Rechargeable lithium battery

• US 5,851,696 A
• Filed: 01/29/1996
• Issued: 12/22/1998
• Est. Priority Date: 01/29/1996
• Status: Expired due to Fees

• Current Assignee: Valence Technology Incorporated (Lithium Werks B.V.)
• Original Assignee: Valence Technology Incorporated (Lithium Werks B.V.)
• Inventors: Barker, Jeremy, Saidi, M. Yazid
• Primary Examiner(s): Gorgos, Kathryn L.
• Assistant Examiner(s): CHANEY, CAROL DIANE
• Application Number:
  US08/593,636
• Time in Patent Office: 1,058 Days
• Field of Search: 429/218
• US Class Current: 429/231.2
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 2004/027 Negative electrodes
• CPC Class Codes: H01M 2300/0025 Organic electrolyte
• CPC Class Codes: H01M 4/485 of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy H01M4/505, H01M4/525 take precedence
• CPC Class Codes: H01M 4/505 of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

The present invention provides an electrochemical cell or battery, which has a nonmetal negative electrode (anode). That is, no solid metal active material is used in the cell. Rather than the conventional solid lithium metal anode, the active material of the new anode comprises a compound of vanadium oxide. Accordingly, the lithium cell of the invention comprises a positive electrode and a negative electrode, where the negative electrode comprises a compound of vanadium oxide which in a fully discharged state is represented by the nominal general formula V₆ O₁₃ or Li_y V₆ O₁₃, y equal to 0; and, in a fully or partially lithiated, fully or partially charged state, is represented by the nominal general formula Li_y V₆ O₁₃, where y is greater than 0 and less than or equal to 8. The unique negative electrode of the invention demonstrates exceptional performance without the disadvantages of metallic lithium negative electrodes.

Claims

1. A lithium battery which comprises a positive electrode and a negative electrode, said negative electrode having an active material comprising an oxide of vanadium and said positive electrode having an active material which is a lithium chalcogenide compound different from Li_y V₆ O_13+x, with 0≦

y<

8 and 0<

x<

2;

said negative electrode comprising said oxide of vanadium, represented by the formula Li_y V₆ O_13+z, where y is greater than or equal to 0 and less than or equal to 8, where z is greater than 0 and less than 2; and

having said oxide which, when fully or partially lithiated with lithium ions and fully or partially charged, is represented by said formula Li_y V₆ O_13+z where y is greater than 4; and

having said oxide which, in an unlithiated, uncharged state, or fully discharged state, is represented by said formula Li_y V₆ O_13+z with y equal to 0, corresponding to V₆ O_13+z ;

said oxide further characterized by an inherent monoclinic crystal structure, and is in the monoclinic crystal structure condition after repeated charging and discharging.

2. The battery according to claim 1 further comprising an electrolyte interposed between said positive electrode and said negative electrode;

and where at least one of said electrolyte and active material of said positive electrode comprises a lithium compound characterized by an ability to react electrochemically with said oxide and releases lithium ions for intercalation into said oxide during charging of said battery.

3. A lithium ion battery which comprises:

a positive electrode and a negative electrode, said negative electrode having an active material comprising an oxide of vanadium and said positive electrode having an active material which is a lithium chalcogenide compound different from Li_y V₆ O_13+x, with 0≦

y<

8 and 0<

x<

2;

said negative electrode comprising said oxide of vanadium which is characterized by an uncharged or fully discharged state which is lithium-free and represented by the formula V₆ O_13+z, and by a charged state represented by the formula Li_x V₆ O_13+z, 4<

x≦

8, where z is greater than 0 and less than 2;

said oxide further characterized by an inherent monoclinic crystal structure and is in monoclinic crystal structure after repeated charging and discharging.

4. A rechargeable lithium battery having non-metallic electrode active material, which has a nominal operating potential in the range of about 1 to about 2 volts, and which maintains over 60 percent of its discharge capacity after 80 cycles at a current density of about 0.5 m A/cm² ;

said battery comprising a positive electrode and a negative electrode, said negative electrode comprising a monoclinic structured active material consisting of an oxide of vanadium, represented by the formula V₆ O_13+z, where z is greater than 0 and less than 2, and said positive electrode having an active material represented by the formula Li_x Mn₂ O₄ having 0<

x<

1;

said positive electrode active material characterized by deintercalation of lithium ions therefrom for intercalation into the negative electrode active material during charging of said battery, whereupon x in Li_x Mn₂ O₄ declines from said value of about 1 during said charging; and

wherein said anode active material contains said oxide of vanadium as the only transition metal oxide therein, and is in the monoclinic crystal structure condition after repeated charging and discharging of said battery.