Process for generating burnable gas

• US 5,849,050 A
• Filed: 08/14/1996
• Issued: 12/15/1998
• Est. Priority Date: 02/15/1994
• Status: Expired due to Term

• Current Assignee: Linde AG (Linde Plc)
• Original Assignee: CRG Kohlenstoffrecycling GmbH
• Inventors: Wolf, Bodo
• Primary Examiner(s): Marschel, Ardin H.
• Assistant Examiner(s): Riley, Jezia
• Application Number:
  US08/693,167
• Time in Patent Office: 853 Days
• Field of Search: 48/73, 48/111, 48/197 R, 48/202, 48/209, 60/39.12
• US Class Current: 48/197.00R
• CPC Class Codes: C10J 2300/0906 Physical processes, e.g. shredding, comminuting, chopping, sorting
• CPC Class Codes: C10J 2300/0959 Oxygen
• CPC Class Codes: C10J 2300/1628 Ash post-treatment
• CPC Class Codes: C10J 3/66 by introducing them into the gasification zone

Abstract

A process is disclosed for generating burnable gas by gasifying water- and ballast-containing organic materials, be it coal or garbage. The drying, low temperature carbonization and gasification steps are carried out separately. The heat taken form cooled gasified gas is supplied to the endothermic drying low temperature in low temperature carbonation stages. The low temperature carbonization gas is burned in a melting chamber furnace with air and/or oxygen or oxygen-rich flue gas and the liquid slag is evacuated, whereas the low temperature carbonization coke is blown into the hot combustion gases that leave the melting reactions which take place and give carbon monoxide and hydrogen reduce the carbon is removed from the gasified gas, supplied to the melting chamber furnace and completely burned. The advantage of the invention is that the ashes may be transformed into an elution-resistant granulated building material, in that a tar-free burnable gas is generated and in that oxygen consumption is strongly reduced in comparison with the fly stream gasification process.

Claims

1. A process for generating burnable gas from organic materials comprising:

drying the organic materials by direct or indirect supply of physical enthalpy to form dried materials, and subjecting said dried materials to low-temperature carbonization at 350°

to 500°

C., thereby effecting thermal decomposition into a carbonization gas comprising liquid hydrocarbons, steam, and coke, wherein said coke comprises carbon and an inorganic portion;

burning the carbonization gas with one or more of air, oxygen and oxygen-containing exhaust gases at temperatures above the melting temperature of said inorganic portion to form combustion gas, and removing molten inorganic portions;

converting the combustion gas into gasification gas by decreasing the gas temperature to 800°

to 900°

C., and blowing at least a portion of said coke, which has optionally been ground to form a pulverized fuel, into the combustion gas at 1200°

to 2000°

C., whereby said coke at least partially reduces carbon dioxide present to carbon monoxide, at least partially reduces said steam to hydrogen, and consumes heat;

processing the gasification gas, optionally after indirect and/or direct cooling, by dedusting and chemically cleaning said gasification gas to produce a burnable gas, and feeding dust containing carbon removed from said gasification gas to said burning step.

2. A process according to claim 1, wherein said enthalpy in said drying step is provided by enthalpy from said converting step and from said processing step.

3. A process according to claim 1, wherein said organic materials are selected from the group consisting of water-containing or ballast-containing materials.

4. A process according to claim 3, wherein said water-containing and ballast-containing materials are selected from the group consisting of coal, sludge, refuse, wood, and biomasses.

5. A process according to claim 1, wherein said organic materials have been previously comminuted.

6. A process according to claim 1, wherein the drying step is operated at atmospheric pressure.

7. A process according to claim 1, wherein solids in said carbonization gas formed in the drying step are separated using a screen.

8. A process according to claim 1, wherein said inorganic portion of the drying step is optionally removed by employing a further gas dedusting step.

9. A process according to claim 1, wherein the carbonization gas of the burning step is burnt in a slag-tap furnace.

10. A process according to claim 1, wherein the oxygen-containing exhaust gases are selected from the group consisting of exhaust gas from gas turbines and exhaust gas from internal combustion engines.

11. A process according to claim 1, wherein the melting temperature of the inorganic portion is in the range of 1200°

to 2000°

C.

12. A process according to claim 1, wherein the process occurs at a pressure of 1 to 50 bar.

13. A process according to claim 1, wherein said enthalpy in said drying step is provided by heat generated in said process itself.