Product produced by coating a substrate with an electrically conductive layer

• US 5,851,642 A
• Filed: 07/10/1989
• Issued: 12/22/1998
• Est. Priority Date: 01/22/1985
• Status: Expired due to Fees

• Current Assignee: Saint-Gobain Vitrage "LES Miroirs"
• Original Assignee: Saint-Gobain Vitrage
• Inventors: Sauvinet, Vincent, Bonnaud, Micheline, Bletry, Jean, Trouve, Maurice
• Primary Examiner(s): Turner, A. A.
• Application Number:
  US07/363,758
• Time in Patent Office: 3,452 Days
• Field of Search: 428/212, 428/688, 428/689, 428/699, 428/697, 428/701, 428/702, 428/426, 428/432, 428/336, 428/332, 204/192.1, 204/192.15, 204/192.29, 204/192.27, 204/192.28
• US Class Current: 428/212
• CPC Class Codes: C03C 17/23 Oxides C03C17/02 takes precedence
• CPC Class Codes: C03C 17/253 Coating containing SnO2
• CPC Class Codes: C03C 2217/231 In2O3/SnO2
• CPC Class Codes: C03C 2218/11 from solutions or suspensions
• CPC Class Codes: C03C 2218/17 from a solid phase
• CPC Class Codes: H01L 31/1884 Manufacture of transparent electrodes, e.g. TCO, ITO
• CPC Class Codes: Y02E 10/50 Photovoltaic [PV] energy
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree
• CPC Class Codes: Y10T 428/265 1 mil or less

Abstract

A method for coating a substrate, preferably of glass, with a pyrolyzed transparent, electroconductive layer. The coating is comprised of indium formate, optionally mixed with a powdered or gaseous tin compound or a gaseous organotin compound. The coating layer is deposited upon a hot substrate whereupon it pyrolytically decomposes, forming a layer which is subsequently heat treated in a reducing or an oxidizing atmosphere to optionally enhance the low emissivity and low resistivity of the coating or reduce said low emissivity and low resistivity properties.

Claims

1. A plate of glass coated with a layer consisting essentially of indium and tin oxides having zones of a low emissivity and resistivity of less than or equal to 0.15 and 3×

10^-4 ohm-cm, respectively for a thickness of between about 1800 and 4500 angstroms with at least one other zone wherein the emissivity and resistivity are higher than 0.15 and 3×

10^-4 ohm-cm, respectively that is produced by;

preparing a dry metal composition containing indium formate;

mixing at least a powdered or gaseous tin compound or a gaseous organotin compound with the indium formate in proportions ranging from one to thirty weight percent;

depositing said composition onto a surface of a heated glass plate so as to pyrolyze the composition; and

heating the coated glass plate to enhance the properties of the layer.

2. A plate of glass coated with a pyrolyzed metal oxide layer consisting essentially of indium oxide formed by depositing a predetermined amount of a dry, powdered organic indium compound on the heated glass plate, thereby pyrolyzing the indium compound;

wherein the layer comprises a first zone having an emissivity of less than or equal to 0.15 and a resistivity of less than or equal to 3×

10^-4 ohm-cm, and a second zone having a emissivity greater than 0.15 and a resistivity greater than 3×

10^-4 ohm-cm.

3. The glass plate of claim 2, wherein the thickness of the layer is between about 1800 to 4500 Angstroms.

4. The glass plate of claim 2, wherein the metal oxide layer further comprises oxides of an electrically conductive metal formed by combining at least one compound of the electrically conductive metal with the organic indium compound and depositing the combined compounds on the substrate.

5. The glass plate of claim 4, wherein the at least one electrically conductive metal compound has a decomposition temperature on the same order as the indium compound.

6. The glass plate of claim 5, wherein the at least one electrically conductive metal compound is selected from the group consisting of powdered or gaseous tin compounds and gaseous organotin compounds.

7. The glass plate of claim 6, wherein the indium compound is dry and powdered.

8. The glass plate of claim 6, wherein the powdered tin compounds are added in proportions ranging from one to thirty weight percent and are selected from the group consisting of dibutyltin oxide and dibutyltin fluoride.