Interfacial blending agent for natural fiber composites

• US 5,858,522 A
• Filed: 02/21/1997
• Issued: 01/12/1999
• Est. Priority Date: 08/30/1993
• Status: Expired due to Term

• Current Assignee: Formtech Enterprises, Inc.
• Original Assignee: Formtech Enterprises, Inc.
• Inventors: Grill, Otto, Turk, David L.
• Primary Examiner(s): PEZZUTO, HELEN LEE
• Application Number:
  US08/803,983
• Time in Patent Office: 690 Days
• Field of Search: 428/308.8, 428/375, 428/378, 428/392, 428/393, 428/394, 428/395
• US Class Current: 428/308.8
• CPC Class Codes: B27N 3/28 characterised by using extrusion presses
• CPC Class Codes: B29C 48/022 characterised by the choice of material
• CPC Class Codes: B29C 48/07 Flat, e.g. panels
• CPC Class Codes: B29C 48/09 Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
• CPC Class Codes: B29C 48/12 Articles with an irregular circumference when viewed in cross-section, e.g. window profiles
• CPC Class Codes: B29K 2105/06 containing reinforcements, fillers or inserts
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: E06B 3/22 Hollow frames E06B3/205 takes precedence
• CPC Class Codes: Y10T 428/249959 Void-containing component is wood or paper
• CPC Class Codes: Y10T 428/2933 Coated or with bond, impregnation or core
• CPC Class Codes: Y10T 428/2938 Coating on discrete and individual rods, strands or filaments
• CPC Class Codes: Y10T 428/2964 Artificial fiber or filament
• CPC Class Codes: Y10T 428/2965 Cellulosic
• CPC Class Codes: Y10T 428/2967 Synthetic resin or polymer
• CPC Class Codes: Y10T 428/2969 Polyamide, polyimide or polyester

Abstract

The invention describes a process for the preparation of a natural fiber and thermoplastic composite and the resulting products therefrom. The process includes the steps of mixing the natural fiber and the thermoplastic in a blender with a porosity aid and an interfacial agent to form a mixture; adding the mixture to a heated extruder; compressing the mixture with an extruder screw having a plurality of flight sections, at least one of the flight sections serving as a compression flight section which compresses the mixture by having its flights spaced closer together than other adjacent flight sections, and at least one other vent flight section which allows gaseous reaction products to be removed from the extruder through a vent in the extruder by having its flights spaced farther apart than the compression section, the vent flight section being positioned after the compression flight section; extruding the mixture through an extrusion die as a composite; and shaping the composite in a vacuum calibration device to a desired profile. The process further includes the step of co-extruding a second thermoplastic onto the natural fiber/thermoplastic composite for some applications (e.g., windows, doors and siding).

Claims

1. A composite article comprising:

a first zone, said first zone being comprised of a first polymer; and

a second zone, said second zone being comprised of

a second polymer,

a natural cellulose-containing fiber,

a porosity agent to control the porosity of said second zone, said second zone having an outer surface, said outer surface being porous to hold and retain wood stain or paint, said porosity agent being present in an amount of from 0.01 to 5% by weight inclusive and selected from the group consisting of a paraffin and a hydrocarbon wax blend; and

an interfacial agent to aid in forming a homogeneous distribution of the natural cellulose-containing fiber in the second polymer, said interfacial agent being functionalized to the extent wherein at least one part of the interfacial agent can form a chemical or a physical bond to at least a portion of a cellulose component of the natural cellulose-containing fiber while at least one other portion of the interfacial agent aids in the compatibilization with the second polymer, said interfacial agent being present in an amount of from 0.01 to 2% by weight inclusive; and

said first and second zones being integral and being coextruded together,

said second zone having a porosity of between 5-40% inclusive.

2. The article of claim 1 wherein

said second zone comprises

from 90-45% by weight inclusive of said second polymer and

from 10-55% by weight inclusive of said natural cellulose-containing fiber.

3. The composite of claim 1 wherein the porosity agent has a melting point of 200°

F. or lower and the interfacial agent is a polymer having at least one linking group capable of forming said chemical or physical bond with said cellulose-containing fiber.

4. The composite of claim 3 wherein the interfacial agent is a polymeric surfactant.

5. The composite of claim 4 wherein the at least one linking group comprises oxygen.

6. The composite of claim 5 wherein at least one atom in the linking group is oxygen contained within a functional group in the polymeric surfactant, said functional group being selected from the group consisting of carboxylic acids, esters, ethers, acrylates, acid anhydrides, amides and alcohols.

