Electrically conductive fiber filled elastomeric foam

• US 5,855,818 A
• Filed: 09/01/1995
• Issued: 01/05/1999
• Est. Priority Date: 01/27/1995
• Status: Expired due to Fees

• Current Assignee: World Properties Incorporated
• Original Assignee: Rogers Corporation (Rogers Communications Inc.)
• Inventors: Gan, Poh Poh, Bessette, Michael
• Primary Examiner(s): McGinty, Douglas J.
• Application Number:
  US08/612,658
• Time in Patent Office: 1,222 Days
• Field of Search: 252/500, 252/510, 252/511, 252/512, 252/513, 252/514, 252/518, 252/519, 252/520, 252/521, 252/502, 252/503, 252/506, 252/507, 252/518.1, 252/519.1, 428/304.4, 428/308.4, 428/319.1, 521/67, 521/137, 521/130, 521/123, 521/99, 521/76
• US Class Current: 252/511
• CPC Class Codes: A43B 7/36 with earthing or grounding means
• CPC Class Codes: C08J 9/0085 Use of fibrous compounding ingredients C08J9/0076 takes precedence
• CPC Class Codes: C08K 2201/016 Additives defined by their aspect ratio
• CPC Class Codes: C08K 7/02 Fibres or whiskers
• CPC Class Codes: G03G 15/65 Apparatus which relate to the handling of copy material handling sheets or webs in general B65H; for photographic purposes in general G03B
• CPC Class Codes: H01B 1/22 the conductive material comprising metals or alloys
• CPC Class Codes: H01B 1/24 the conductive material comprising carbon-silicon compounds, carbon or silicon
• CPC Class Codes: Y10T 428/249953 Composite having voids in a component [e.g., porous, cellular, etc.]
• CPC Class Codes: Y10T 428/249958 Void-containing component is synthetic resin or natural rubbers
• CPC Class Codes: Y10T 428/24999 Inorganic

Abstract

An electrically conductive elastomeric foam is presented. Preferably, the elastomeric foam comprises polyurethane foam and in accordance with an important feature of this invention, the elastomeric foam is rendered electrically conductive by incorporating therein electrically conductive fibers. As used herein, a "fiber" has a diameter greater than or equal to one micron, and an aspect ratio (length/diameter) greater than or equal to fifteen. In accordance with the method of the present invention, the elastomeric foam is prepared from a polyurethane stock comprised of a polyhydroxyl compound, an organic polyisocyanate compound, a catalyst, a foam stabilizer and an amount of electrically conductive fiber which is effective to render the elastomeric foam electrically conductive. The conductive foam of this invention finds particular utility in the manufacture of conductive soling in footwear, conductive rollers and the like for use in electrophotographic equipment as well as in electrostatic dissipative and EMI/RFI shielding applications.

Claims

1. An electrically conductive elastomeric foam comprising:

an elastomeric foam;

electrically conductive PAN fibers carbonized at least 99% dispersed within said foam, said fibers being present in an amount effective to render said elastomeric foam electrically conductive, such that the volume resistivity of said electrically conductive foam is less th an 1×

10⁶ ohm-cm.

2. The foam of claim 1 wherein:

said effective amount of conductive fibers is in the range of about 5 to about 30 weight percent with respect to the total composition.

3. The foam of claim 1 wherein said elastomeric foam is selected from the group consisting of:

polyvinyl chloride polymers, styrene butadiene rubber polymers, ethylene propylene rubber, ethylene propylene diene monomer polymers, and acrylic polymers.

4. The foam of claim 1 wherein:

said elastomeric foam comprises polyurethane foam.

5. The foam of claim 4, wherein:

said foam is synthesized from a foamable polyurethane mixture comprising at least one polyhydroxyl compound, at least one organic polyisocyanate compound, a catalyst, and a foam stabilizing surfactant.

6. The foam of claim 5, wherein said polyhydroxyl compound is selected from the group consisting of:

hydroxyl terminated polyether polyols, hydroxyl terminated polyester polyols, hydroxyl terminated polyols which are copolymers of polyethers and polyesters, polymer polyols produced by polymerization of ethylenically unsaturated monomers or mixtures thereof in polyol, hydroxyl terminated polybutadiene, and low molecular weight alcohols.

