Binder composition for use in three dimensional printing

• US 5,851,465 A
• Filed: 08/21/1997
• Issued: 12/22/1998
• Est. Priority Date: 12/29/1995
• Status: Expired due to Fees

• Current Assignee: Massachusetts Institute of Technology
• Original Assignee: Massachusetts Institute of Technology
• Inventors: Bredt, James F.
• Primary Examiner(s): BRUNSMAN, DAVID M
• Application Number:
  US08/915,977
• Time in Patent Office: 488 Days
• Field of Search: 106/287.34, 106/600, 106/634, 106/636, 106/638, 106/808, 106/816, 106/287.23, 106/287.25, 264/109, 264/112, 264/DIG. 72
• US Class Current: 264/109
• CPC Class Codes: B29C 41/003 characterised by the choice of material
• CPC Class Codes: B29C 64/153 using layers of powder being selectively joined, e.g. by selective laser sintering or melting
• CPC Class Codes: B33Y 10/00 Processes of additive manufacturing
• CPC Class Codes: B33Y 70/00 Materials specially adapted for additive manufacturing
• CPC Class Codes: B41M 3/16 Braille printing typewriters or selective printing mechanisms for Braille printing B41J3/32
• CPC Class Codes: Y10S 264/72 Processes of molding by spraying

Abstract

A binder composition for three dimensional printing of parts is disclosed which is stable during storage and passage through a printhead, yet able to gel under the conditions existing in a powder bed. The binder composition comprises colloidal silica, a catalyst able to promote gelation of the composition when the composition is below a predetermined pH value, and a base able to maintain the pH of the composition above the predetermined value at which the composition gels. Preferably, the catalyst is polyethylene glycol or another ethylene oxide-derived polymer, and the base is triethanolamine. Upon impact with a powder bed, the pH of the binder composition is reduced, as by adding an acid such as citric acid to the powder, thereby causing the binder to gel in the powder.

Claims

1. A process for forming a three dimensional part, comprising:

building up the part in layers, the formation of each layer comprising;

(a) providing a layer of powder in a bed;

(b) providing a binder composition comprising;

a fluid dispersing medium;

silica in a solid particulate form dispersed in the fluid dispersing medium;

a catalyst able to promote gelation of the binder composition when the binder composition is below a predetermined pH value; and

a base able to maintain the pH of the binder composition above the predetermined value at which the binder composition gels; and

(c) selectively depositing through a print head a binder composition onto the powder layer; and

altering the pH of the binder composition in the powder to below the value at which the binder composition gels, whereby the binder composition becomes immobilized in the powder.

2. The process of claim 1, wherein the pH of the binder composition in the powder is altered by providing an acid to the powder prior to the step of selectively depositing the binder composition to the powder.

3. The process of claim 1, wherein the acid comprises citric acid at a concentration of approximately 0.5 percent by weight of powder.

4. The process of claim 1, wherein the pH of the binder composition in the powder is altered by applying gaseous CO₂ to the binder composition and the powder after the step of the selectively depositing the binder composition.

5. The process of claim 1, wherein the powder comprises aluminum oxide or zirconium silicate.

6. The process of claim 1, wherein the fluid dispersing medium comprises distilled water.

7. The process of claim 1, wherein the base substance comprises triethanolamine.

8. The process of claim 1, wherein the base substance is able to maintain the pH of the binder composition above 7.5.

9. The process of claim 1, wherein the base substance is able to maintain the pH of the binder composition between 9 and 9.5.

10. The process of claim 1, wherein the silica is amorphous.

11. The process of claim 1, wherein the silica comprises at least 10 percent by volume of the binder composition.

12. The process of claim 1, wherein the silica comprises at least 17.5 percent by weight of the binder composition.

13. The process of claim 1, wherein the polymer is made from an ethylene oxide.

14. The process of claim 13, wherein the polymer made from an ethylene oxide comprises polyethylene glycol.

15. The process of claim 13, wherein the polymer made from an ethylene oxide is provided at a concentration of at least 100 ppm.

16. The process of claim 13, wherein the molecular weight of the polymer made from an ethylene oxide is between 400 and 35,000.

17. The process of claim 13, wherein the concentration of the polymer made from an ethylene oxide is approximately 0.1 percent by weight.

18. The process of claim 1, further comprising a pH indicator.

19. The process of claim 18, wherein the pH indicator comprises thymol blue.

20. The process of claim 1, wherein the base substance comprises an organic base.

21. The process of claim 1, wherein the base substance comprises triethanolamine, tetramethylammonium hydroxide, ammonia, or morpholine.