Polyethylene-2,6-naphthalene dicarboxylate resin and preform and bottle molded thereof

• US 5,837,800 A
• Filed: 01/30/1998
• Issued: 11/17/1998
• Est. Priority Date: 02/03/1997
• Status: Expired due to Term

• Current Assignee: Teijin Limited
• Original Assignee: Teijin Limited
• Inventors: Suzuki, Minoru, Sato, Kimihiko, Umeda, Masami
• Primary Examiner(s): BOYKIN, TERRESSA M
• Application Number:
  US09/016,280
• Time in Patent Office: 291 Days
• Field of Search: 528/190, 528/193
• US Class Current: 528/193
• CPC Class Codes: C08G 63/189 containing a naphthalene ring
• CPC Class Codes: C08G 63/82 characterised by the catalyst used
• CPC Class Codes: C08G 63/863 Germanium or compounds thereof

Abstract

A polyethylene-2,6-naphthalene dicarboxylate resin for molding a bottle, which comprises 2,6-naphthalenedicarboxylic acid as a main acid component and ethylene glycol as a main glycol component and contains a germanium compound as a polycondensation catalyst, and has an intrinsic viscosity of 0.55 to 0.75 dl/g, a terminal carboxyl group content of 32 eq/ton or less, an acetaldehyde content of 8 ppm or less and a diethylene glycol component content of 0.8 to 3.0 wt %.

Claims

1. A polyethylene-2,6-naphthalene dicarboxylate resin for molding a bottle, which comprises 2,6-naphthalenedicarboxylic acid as a main acid component and ethylene glycol as a main glycol component and contains a germanium compound as a polycondensation catalyst, and has an intrinsic viscosity of 0.55 to 0.75 dl/g, a terminal carboxyl group content of 32 eq/ton or less, an acetaldehyde content of 8 ppm or less and a diethylene glycol component content of 0.8 to 3.0 wt %.

2. The polyethylene-2,6-naphthalene dicarboxylate resin of claim 1, which has an intrinsic viscosity of 0.58 to 0.73 dl/g.

3. The polyethylene-2,6-naphthalene dicarboxylate resin of claim 1, which has a terminal carboxyl group content of 30 eq/ton or less.

4. The polyethylene-2,6-naphthalene dicarboxylate resin of claim 1, which has an acetaldehyde content of 6 ppm or less.

5. The polyethylene-2,6-naphthalene dicarboxylate resin of claim 1, which has a diethylene glycol component content of 1.0 to 2.8 wt %.

6. The polyethylene-2,6-naphthalene dicarboxylate resin of claim 1, which has a b value in the range of +0.6 to -6.0.

7. The polyethylene-2,6-naphthalene dicarboxylate resin of claim 1, which further contains a cobalt compound, a magnesium compound, a calcium compound and a phosphorus compound in amounts that satisfy the following expressions:

space="preserve" listing-type="equation">0.12 ≦

Co≦

1.2 (1)

space="preserve" listing-type="equation">2.0≦

Mg+Ca≦

6.0 (2)

space="preserve" listing-type="equation">1.3≦

Mg/Ca≦

6.0 (3)

space="preserve" listing-type="equation">1.0≦

P/(Co+Mg+Ca)≦

1.5 (4)

space="preserve" listing-type="equation">1.0≦

Ge≦

3.0 (5)

wherein Co, Mg, Ca, P and Ge indicate the number of moles of cobalt atoms in the cobalt compound, the number of moles of magnesium atoms in the magnesium compound, the number of moles of calcium atoms in the calcium compound, the number of moles of phosphorus atoms in the phosphorus compound and the number of moles of germanium atoms in the germanium compound, based on 1 ton of acid components constituting the polymer, respectively.

8. The polyethylene-2,6-naphthalene dicarboxylate resin of claim 7, wherein the amount of the cobalt compound satisfies the following expression:

space="preserve" listing-type="equation">0.41≦

Co≦

1.2 (1)'"'"'

wherein Co is the same as defined in the above expression (1).

9. The polyethylene-2,6-naphthalene dicarboxylate resin of claim 8, which has an acetaldehyde content of 5 ppm or less.

10. The polyethylene-2,6-naphthalene dicarboxylate resin of claim 7, which has a b value in the range of +0.6 to -6.0.

11. A preform for a bottle, which is formed from the polyethylene-2,6-naphthalene dicarboxylate resin of claim 1.

12. A bottle formed from the polyethylene-2,6-naphthalene dicarboxylate resin of claim 1.