Joining by brazing of ceramic materials containing silicon carbide

• US 5,836,505 A
• Filed: 05/07/1997
• Issued: 11/17/1998
• Est. Priority Date: 05/07/1996
• Status: Expired due to Term

• Current Assignee: Commissariat a L'Energie Atomique (AES Corporation)
• Original Assignee: Commissariat a L'Energie Atomique (AES Corporation)
• Inventors: Chaumat, Gilles, Coing-Boyat, Gisele
• Primary Examiner(s): Heinrich, Samuel M.
• Application Number:
  US08/852,375
• Time in Patent Office: 559 Days
• Field of Search: 228/121, 228/122.1, 228/124.1, 228/232, 228/233.2, 228/248.1, 420/462, 420/578, 420/590
• US Class Current: 228/121
• CPC Class Codes: C04B 2235/5436 micrometer sized, i.e. from 1 to 100 micron
• CPC Class Codes: C04B 2235/6581 Total pressure below 1 atmosphere, e.g. vacuum
• CPC Class Codes: C04B 2237/125 based on noble metals, e.g. silver
• CPC Class Codes: C04B 2237/126 wherein the active component for bonding is not the largest fraction of the interlayer
• CPC Class Codes: C04B 2237/128 The active component for bonding being silicon
• CPC Class Codes: C04B 2237/16 Silicon interlayers
• CPC Class Codes: C04B 2237/365 Silicon carbide
• CPC Class Codes: C04B 2237/52 Pre-treatment of the joining surfaces, e.g. cleaning, machining
• CPC Class Codes: C04B 2237/525 by heating
• CPC Class Codes: C04B 2237/55 Pre-treatments of a coated or not coated substrate other than oxidation treatment in order to form an active joining layer
• CPC Class Codes: C04B 37/006 consisting of metals or metal salts

Abstract

The present invention relates to joining by brazing ceramic elements comprising SiC. The purpose of the invention is to provide a braze alloy which gives a brazed joint resistant to fluorine effluents and having controlled reactivity with SiC. This purpose is achieved using a braze alloy comprising Si and rhodium.

Claims

1. Joining of ceramic elements comprising SiC, by means of a brazed joint, characterized in that the brazed joint is formed of a braze alloy of Si and Rh, resistant to fluorine at temperatures of over 50°

C.

2. Joining in accordance with claim 1, characterised in that the alloy is a Si--Rh alloy, in which Si represents 40 to 60 atomic % of said alloy.

3. Joining in accordance with claim 2, characterised in that Si represents 50 atomic % of said alloy.

4. Method for joining ceramic elements comprising SiC, characterized in that it comprises the stages of positioning the braze alloy of Si and Rh between the surfaces of the ceramic elements to be joined, and heating to a brazing temperature of 1450°

C. to 1600°

C. to obtain brazing.

5. Method for manufacturing a joint in accordance with claim 4, characterized in that the braze alloy is placed in position by surface enduction by means of a suspension of braze alloy particles in a volatilizable binding agent at a temperature of less than 10000°

C.

6. Method in accordance with claim 5, characterized in that the suspension is prepared by fusion of silicon and rhodium in such manner as to obtain an alloy, cooling the alloy to obtain a solid braze alloy, grinding the solid braze alloy into powder form and mixing the powder with the binding agent.

7. Method in accordance with claim 6, characterized in that fusion is carried out under a secondary vacuum at a temperature of between 450°

and 1600°

C.

8. Method in accordance with claim 7, characterized in that the braze powder has a grain diameter of 0.05 to 0.1 mm.

9. Method in accordance with claim 4, characterized in that the braze alloy is a Si--Rh alloy in which Si represents 40 to 60 atomic %.

10. Method of manufacturing a joint in accordance with claim 4, characterized in that heating is carried out following a cycle comprising a first heating stage at a temperature of 200°

to 400°

C., and a second heating stage at brazing temperature.

11. Method of manufacturing a joint in accordance with claim 9, characterized in that heating is carried out following a cycle comprising a first heating stage at a temperature of 200°

to 400°

C., and a second heating stage at brazing temperature.

12. Method in accordance with claim 10, characterized in that the brazing temperature is 1450°

to 1600°

C.

13. Method in accordance with claim 11, characterized in that the brazing temperature is 1450°

to 1600°

C.