Shape memory alloy treatment

• US 5,843,244 A
• Filed: 06/13/1996
• Issued: 12/01/1998
• Est. Priority Date: 06/13/1996
• Status: Expired due to Term

• Current Assignee: Cordis Corporation (Cardinal Health, Inc.)
• Original Assignee: Nitinol Devices and Components
• Inventors: Pelton, Alan, Duerig, Thomas
• Primary Examiner(s): WYSZOMIERSKI, GEORGE P
• Application Number:
  US08/661,305
• Time in Patent Office: 901 Days
• Field of Search: 148/402, 148/563, 148/676, 148/670
• US Class Current: 148/563
• CPC Class Codes: A61F 2/82 Devices providing patency to, or preventing collapsing of, tubular structures of the body, e.g. stents stent-grafts for tubular structures of the body other than blood vessels A61F2/04; stent-grafts for blood vessels A61F2/07; instruments specially adapted for placement or removal of stents or stent-grafts A61F2/95; for closing wounds, or holding wounds closed A61B17/04 - A61B17/115; dilators A61M29/00
• CPC Class Codes: C22F 1/006 Resulting in heat recoverable alloys with a memory effect

Abstract

A method of treating a component formed from a Ni--Ti based shape memory alloy, so that the component exhibits superelasticity, comprises cold working the component, annealing the alloy while the component is restrained in the configuration resulting from the cold working step, and exposing the component to a temperature that is less than the solvus temperature of the alloy and greater than the temperature to which it is exposed in the annealing step to cause the A_f temperature to be reduced.

Claims

1. A method of treating a component formed from a Ni--Ti based shape memory alloy so that the component exhibits superelasticity and to impart a desired shape to the component and thereafter lower the component'"'"'s Af, which comprises:

(a) cold working the component, the component comprising greater than 50.5 at. % nickel;

(b) restraining the alloy to a desired shape and heat treating the alloy at a temperature that is less than solvus temperature of the alloy, to cause dislocations in the alloy resulting from the cold working step to combine; and

(c) after heat treating the component in the restrained desired shape in step (b), removing the restraint and thereafter heat treating the component at a temperature that is greater than the temperature to which it is exposed in step (b) and less than the solvus temperature of the alloy, causing the component to retain the desired shape and causing the Af temperature to be reduced so that said component is superelastic at body temperature.

2. A method as claimed in claim 1, further including the step of annealing the component prior to step (a) and wherein the amount of cold work imparted to the component in step (a) is greater than about 10%.

3. A method as claimed in claim 1, in which the component is exposed to elevated temperature in step (c) for not more than about 10 minutes.

4. A method as claimed in claim 3, in which the component is exposed to elevated temperature in step (c) for not more than about 5 minutes.

5. A method as claimed in claim 1, in which the component is exposed to elevated temperature in step (c) for at least about 30 seconds.

6. A method as claimed in claim 1, in which step (b) is carried out more than once but before step (c) is carried out.

7. A method as claimed in claim 1, in which the alloy is a thermally unstable alloy.

8. A method as claimed in claim 1, in which the heat treatment of step (c) is performed at a temperature above 510°

C.