Process for the processing of salvaged or waste plastic materials

• US 5,849,964 A
• Filed: 12/27/1995
• Issued: 12/15/1998
• Est. Priority Date: 04/03/1993
• Status: Expired due to Fees

• Current Assignee: "DER Gruene Punkt" Duales System Deutschland AG
• Original Assignee: Veba Oel AG (BP PLC)
• Inventors: Rupp, Martin, Niemann, Klaus, Holighaus, Rolf
• Primary Examiner(s): Caldarola, Glenn
• Assistant Examiner(s): DANG, THUAN D
• Application Number:
  US08/525,750
• Time in Patent Office: 1,084 Days
• Field of Search: 585/241, 585/250
• US Class Current: 585/241
• CPC Class Codes: C10B 57/06 containing additives
• CPC Class Codes: C10G 1/002 in combination with oil conversion- or refining processes
• CPC Class Codes: C10G 1/10 from rubber or rubber waste
• CPC Class Codes: C10G 9/005 Coking (in order to produce liquid products mainly)

Abstract

A process is disclosed for processing used or waste plastic materials in order to recover chemical raw materials and liquid fuel components by depolymerisation of the used materials, which are transformed into a pumpable and into a volatile phase. The volatile phase is separated into a gaseous phase and a condensate or condensable depolymerisation product, which are refined by standard usual procedures. The pumpable phase remaining once the volatile phase is separated is subjected to liquid phase hydrogenation, gasification, low temperature carbonisation or to a combination of said processes.

Claims

1. A process for extracting chemical starting materials and liquid fuel components from a salvaged or waste plastic material, comprising the steps of:

depolymerizing a salvaged or waste plastic material to produce a pumpable liquid phase and a volatile phase without the additions of hydrogen;

separating said liquid phase from said volatile phase;

further separating said volatile phase into a gaseous phase and a condensate;

subjecting said pumpable liquid phase to liquid phase hydrogenation, gassification, low-temperature carbonization or a combination thereof, and subjecting said gaseous phase to a scrubbing step to remove acid components, then subjecting the scrubbed effluent to a liquid phase hydrogenation.

2. The process of claim 1, wherein said depolymerizing is carried out at a pressure of 0.01-300 bar.

3. The process of claim 2, wherein said pressure is 0.1-100 bar.

4. The process of claim 3, wherein said pressure is 0.2-2 bar.

5. The process of claim 1, wherein said depolymerizing is conducted at a temperature of 150°

-470°

C.

6. The process of claim 5, wherein said temperature is 250°

-450°

C.

7. The process of claim 1, wherein said salvaged or waste plastic material has a residence time in said depolymerizing step of 0.1-10 hours.

8. The process of claim 7, wherein said residence time is 0.5-5 hours.

9. The process of claim 1, wherein said separating and further separating steps produce a first flow stream comprising 15-85% by mass of a depolymerized pumpable liquid, a second stream comprising 10-80% by mass of a condensate and a third stream comprising 5-20% by mass of a gas mixture, relative to the mass of said salvaged or waste plastic material.

10. The process of claim 1, wherein said depolymerizing is carried out in the presence of a catalyst.

11. The process of claim 1, wherein said depolymerizing is carried out under turbulent flow conditions.

12. The process of claim 1, wherein said depolymerizing is carried out under an inert gas atmosphere.

13. The process of claim 1, further comprising adding a stripping medium to said depolymerizing step.

14. The process of claim 13, wherein said stripping medium is selected from the group consisting of nitrogen, water vapor, hydrocarbon-containing gases and low-boiling hydrocarbon fractions.

15. The process of claim 1, wherein said salvaged or waste plastic material is combined with a liquid carrier in said depolymerizing step.

16. The process of claim 1, wherein said condensate is further subjected to a hydrogenating refining process on a fixed-bed catalyst.

17. The process of claim 1, wherein said condensate is subjected to a hydrogenating refining process on a moving bed catalyst or in a fluid catalyst bed.