Sealant compositions and sealed electrical connectors

• US 5,844,021 A
• Filed: 05/11/1995
• Issued: 12/01/1998
• Est. Priority Date: 08/23/1991
• Status: Expired due to Term

• Current Assignee: The Whitaker LLC (TE Connectivity Ltd. (United Kingdom))
• Original Assignee: The Whitaker Corporation (Meggitt PLC)
• Inventors: Koblitz, Francis Frederick, Mellinger, Ricky Charles, Lynch, Thomas John, Pawlikowski, Gregory T.
• Primary Examiner(s): MERRIAM, ANDREW EDWIN
• Application Number:
  US08/438,835
• Time in Patent Office: 1,300 Days
• Field of Search: 439/276, 439/936, 523/173, 524/505, 524/507, 524/476, 252/570, 525/89, 525/903, 525/95
• US Class Current: 523/173
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 53/005 Modified block copolymers
• CPC Class Codes: C08L 53/02 of vinyl-aromatic monomers and conjugated dienes
• CPC Class Codes: C08L 53/025 modified
• CPC Class Codes: C09K 2200/0247 Silica
• CPC Class Codes: C09K 2200/0405 Hydrocarbons
• CPC Class Codes: C09K 2200/06 Macromolecular organic compounds, e.g. prepolymers
• CPC Class Codes: C09K 2200/0617 Polyalkenes
• CPC Class Codes: C09K 2200/062 Polyethylene
• CPC Class Codes: C09K 2200/0632 Polystyrenes
• CPC Class Codes: C09K 2200/0642 Copolymers containing at least three different monomers
• CPC Class Codes: C09K 3/10 Materials in mouldable or extrudable form for sealing or packing joints or covers filling pastes C09D5/34
• CPC Class Codes: H01B 7/282 Preventing penetration of fluid , e.g. water or humidity, into conductor or cable
• CPC Class Codes: H01B 7/285 by completely or partially filling interstices in the cable
• CPC Class Codes: H01B 7/292 using material resistant to heat
• CPC Class Codes: H01R 13/5216 characterised by the sealing material, e.g. gels or resins
• CPC Class Codes: H01R 4/2495 Insulation penetration combined with permanent deformation of the contact member, e.g. crimping
• CPC Class Codes: H01R 4/70 Insulation of connections end caps H01R4/22
• CPC Class Codes: Y10S 439/936 : Potting material or coating, e.g. grease, insulative coating, sealant or, adhesive
• CPC Class Codes: Y10S 525/903 : Interpenetrating network

Abstract

Disclosed are sealant compositions and electrical connectors having excellent low temperature repairability and outstanding sealing ability at both high and low temperatures. The preferred connectors contain a sealant composition comprising an elastomeric thermoplastic polymer and an extender for said polymer, said extender constituting a major proportion by weight of said sealant composition and said polymer constituting a minor proportion by weight of said sealant composition, wherein said composition preferably has a low-temperature wire insertability of at least about 80 mm. Furthermore, the preferred compositions are both slump and spew resistant over the operating temperature range of the connector.

Claims

1. A moisture and temperature resistant electrical connector for sealingly connecting transmission means comprising:

(a) a connector body comprising terminal means for accepting and electrically connecting with said transmission means; and

(b) a sealing and lubricating composition disposed along or adjacent to said terminal means for providing low-temperature sealing and wire-insertability to the connector, said composition comprising an elastomeric thermoplastic polymer, said elastomeric thermoplastic polymer being elastomeric at temperatures of from about -40°

C. to at least about +150°

C. and flowable yet thermally stable at temperatures of from about +200°

C., said elastomeric thermoplastic polymer comprising at least one elastomeric block and one non-elastomeric block, and said elastomeric thermoplastic polymer comprising a composite of a first elastomeric thermoplastic polymer and a second elastomeric thermoplastic polymer, the melt viscosity of said second elastomeric thermoplastic polymer being at least about 50 times greater than the melt viscosity of said first elastomeric thermoplastic polymer, and an extender for said polymer, said extender comprising a major proportion by weight of said composition and said extender comprising an extender having a secondary swelling percentage at about 60°

C. of at least about 700% in a poly(styrene-ethylene-butylene-styrene) tri-block copolymer, wherein said composition has a slump resistance at about 80°

C. of less than about 0.5 inches, a low-temperature cohesive strength at about -22°

C. of no greater than about 0.01 g and a low-temperature wire insertability at about -22°

C. of no less than about 80×

0.1 mm.

2. The connector of claim 1 wherein the weight ratio of said extender to said polymer is in the range of about 99:

0.5 to 85;

15.

