Electrophotographic photoreceptor containing uniform and nonuniform charge transporting layers

• US 5,834,146 A
• Filed: 07/23/1996
• Issued: 11/10/1998
• Est. Priority Date: 07/25/1995
• Status: Expired due to Term

• Current Assignee: Fuji Xerox Company Limited (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Xerox Company Limited (Fujifilm Holdings Corporation)
• Inventors: Igarashi, Ryosaku, Hoshizaki, Taketoshi, Sakaguchi, Yasuo, Yamaguchi, Yasuhiro
• Primary Examiner(s): Rodee, Christopher D.
• Application Number:
  US08/681,370
• Time in Patent Office: 840 Days
• Field of Search: 430/59, 430/58
• US Class Current: 430/58.5
• CPC Class Codes: G03G 5/047 characterised by the charge-generation layers or charge transport layers G03G5/0433 and G03G5/0436 take precedence
• CPC Class Codes: G03G 5/0764 triarylamine
• CPC Class Codes: G03G 5/0766 benzidine

Abstract

An electrophotographic photoreceptor comprising an electrically conductive substrate having thereon a charge-generating layer and a charge-transporting layer, wherein the charge-transporting layer comprises: a nonuniform charge-transporting layer comprising an electrically inactive matrix and a charge-transporting domain dispersed in the matrix; and the uniform charge-transporting layer comprising a charge-transporting matrix.

Claims

1. An electrophotographic photoreceptor comprising an electrically conductive substrate having thereon a charge-generating layer and a charge-transporting layer, wherein said charge-transporting layer comprises:

a nonuniform charge-transporting layer comprising an electrically inactive matrix and a charge-transporting domain dispersed in the matrix; and

a uniform charge-transporting layer comprising a charge-transporting matrix,

wherein the charge-transporting domain in the nonuniform charge-transporting layer has an average grain diameter of from 0.005 to 0.5 μ

m.

2. The electrophotographic photoreceptor according to claim 1, wherein the exposure amount of said photoreceptor required for 50% potential decay is less than 5 times that required for 10% potential decay.

3. The electrophotographic photoreceptor according to claim 1, wherein the exposure amount of the photoreceptor required for 50% potential decay is less than 3 times that required for 10% potential decay.

4. The electrophotographic photoreceptor according to claim 1, wherein said charge-generating layer and said nonuniform charge-transporting layer are adjacent to each other.

5. The electrophotographic photoreceptor according to claim 1, wherein said charge-generating layer, said nonuniform charge-transporting layer and said uniform charge-transporting layer are laminated on said electrically conductive substrate in this order.

6. The electrophotographic photoreceptor according to claim 1, wherein said uniform charge-transporting layer comprises a charge-transporting polymer.

7. The electrophotographic photoreceptor according to claim 6, wherein said charge-transporting polymer comprises at least one structure represented by the following general formula (1) as a repeating unit:

##STR8## wherein R₁ to R₆ each independently represent a hydrogen atom, an alkyl group, an alkoxy group, a substituted amino group, a halogen atom or a substituted or unsubstituted aryl group;

X represents a divalent hydrocarbon or hetero atom-containing divalent hydrocarbon group containing a substituted or unsubstituted aromatic group;

T represents a divalent hydrocarbon or hetero atom-containing divalent hydrocarbon group having from 1 to 20 carbon atoms and containing or not containing a branched-structure and a ringstructure; and

k and l each represent an integer of 0 or 1.

8. The electrophotographic photoreceptor according to claim 6, wherein the content of a charge-transporting compound having a molecular weight of not more than 1,000 in said uniform charge-transporting layer is less than 5% by weight.

9. The electrophotographic photoreceptor according to claims 1, wherein said nonuniform charge-transporting layer comprises a binder resin having an electrical resistivity of not less than 10¹³ Ω

·

cm and a fine particulate charge-transporting material dispersed in said binder resin in a volume proportion of from 20 to 40%.

10. The electrophotographic photoreceptor according to claim 9, wherein said fine particulate charge-transporting material comprises hexagonal selenium.

11. The electrophotographic photoreceptor according to claim 1, wherein said charge-generating layer comprises a phthalocyanine compound as a charge-generating material.

12. The electrophotographic photoreceptor according to claim 11, wherein said phthalocyanine compound is selected from the group consisting of dichlorotin phthalocyanine, titanyl phthalocyanine, chlorogallium phthalocyanine, hydroxygallium phthalocyanine, 1,2-di(oxogallium phthalocyanyl)ethane, metal-free phthalocyanine and vanadyl phthalocyanine.

13. The electrophotographic photoreceptor according to claim 11, wherein said phthalocyanine compound is dichlorotin phthalocyanine, and said charge-transporting layer is hole-transporting, said charge-generating layer and said hole charge-transporting layer are laminated on said electrically conductive substrate in this order.

14. The electrophotographic photoreceptor according to claim 1, wherein said charge-generating layer comprises hexagonal selenium as a charge-generating material.

15. The electrophotographic photoreceptor according to claim 1, further comprising an interlayer interposed between said charge-generating layer and said nonuniform charge-transporting layer, said interlayer comprising a second charge-transporting matrix.

16. The electrophotographic photoreceptor according to claim 1, wherein said charge-transporting domains in said nonuniform charge-transporting layer contact with each other to form a contorted charge-transporting passage.

17. The electrophotographic photoreceptor according to claim 1, further comprising an undercoat layer and an interlayer, wherein said undercoat layer, said charge generating layer, said interlayer, said nonuniform transporting layer and said uniform charge-transporting layer are laminated in this order or a reverse order from a support.

18. An electrophotographic photoreceptor comprising an electrically conductive substrate having thereon a charge-generating layer and a charge-transporting layer, wherein said charge-transporting layer comprises:

a nonuniform charge-transporting layer comprising an electrically inactive matrix and a charge-transporting domain dispersed in the matrix; and

a uniform charge-transporting layer comprising a charge-transporting matrix,

wherein said uniform charge-transporting layer, said nonuniform charge-transporting layer and said charge-generating layer are laminated on said electrically conductive substrate in this order.

19. An electrophotographic photoreceptor comprising an electrically conductive substrate having thereon a charge-generating layer and a charge-transporting layer, wherein said charge-transporting layer comprises:

a nonuniform charge-transporting layer comprising an electrically inactive matrix and a charge-transporting domain dispersed in the matrix; and

a uniform charge-transportiny layer comprising a charge-transporting matrix,

wherein said nonuniform charge-transporting layer comprises block or graft copolymer comprising a charge-transporting block and an electrically inactive insulating block, and said block or graft copolymer has undergone microphase separation to have a sea-island structure having a sea portion formed by said insulating block and island portions formed by said charge-transporting block.