7. The foam of claim 5, wherein said organic polyisocyanate compound is selected from the group consisting of:

toluene diisocyanate, crude toluene diisocyanate, 4,4'"'"'-diphenylmethane diisocyanate, crude 4,4'"'"'-diphenylmethane diisocyanate, aliphatic diisocyanates, mixtures of the preceding diisocyanates, and polymers prepared by the partial reaction of these diisocyanates with polyols.

8. The foam of claim 5, wherein said catalyst is selected from the group consisting of:

dibutyltin dilaurate, stannous octoate, tin and zinc waxes, metal acetyl acetonates, and tertiary amines.

9. The foam of claim 5, wherein said foam stabilizing surfactant comprises an organosilicone copolymer.

15. The foam of claim 1, wherein said electrically conductive fibers have a diameter of greater than or equal to one micron and an aspect ratio greater than or equal to 15.

16. The foam of claim 1, further including:

an ionic additive in an amount in the range from about 0.5 to 10.0 parts of the total formulation.

17. The foam of claim 16 wherein:

said ionic additive is present in an amount of from about 0.5 to 10.0 parts of the total formulation.

18. The foam of claim 16, wherein said ionic additive is a quaternary ammonium salt.

19. The foam of claim 1, further comprising:

an electrically conductive particulate filler.

20. The foam of claim 1 wherein:

said electrically conductive elastomeric foam has a volume resistivity of between about 1×

10² to 1×

10⁶ ohm.cm.

25. The foam of claim 1 wherein:

said dispersing agent is selected from the group consisting of fatty acids, unsaturated polyamine amides and higher molecular weight acidic esters and alkanolammonium salts of polyfunctional polymers.

26. The foam of claim 1 wherein:

said dispersing agent is present in an amount of from about 0.1 to 2 wt. % based on the weight of said fibers.

10. An electrically conductive elastomeric foam comprising:

an elastomeric foam;

electrically conductive fibers dispersed within said foam, wherein said electrically conductive fibers are selected from the group consisting of electrically conductive metals, and glass, ceramic and polymeric fibers rendered electrically conductive by coating with electrically conductive materials, said fibers being present in an amount effective to render said elastomeric foam electrically conductive such that the volume resistivity of said electrically conductive foam is less than 1×

10⁶ ohm-cm; and

at least one coupling agent for improving the dispersion of said fibers in said foam, said coupling agent being selected from the group consisting of silanes, titanates, and zirconates.

11. The foam of claim 10, wherein said electrically conductive material is selected from the group consisting of:

niobium, nickel, stainless steel, chrome, nickel, copper and silver.

13. The foam of claim 10, wherein

said foam is a polyurethane foam.

14. The foam of claim 10, further comprising

at least one dispersing agent for improving the dispersion of said fibers in said foam.

21. The foam of claim 14 wherein:

said dispersing agent is selected from the group consisting of fatty acids, unsaturated polyamine amides, higher molecular weight acidic esters, and alkanolanunonium salts of polyfunctional polymers.

22. An electrically conductive article, comprising

the electrically conductive foam of claim 10.

23. The foam of claim 10 wherein:

said coupling agent is present in an amount of from about 0.1 to 2 wt. % based on the weight of said fibers.

24. The article of claim 22, wherein

the volume resistivity of said electrically conductive foam is less than 1×

10⁶ ohm-cm.

12. An electrically conductive elastomeric foam comprising:

an elastomeric polyurethane foam;

electrically conductive PAN carbon fibers dispersed within said foam, wherein said fibers are carbonized at least 99%, and further wherein said fibers are present in an amount effective to render said elastomeric foam electrically conductive such that the volume resistivity of said electrically conductive foam is less than 1×

10⁶ ohm-cm; and

at least one dispersing agent for improving the dispersion of said fibers in said foam.

27. An electrically conductive article, comprising:

an elastomeric polyurethane foam containing electrically conductive PAN fibers carbonized at least 99% in an amount effective to render said elastomeric foam electrically conductive.

28. The article of claim 27, wherein

the volume resistivity of said electrically conductive foam is less than 1×

10⁶ ohm-cm.

29. An electrically conductive elastomeric foam comprising:

a polyurethane foam;

electrically conductive PAN fibers carbonized at least 99% dispersed within said foam, said fibers being in an amount effective to render said elastomeric foam electrically conductive; and

at least one dispersing agent for improving the dispersion of asid fibers in said foam.