3. The connector of claim 1 wherein said extender comprises at least about 35% by weight of extender having a secondary swelling percentage at about 60°

C. of at least about 900% in a ploy (styrene-ethylene-butylene-styrene) tri-block copolymer.

4. The connector of claim 3 wherein said extender comprises a mixture of extenders, at least about 50% by weight said extenders having a secondary swelling percentage at 60°

C. of at least about 1200% in a poly (styrene-ethylene-butylene-styrene) tri-block copolymer.

5. The connector of claim 1 wherein said extender comprises a C2-C12 polyolefin.

6. The connector of claim 2 wherein said extender comprises extender selected from the group consisting of polybutadiene, polybutene, polybutylene, hydrocarbon resins, atactic polypropylene, branched polyethylene, ethylene-propylene copolymers and low molecular weight styrenic polymers and combinations and copolymers of these.

7. The connector of claim 1 wherein said extender comprises extender selected from the group consisting of naphthenic oils, aliphatic oils and solvents, white oils, terpenoid hydrocarbons and combinations of these.

8. The connector of claim 1 wherein said extender consists essentially of synthetic oil having a molecular weight of from about 250 to about 450 and comprising from about 40% to about 60% of paraffinic carbon atoms, from about 35% to about 60% naphthenic carbon atoms, and about 1% to about 10% aromatic carbon atoms, said aromatic carbon atoms not including carbon atoms which are members of naphthenic rings.

9. The connector of claim 1 wherein said elastomeric, thermoplastic polymer comprises primary polymer and secondary polymer, said secondary polymer having a melt viscosity of at least about 10,000 cps, the melt viscosity being measured at about 150°

C.

10. The connector of claim 9 wherein the primary polymer comprises di-block copolymer.

11. The connector of claim 10 wherein said di-block copolymer comprises a block of non-elastomeric polymer connected to a block of elastomeric polymer, said non-elastomeric polymer block being selected from the group consisting of poly(alkenyl arenes), polyurethanes and combinations of these, and said elastomeric polymer block being selected from the group consisting of non-aromatic polyolefins, polyesters, polyethers and combinations of these.

12. The connector of claim 10 wherein said secondary polymer block comprises tri-block copolymer.

13. The connector of claim 12 wherein said tri-block copolymer comprises a block of non-elastomeric polymer connected to a block of elastomeric polymer, said block of elastomeric polymer being connected to another block of non-elastomeric polymer, said non-elastomeric polymer block being selected from the group consisting of poly(alkenyl arenes), polyurethanes and combinations of these, and said elastomeric polymer block being selected from the group consisting of non-aromatic polyolefins, polyesters, polyethers and combinations of these.

14. A moisture and temperature resistant electrical connector for sealingly connecting transmission means comprising:

(a) a connector body; and

(b) a sealant composition disposed in said connector body, said sealant composition comprising;

(i) a minor proportion by weight of an elastomeric thermoplastic polymer, said elastomeric thermoplastic polymer being elastomeric at ambient temperatures and flowable yet thermally stable at elevated temperatures, said elastomeric thermoplastic polymer comprising at least one elastomeric block and one non-elastomeric block, and said elastomeric thermoplastic polymer comprising a composite of a first elastomeric thermoplastic polymer and a second elastomeric thermoplastic polymer, the melt viscosity of said second elastomeric thermoplastic polymer being at least about 50 times greater than the melt viscosity of said first elastomeric thermoplastic polymer; and

(ii) a major proportion by weight of an extender, at least about 35% by weight of said extender having a secondary swelling percentage at about 60°

C. of at least about 700% in a poly (styrene-ethylene-butylene-styrene) tri-block copolymer.

15. The connector of claim 14 wherein said connector body comprises a container having access means for allowing entry of said transmission means into said connector body and a terminal means for accepting and electrically connecting with said transmission means.

16. The connector of claim 14 wherein the weight ratio of said first polymer to said second polymer is from about 4:

1 to about 20;

1.

17. The connector of claim 14 wherein said sealant composition has a flow of at least about 2 gram per min. at about 160°

C., a slump resistance of less than about 0.5 in. at about 80°

C., and an elastic memory of at least about 200% at temperatures of from about -22°

C. to about +80°

C.

18. The connector of claim 17 wherein the weight ratio of said extender to said polymer is in the range of about 99:

0.5 to 85;

15.

19. The connector of claim 14 wherein said elastomeric thermoplastic organic polymer comprises a block copolymer blend.

20. The connector of claim 19 wherein said block copolymer comprises a di-block copolymer and a tri-block copolymer.

21. The connector of claim 14 wherein:

(a) said extender consists essentially of extender having a swelling percentage at 60°

C. of at least about 1200% in a poly (styrene-ethylene-butylene-styrene) tri-block copolymer; and

(b) the weight ratio of said first polymer to said second polymer is 4;

1.

22. The connector of claim 21 wherein said extender consists essentially of synthetic oil having a molecular weight of about 400 and comprises from about 50% to about 60% of paraffinic carbon atoms, from about 40% to about 50% naphthenic carbon atoms, and about 1% aromatic carbon atoms, said aromatic carbon atoms not including carbon atoms which are members of naphthenic rings.