Mineral-filled roofing membrane compositions and uses therefor

• US 5,854,327 A
• Filed: 06/27/1997
• Issued: 12/29/1998
• Est. Priority Date: 06/27/1997
• Status: Expired due to Term

• Current Assignee: Firestone Building Products Company LLC (Bridgestone Corporation)
• Original Assignee: Bridgestone Firestone North American Tire LLC (Bridgestone Corporation)
• Inventors: Davis, James A., Alexander, Brian S.
• Primary Examiner(s): Cain, Edward J.
• Application Number:
  US08/883,647
• Time in Patent Office: 550 Days
• Field of Search: 524/445, 524/492, 524/493
• US Class Current: 524/445
• CPC Class Codes: C08J 2323/16 Ethene-propene or ethene-propene-diene copolymers
• CPC Class Codes: C08J 5/18 Manufacture of films or sheets
• CPC Class Codes: C08K 3/04 Carbon
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08K 3/346 Clay
• CPC Class Codes: C08K 3/36 Silica
• CPC Class Codes: C08K 5/09 Carboxylic acids; Metal salts thereof; Anhydrides thereof
• CPC Class Codes: C08K 5/39 Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
• CPC Class Codes: C08K 5/47 Thiazoles
• CPC Class Codes: C08K 9/00 Use of pretreated ingredients
• CPC Class Codes: C08K 9/06 with silicon-containing compounds
• CPC Class Codes: C08L 23/16 Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
• CPC Class Codes: C08L 2312/00 Crosslinking
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 71/02 Polyalkylene oxides
• CPC Class Codes: E04D 5/06 by making use of plastics

Abstract

A non-black roof sheeting material may be prepared from a composition of matter comprising 100 parts by weight of at least one polymeric rubber selected from the group consisting of ethylene-propylene-diene terpolymers, ethylene-propylene copolymers and other polyolefinic type polymers; from about 20 to about 300 parts by weight of a blend of at least two mineral fillers, per 100 parts of said polymeric rubber, wherein one of said mineral fillers is a reinforcing silica and wherein another of said mineral fillers is a chemically modified clay; from about 20 to about 150 parts by weight of a processing oil, per 100 parts of said polymeric rubber; from 1 to about 6 parts by weight of a sulfur cure package having at least one accelerator but being devoid of any thiuram accelerators, said cure package allowing said sheeting material to cure at about the same rate as a comparable black roof sheeting material at 160° C. The non-black (white) sheeting material may form the ply of a white-on-black bilaminant roofing membrane or it may represent both the top and bottom ply of a non-black (white) polymeric roof sheeting material.

Claims

1. A non-black roof sheeting material prepared from a composition of matter consisting essentially of:

100 parts by weight of at least one polymeric rubber selected from the group consisting of ethylene-propylene-diene terpolymers, ethylene-propylene copolymers and other polyolefinic type polymers;

from about 20 to about 300 parts by weight of a blend of at least two mineral fillers, per 100 parts of said polymeric rubber, wherein one of said mineral fillers is a reinforcing silica and wherein another of said mineral fillers is a clay surface modified with a polyfulctional silane couling agent;

from about 20 to about 150 parts by weight of a processing oil per 100 parts of said polymeric rubber;

from about 1 to about 6 parts by weight of a sulfur cure package having at least one accelerator but being devoid of any thiuram accelerators, said cure package allowing said sheeting material to cure at about the same rate as a carbon black reinforced roof sheeting material at 160°

C.

2. A non-black sheeting material, as set forth in claim 1, wherein said polymeric rubber includes at least one ethylene-propylene-diene terpolymer.

3. A non-black sheeting material, as set forth in claim 2, wherein said at least one ethylene-propylene-diene terpolymer has from about 2 to about 3.2 weight percent unsaturation.

4. A non-black sheeting material, as set forth in claim 1, wherein said chemically modified clay is a mercapto-functional hydrated aluminum silicate.

5. A non-black sheeting material, as set forth in claim 1, wherein said reinforcing silica is a powder having a BET surface area of at least about 210 m² /gram.

