Method for removing carbon dioxide from exhaust gases

• US 5,832,712 A
• Filed: 10/11/1996
• Issued: 11/10/1998
• Est. Priority Date: 02/15/1994
• Status: Expired due to Term

• Current Assignee: Kvaerner ASA (Kvaerner Oilfield Products Inc)
• Original Assignee: Kvaerner ASA (Kvaerner Oilfield Products Inc)
• Inventors: R.o slashed.nning, Svein O., Glittum, Geir, Bolland, Olav, Bjerve, Yngvil, Falk-Pedersen, Olav
• Primary Examiner(s): FREAY, CHARLES GRANT
• Application Number:
  US08/693,170
• Time in Patent Office: 760 Days
• Field of Search: 60/39.02, 60/39.04, 60/39.182, 60/39.5, 60/39.52
• US Class Current: 60/783
• CPC Class Codes: B01D 53/1475 Removing carbon dioxide
• CPC Class Codes: B01D 53/229 Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

A method for removing and preventing emissions into the atmosphere of carbon dioxide (CO₂) from exhaust gases from gas turbines for the production of oil and gas, comprising the following steps: (a) natural gas and air are introduced into a gas turbine in which natural gas is converted to mechanical energy; (b) the exhaust gas from the gas turbine is passed through a heat recovery unit for recovery of the heat content in the exhaust gas; (c) after emitting heat in the recovery unit whereby the temperature of the exhaust gas has been reduced to 20°-70° C., the exhaust gas is passed to an absorption column containing an absorption liquid, where the carbon dioxide is absorbed in the said liquid, and the thereby purified exhaust gas, essentially free of carbon dioxide, is vented to the atmosphere; (d) the absorption liquid which contains CO₂ is passed to a stripping column where the CO₂ is removed from the absorption liquid heated to a temperature of 120°-150° C.; (e) the thereby regenerated absorption liquid which is essentially free of CO₂ is recycled to the absorption column and the separated CO₂ gas is passed to a compression stage for compression and utilization or disposal; wherein approximately 40% of the exhaust gas is recycled to the compressor air inlet for said gas turbine before the exhaust gas is passed to the absorption stage (c).

Claims

1. A method for removing and preventing emissions into the atmosphere of carbon dioxide (CO₂) from exhaust gases from gas turbines, for the production of oil and gas, comprising the following steps:

(a) introducing natural gas and air into a gas turbine in which natural gas is converted to mechanical energy;

(b) passing the exhaust gas from the gas turbine through a heat recovery unit for recovery of the heat content in the exhaust gas;

(c) after emitting heat in the heat recovery unit whereby the temperature of the exhaust gas has been reduced to 20°

-70°

C., passing the exhaust gas to an absorption column containing an absorption liquid, where the carbon dioxide is absorbed in said liquid, and the thereby purified exhaust gas which is essentially free of carbon dioxide, is vented to the atmosphere;

(d) passing the absorption liquid which contains CO₂ to a stripping column where the CO₂ is removed from the absorption liquid by heating to a temperature of 120°

-150°

C., thereby regenerating the absorption liquid; and

(e) recycling the thereby regenerated absorption liquid which is essentially free of CO₂ to the absorption column and passing the separated CO₂ gas to a compression stage for compression and utilization or disposal;

wherein approximately 40% of the exhaust gas is recycled to the compressor stage for said gas turbine before the exhaust gas is passed to the absorption stage (c).

2. The method according to claim 1, wherein the heat recovery unit used is an exhaust heat boiler.

3. The method according to claim 1, further comprising employing a device as a gas absorption column said device comprising gas absorption membranes suitable for separating CO₂ gas from exhaust gases.

4. The method according to claim 1, wherein steam from the heat recovery plant is used to heat the stripping column and the steam is also used for the production of electrical energy via a high pressure steam turbine.

5. A method for removing and preventing emissions into the atmosphere of carbon dioxide (CO₂) from exhaust gases from gas turbines, for the production of oil and gas, comprising the following steps:

(a) introducing natural gas and air into a gas turbine in which natural gas is converted to mechanical energy;

(b) passing the exhaust gas from the gas turbine through a heat recovery unit for recovery of the heat content in the exhaust gas;

(c) after emitting heat in the heat recovery unit whereby the temperature of the exhaust gas has been reduced to 20°

-70°

C., passing the exhaust gas to an absorption column containing an absorption liquid, where the carbon dioxide is absorbed in said liquid, and the thereby purified exhaust gas which is essentially free of carbon dioxide, is vented to the atmosphere;

(d) passing the absorption liquid which contains CO₂ to a stripping column where the CO₂ is removed from the absorption liquid by heating to a temperature of 120°

-150°

C., thereby regenerating the absorption liquid; and

(e) recycling the thereby regenerated absorption liquid which is essentially free of CO₂ to the absorption column and passing the separated CO₂ gas to a compression stage for compression and utilization or disposal;

wherein approximately 40% of the exhaust gas is recycled to the compressor stage for said gas turbine before the exhaust gas is passed to the absorption stage (c) and wherein steam from the heat recovery plant is used to heat the stripping column and the steam is also used for the production of electrical energy via a high pressure steam turbine.