Transparent barrier coatings exhibiting reduced thin film interference

• US 5,853,830 A
• Filed: 06/06/1997
• Issued: 12/29/1998
• Est. Priority Date: 06/12/1996
• Status: Expired due to Fees

• Current Assignee: Hoechst Trespaphan GmbH
• Original Assignee: Hoechst Trespaphan GmbH
• Inventors: Hubbard, Michael A., McCaulley, James A.
• Primary Examiner(s): Michl, Paul R.
• Application Number:
  US08/870,575
• Time in Patent Office: 571 Days
• Field of Search: 428/35.7, 428/446
• US Class Current: 428/35.7
• CPC Class Codes: C08J 7/043 Improving the adhesiveness of the coatings per se, e.g. forming primers adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50
• CPC Class Codes: C08J 7/048 Forming gas barrier coatings
• CPC Class Codes: C08J 7/06 with compositions not containing macromolecular substances
• CPC Class Codes: C09D 1/02 alkali metal silicates
• CPC Class Codes: Y10T 428/1352 Polymer or resin containing [i.e., natural or synthetic]

Abstract

A vapor barrier coating solution for poly(ethylene terephthalate) (PET) polymeric articles contains a metal polysilicate and transparent nanocrystalline titanium dioxide. The coating reduces interference between light reflected from the top surface of a coated PET polymeric article and the interface between the dried coating and said PET polymeric article. The coated articles are also provided.

Claims

1. A barrier-coated polymeric article comprising a polymeric substrate coated with an inorganic barrier layer, said barrier layer formed by drying on the surface of said article a coating solution comprising a metal polysilicate solution and nanocrystalline titanium dioxide, wherein said coated article is characterized by impermeability to gases, vapors, and aromas, and reduced interference between light reflected from the surface of said barrier layer and the interface between said barrier layer and the polymeric substrate.

2. The article according to claim 1 wherein said metal polysilicate is selected from the group consisting of lithium polysilicate, sodium polysilicate, potassium polysilicate and copolysilicate blends thereof.

3. The article according to claim 1, wherein said metal polysilicate is a copolysilicate of lithium and potassium.

4. The article according to claim 1, wherein said barrier layer is substantially transparent at a thickness of less than 500 nm.

5. The article according to claim 1 wherein said nanocrystalline TiO₂ has an average particle size of less than about 50 nm.

6. The article according to claim 1 wherein said nanocrystalline TiO₂ is rutile.

7. The article according to claim 1 wherein said nanocrystalline TiO₂ is anatase.

8. The article according to claim 1, wherein said solution further comprises a suitable surfactant.

9. The article according to claim 8, wherein the surfactant is nonionic.

10. The article according to claim 9, wherein the surfactant is selected from the group consisting of acetylenic diols and alkyl ethoxylates.

11. The article according to claim 1 which is a film.

12. The article according to claim 1 which is a bottle.

13. The article according to claim 11 wherein said polymer is biaxially oriented.

14. The article according to claim 1 wherein said substrate is plasma treated, corona treated, flame treated or chemically etched/oxidized prior to application of said coating.

16. The article according to claim 3, wherein said copolysilicate has the formula (M₂ O)(SiO₂)_y, wherein M₂ O is (Li₂ O)_x (K₂ O)_1-x, and wherein

(i) x is between 0 and 0.5 and y has a value greater than 4.6 and to about 10;

or

(ii) x ranges from 0.5 to less than 1, and y ranges from about 1 to about 10.

17. The article according to claim 1 wherein said polymeric substrate is substantially transparent.

18. The article according to claim 1 wherein said polymeric substrate has a bulk-averaged refractive index greater than 1.55.

19. The article according to claim 1 wherein said inorganic barrier layer is substantially transparent.

20. The article according to claim 1 wherein said inorganic barrier layer comprises a metal polysilicate and up to about 25% by weight of nanocrystalline titanium dioxide.

21. The article according to claim 1 wherein said nanocrystalline titanium dioxide has an average particle size of less than about 100 nm.

15. A method for producing an improved poly(ethylene terephthalate) polymeric article comprising coating said article with a coating solution comprising a metal polysilicate solution and nanocrystalline titanium dioxide;

drying said solution into an inorganic barrier layer; and

reducing interference between light reflected from the top surface of the coated article and the interface between the inorganic barrier layer and said article.

24. The method according to claim 15, wherein said nanocrystalline titanium dioxide has an average particle size of less than about 100 nm.

25. The method according to claim 15 wherein said coating solution comprises less than about 25% by weight of said titanium dioxide.

22. A barrier-coated polymeric article comprising a substantially transparent polymeric substrate having a bulk-averaged refractive index greater than 1.55, coated with a substantially transparent, inorganic barrier layer comprising a metal polysilicate and up to about 25% by weight of nanocrystalline titanium dioxide, said barrier layer formed by drying on the surface of said substrate a coating solution comprising a metal polysilicate solution and nanocrystalline titanium dioxide having an average particle size of less than about 100 nm, wherein said coated article is substantially transparent, substantially impermeable to gases, vapors, and aromas, and has reduced optical interference between light reflected from the surface of said inorganic barrier layer and the interface between said barrier layer and the polymeric substrate.

23. A barrier-coated, polymeric article comprising a poly(ethylene terephthalate) substrate coated with an inorganic barrier layer comprising less than about 25% by weight of nanocrystalline titanium dioxide, said barrier layer formed by drying on the surface of said article a coating solution comprising a metal polysilicate solution and nanocrystalline titanium dioxide having an average particle size of less than about 100 nm, wherein said coated article is substantially transparent, and substantially impermeable to gases, vapors, and aromas, and has reduced interference between light reflected from the surface of said barrier layer and the interface between said barrier layer and the substrate.