Reduced residue hard surface cleaner

• US 5,851,981 A
• Filed: 08/22/1997
• Issued: 12/22/1998
• Est. Priority Date: 03/24/1995
• Status: Expired due to Term

• Current Assignee: Clorox Company
• Original Assignee: Clorox Company
• Inventors: Garabedian, Aram Jr., Julian, Jennifer C., Choy, Clement K., Robinson, Gary L.
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): Hardee, John R.
• Application Number:
  US08/916,893
• Time in Patent Office: 487 Days
• Field of Search: 510/182, 510/433, 510/435, 510/501, 510/503
• US Class Current: 510/433
• CPC Class Codes: C11D 1/75 Amino oxides
• CPC Class Codes: C11D 3/044 Hydroxides or bases
• CPC Class Codes: C11D 3/10 Carbonates ; Bicarbonates
• CPC Class Codes: C11D 3/201 linear
• CPC Class Codes: C11D 3/2068 Ethers

Abstract

The invention provides an aqueous, hard surface cleaner with significantly improved residue removal and substantially reduced filming/streaking, said cleaner comprising:

(a) an effective amount of at least one organic solvent with a vapor pressure of at least 0.001 mm Hg at 25° C., and mixtures of such solvents;

(b) an effective amount of at least one semi-polar nonionic surfactant, said surfactant having the structure: ##STR1## wherein R¹ is C_5-20 alkyl, R² and R³ are both C_1-4 alkyl, ##STR2## OR --(CH₂)_p -OH, although R² and R³ do not have to be equal, and n is 1-5, and p is 1-6;

(c) an effective amount of a buffering system which comprises a nitrogenous buffer which will result in a pH of greater than 6.5; and

(d) the remainder as substantially all water.

Claims

1. A method of cleaning soil, without substantial residue remaining, from a hard surface, comprising applying to said surface an aqueous, hard surface cleaner with significantly improved residue removal and substantially reduced filming/streaking, said cleaner comprising:

(a) about 1-50% of at least one organic solvent with a vapor pressure of at least 0.001 mm Hg at 25°

C., and mixtures of such solvents;

(b) about 0.001-2% of at least one semi-polar nonionic surfactant, said surfactant having the structure;

##STR13## wherein R¹ is C_5-20 alkyl, R² and R³ are both C_1-4 alkyl, ##STR14## or --(CH₂)_p -OH, although R² and R³ do not have to be equal, and n is 1-5, and p is 1-6;

(c) about 0.01-2% of a buffering system which comprises ammonium or alkaline earth carbamate, wherein the total amount of semi-polar nonionic surfactant and any optional surfactants does not exceed 2%; and

(d) the remainder as substantially all water; and

(e) removing said soil and soil cleaner from said surface.

2. The method of claim 1 wherein said applying step further comprises the metered delivery of said cleaner from a trigger sprayer.

3. The method of claim 1 wherein said applying step further comprises the metered delivery of said cleaner from a pump sprayer.

4. The method of claim 1 wherein said solvent of said cleaner is an alkanol which is selected from the group consisting of methanol, ethanol, n-propanol, isopropanol, butanol, pentanol, hexanol, their various positional isomers, and mixtures of the foregoing.

5. The method of claim 1 wherein said solvent of said cleaner is an alkylene glycol ether which is selected from the group consisting of ethylene glycol monobutyl ether, ethylene glycol monopropyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, and mixtures thereof.

6. The method of claim 5 wherein said solvent of said cleaner is ethylene glycol monobutyl ether.

7. The method of claim 5 wherein said solvent of said cleaner is propylene glycol n-butyl ether.

8. The method of claim 5 wherein said solvent of said cleaner is propylene glycol t-butyl ether.

9. The method of claim 1 wherein said surfactant of said cleaner further comprises a mixture of the semi-polar nonionic surfactant and an anionic cosurfactant.

10. The method of claim 1 wherein said buffer of said cleaner is ammonium carbamate.

11. The method of claim 10 wherein said buffer of said cleaner further includes an ammonium hydroxide or ammonia.