum compounds, thereby producing said urea reaction products.
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15. A process for converting an aqueous solution of urea to ammonia, the process comprising:
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(a) heating an aqueous urea solution to a temperature of from 350°
to 600°
F. for producing urea reaction products;(b) pressurizing the urea solution to a pressure of at least 300 psig; and (c) while maintaining the temperature defined in part (a) and the pressure defined in part (b), contacting the urea solution for less than 10 minutes with a conversion catalyst selected from the group consisting of chromium, chromium oxide, chromium compounds, molybdenum, molybdenum oxide, and molybdenum compounds. - View Dependent Claims (16, 17)
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18. A process for converting an aqueous solution of urea to ammonia, the process comprising:
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(a) heating an aqueous urea solution to a temperature of from 350°
to 650°
F. for producing urea reaction products;(b) pressurizing the urea solution to a pressure of at least 300 psig, wherein said pressure is sufficient to maintain the reaction products in the liquid phase; and (c) while maintaining the temperature defined in part (a) and the pressure defined in part (b), contacting the urea solution for less than 10 minutes with a conversion catalyst selected from the group consisting of aluminum, aluminum oxide, aluminum compounds, chromium, chromium oxide, chromium compounds, cobalt, cobalt oxide, cobalt compounds, molybdenum, molybdenum oxide, molybdenum compounds, niobium, niobium oxide, niobium compounds, titanium, titanium oxide, titanium compounds, tungsten, tungsten oxide, tungsten compounds, vanadium, vanadium oxide, and vanadium compounds.
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Specification