Photocatalyst-binder compositions

• US 5,849,200 A
• Filed: 08/21/1996
• Issued: 12/15/1998
• Est. Priority Date: 10/26/1993
• Status: Expired due to Term

• Current Assignee: E. Heller & Company
• Original Assignee: E. Heller & Company
• Inventors: Heller, Ephraim, Heller, Adam, Pishko, Michael V.
• Primary Examiner(s): McCarthy, Neil
• Application Number:
  US08/700,911
• Time in Patent Office: 846 Days
• Field of Search: 106/287.1, 106/287.13, 106/287.14, 106/436, 106/442, 210/748, 210/763, 210/908, 210/909
• US Class Current: 210/748.14
• CPC Class Codes: B01J 35/30 characterised by their physical properties
• CPC Class Codes: B01J 35/39 Photocatalytic properties
• CPC Class Codes: B01J 37/0215 Coating
• CPC Class Codes: B01J 37/0219 the coating containing organic compounds
• CPC Class Codes: C02F 1/32 with ultraviolet light
• CPC Class Codes: C02F 1/725 by catalytic oxidation
• CPC Class Codes: C02F 2305/10 Photocatalysts
• CPC Class Codes: C03C 17/007 containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
• CPC Class Codes: C03C 2217/45 Inorganic continuous phases
• CPC Class Codes: C03C 2217/475 Inorganic materials
• CPC Class Codes: C03C 2217/477 Titanium oxide
• CPC Class Codes: C03C 2217/71 Photocatalytic coatings
• CPC Class Codes: C08G 77/045 containing less than 25 silicon atoms
• CPC Class Codes: C08K 2003/2241 Titanium dioxide
• CPC Class Codes: C09D 183/04 Polysiloxanes
• CPC Class Codes: Y10S 210/908 Organic
• CPC Class Codes: Y10S 210/909 Aromatic compound, e.g. pcb, phenol

Abstract

A photocatalyst composition containing a substantially non-oxidizable binder which allows large amounts of photocatalytic particles to be adhered to a surface. Upon application to a surface, the composition dries or cures to form an adherent, abrasion-resistant, thermostable, and photocatalytic coating.

Claims

1. A process for removing organic compounds from a fluid, the process comprising:

contacting a photocatalytic surface with a fluid containing an organic compound to be removed, the photocatalytic surface being responsive to incident light and comprising particles of a photocatalyst dispersed in a binder, the particles having a diameter of 50 nm or less, the binder having an oxidizable carbon content of less than 15%; and

exposing the contacted photocatalytic surface to incident light for a period of time sufficient to degrade at least a portion of the organic compound.

2. The process of claim 1, wherein said fluid comprises a gas.

3. The process of claim 1, wherein said fluid comprises liquid.

4. The process of claim 1, wherein said fluid comprises air.

5. The process of claim 1, wherein said fluid comprises water.

6. The process of claim 1, wherein said organic compound is oxidized on exposure to ultraviolet light.

7. The process of claim 1, wherein said binder has a backbone and less than one in six atoms of the backbone is oxidizable carbon.

8. The process of claim 1, wherein said binder comprises porous alumina, silica, or mixtures thereof.

9. The process of claim 1, wherein said binder comprises a silicone.

10. The process of claim 1, wherein said binder comprises a macromolecular species.

11. The process of claim 1, wherein said photocatalytic surface further comprises a co-catalyst.

12. The process of claim 1, wherein said photocatalyst comprises a semiconducting oxide.

13. The process of claim 1, wherein said photocatalyst comprises TiO₂.

14. The process of claim 1, wherein said surface comprises metal, glass, wood, plastic, fiber, ceramic or paint.

15. The process of claim 1, wherein said surface comprises a wall, window, flooring, roofing, or filter.

16. The process of claim 1, wherein said surface comprises an interior or exterior surface of a building, vehicle, machine, appliance, fixture, or lamp.

17. The process of claim 1, wherein said photocatalyst catalyzes oxidation of organic compounds by air or oxygen.

18. The process of claim 1, wherein said binder comprises colloidal tin oxide.

19. A process for removing organic compounds from a fluid, the process comprising:

contacting a photocatalytic surface with a fluid containing an organic compound to be removed, the photocatalytic surface being responsive to incident light and comprising particles of a photocatalyst dispersed in a binder, the particles having a diameter of 50 nm or less, the binder having a backbone wherein less than one in six atoms of the backbone is oxidizable carbon; and

exposing the contacted photocatalytic surface to incident light for a period of time sufficient to degrade at least a portion of the organic compound.

20. The process of claim 19, wherein said binder comprises porous alumina, silica, or mixtures thereof.

21. The process of claim 19, wherein said binder comprises colloidal tin oxide.

22. The process of claim 19, wherein said binder comprises a silicone.

23. The process of claim 19, wherein said binder comprises a macromolecular species.

24. A process for removing organic compounds from a fluid, the process comprising:

contacting a photocatalytic surface with a fluid containing an organic compound to be removed, the photocatalytic surface being responsive to incident light and comprising particles of a photocatalyst dispersed in a binder, the particles having a diameter of 50 nm or less, the binder having an oxidizable carbon content of less than 10% after curing for six months; and

exposing the contacted photocatalytic surface to incident light for a period of time sufficient to degrade at least a portion of the organic compound.