6. A non-black sheeting material, as set forth in claim 1, wherein said processing oil is selected from the group consisting of paraffinic oils, naphthenic oils and mixtures thereof.

7. A non-black sheeting material, as set forth in claim 1, wherein said processing oil is selected from the group consisting of petroleum-derived processing oils which are essentially free of aromaticity and sulfur.

8. A non-black sheeting material, as set forth in claim 1, wherein said accelerators of said sulfur cure package includes a dithiocarbamate accelerator and a thiazole accelerator.

9. A bilaminant roofing membrane comprising a first ply of white polymeric sheeting material and a second ply of polymeric sheeting material, said first ply of white polymeric sheeting material being laminated to said second ply of polymeric sheeting material and being prepared from a composition of matter consisting essentially ofparts by weight of at least one polymeric rubber selected from the group consisting of ethylene-propylene-diene terpolymers, ethylene-propylene copolymers and other polyolefinic type polymers;

from about 60 to about 150 parts by weight of a blend of at least two mineral fillers, per 100 parts of said polymeric rubber, wherein one of said mineral fillers is a reinforcing silica and wherein another of said mineral fillers is a clay surface modified with a polvfimctional silane coupling agent;

from about 35 to about 100 parts by weight of a processing oil per 100 parts of said polymeric rubber;

from about 2.5 to about 5 parts by weight of a sulfur cure package having at least one accelerator but being devoid of any thiuram accelerators, said cure package allowing said first ply of sheeting material to cure at about the same rate as said second ply of sheeting material at 160°

C.

10. A bilaminant roofing membrane, as set forth in claim 9, wherein said polymeric rubber includes at least one ethylene-propylene-diene terpolymer.

11. A bilaminant roofing membrane, as set forth in claim 10, wherein said at least one ethylene-propylene-diene terpolymer has from about 2 to about 3.2 weight percent unsaturation.

12. A bilaminant roofing membrane, as set forth in claim 9, wherein said chemically modified clay is a mercapto-functional hydrated aluminum silicate.

13. A bilaminant roofing membrane, as set forth in claim 9, wherein said reinforcing silica is a powder having a BET surface area of at least about 210 m² /gram.

14. A bilaminant roofing membrane, as set forth in claim 9, wherein said processing oil is selected from the group consisting of paraffinic oils, naphthenic oils and mixtures thereof.

15. A bilaminant roofing membrane, as set forth in claim 9, wherein said processing oil is selected from the group consisting of petroleum-derived processing oils which are essentially free of aromaticity and sulfur.

16. A bilaminant roofing membrane, as set forth in claim 9, wherein said accelerators of said sulfur cure package includes a dithiocarbamate accelerator and a thiazole accelerator.

17. A bilaminant roofing membrane, as set forth in claim 9, wherein said second ply of polymeric sheeting material is a second white polymeric sheeting material.

18. A bilaminant roofing membrane, as set forth in claim 9, wherein said second ply of polymeric sheeting material is a black-colored polymeric sheeting material.

19. A method for covering a roof comprising:

applying a bilaminant of sheeting material comprising a white-colored top ply and a black-colored bottom ply to the roof being covered;

said white colored ply being prepared from a composition of matter comprising

100 parts by weight of at least one polymeric rubber selected from the group consisting of ethylene-propylene-diene terpolymers, ethylene-propylene copolymers and other polyolefinic type polymers;

from about 20 to about 300 parts by weight of a blend of at least two non-black mineral fillers, per 100 parts of said polymeric rubber, wherein one of said mineral fillers is a reinforcing silica and wherein another of said mineral fillers is a chemically modified clay;

from about 20 to about 150 parts by weight of a processing oil, per 100 parts of said polymeric rubber;

from 1 to about 6 parts by weight of a sulfur cure package having at least one accelerator but being devoid of any thiuram accelerators, said cure package allowing said sheeting material to cure at about the same rate as a comparable black roof sheeting material at 160°

C.