7. The composite of claim 6 wherein the interfacial agent is selected from the group consisting of oxidized polyolefin, poly(ethylene-co-acrylic acid), poly(ethylene-co-methacrylic acid), poly(ethylene-co-methyl acrylate-co-acrylic acid), poly(methyl methacrylate-co-methacrylic acid), poly(tert-butyl acrylate-co-ethyl acrylate-co-methacrylic acid), poly(styrene-co-allyl alcohol), poly(vinyl alcohol-co-ethylene), carboxylated poly(vinyl chloride), poly(vinyl chloride-co-vinyl acetate-co-maleic anhydride, polyacrylamide, poly(acrylamide-co-acrylic acid), poly(methyl methacrylate), poly(ethyl methacrylate), poly(ethylene-co-ethyl acrylate), poly(butyl acrylate), poly(ethylene-co-ethyl acrylate-co-maleic anhydride), polystyrene-b-polyacrylic acid, polystyrene-b-polymethacrylic acid, polystyrene-b-polyvinyl alcohol, polystyrene-b-polyoxyethylene, hydroxyl functionalized polybutadiene, poly(vinyl chloride-co-vinyl acetate), poly(vinyl chloride-co-vinyl acetate-co-2-hydroxypropyl acrylate), poly(vinyl chloride-co-vinyl acetate-co-maleic acid).

8. The composite of claim 4 wherein the at least one linking group comprises nitrogen.

9. The composite of claim 8 wherein at least one atom in the linking group is nitrogen contained within a functional group in the polymeric surfactant, said functional group being selected from the group consisting of amines and nitrites.

10. The composite of claim 8 wherein the interfacial agent is selected from the group consisting of poly(acrylonitrile) and poly(acrylonitrile-co-butadiene).

11. The composite of claim 1 wherein the porosity agent is added in an amount of from 0.1% to 4% by weight.

12. The composite of claim 11 wherein the interfacial agent is added in an amount of from 0.05% to 1% by weight.

13. The composite of claim 1 wherein the first and second polymers are independently selected from the group consisting of polyolefins, polystyrenes, polyacrylics, polyvinyl chloride and polyesters.

14. The composite of claim 13 wherein the first and second polymers are different.

15. The composite of claim 13 wherein the first and second polymers are the same.

16. The composite of claim 15 wherein the first and second polymers are polyvinyl chloride.

17. The composite of claim 1 wherein the natural cellulose-containing fiber is wood flour.

18. A composite article comprising:

a first zone, said first zone being comprised of a polyvinyl chloride polymer; and

a second zone, said second zone being comprised of

a polyvinyl chloride polymer,

a natural cellulose-containing fiber,

a porosity agent to control the porosity of said second zone, said second zone having an outer surface, said outer surface being porous to hold and retain wood stain or paint, said porosity agent being present in an amount of from 0.01 to 5% by weight inclusive and selected from the group consisting of a paraffin and a hydrocarbon wax blend; and

an interfacial agent to form a homogeneous melt of the natural cellulose-containing fiber and the second polymer, said interfacial agent being functionalized to the extent wherein at least one part of the interfacial agent can form a chemical or a physical bond to at least a portion of a cellulose component of the natural cellulose-containing fiber while at least one other portion of the interfacial agent aids in the compatibilization with the second polymer, said interfacial agent being present in an amount of from 0.01 to 2% by weight inclusive; and

said first and second zones being integral and being coextruded together,

said second zone having a porosity of between 5-40% inclusive.

19. The article of claim 18 wherein

said second zone comprises

from 90-45% by weight inclusive of polyvinyl chloride polymer and

from 10-55% by weight inclusive of said natural cellulose-containing fiber.

20. The composite of claim 18 wherein the porosity agent has a melting point of 200°

F. or lower and the interfacial agent is a polymer having at least one linking group capable of forming said chemical or physical bond with said cellulose-containing fiber.

21. The composite of claim 20 wherein the interfacial agent is a polymeric surfactant.

22. The composite of claim 21 wherein the at least one linking group comprises oxygen.

23. The composite of claim 22 wherein at least one atom in the linking group is oxygen contained within a functional group in the polymeric surfactant, said functional group being selected from the group consisting of carboxylic acids, esters, ethers, acrylates, acid anhydrides, amides and alcohols.

24. The composite of claim 23 wherein the interfacial agent is selected from the group consisting of oxidized polyolefin, poly(ethylene-co-acrylic acid), poly(ethylene-co-methacrylic acid), poly(ethylene-co-methyl acrylate-co-acrylic acid), poly(methyl methacrylate-co-methacrylic acid), poly(tert-butyl acrylate-co-ethyl acrylate-co-methacrylic acid), poly(styrene-co-allyl alcohol), poly(vinyl alcohol-co-ethylene), carboxylated poly(vinyl chloride), poly(vinyl chloride-co-vinyl acetate-co-maleic anhydride, polyacrylamide, poly(acrylamide-co-acrylic acid), poly(methyl methacrylate), poly(ethyl methacrylate), poly(ethylene-co-ethyl acrylate), poly(butyl acrylate), poly(ethylene-co-ethyl acrylate-co-maleic anhydride), polystyrene-b-polyacrylic acid, polystyrene-b-polymethacrylic acid, polystyrene-b-polyvinyl alcohol, polystyrene-b-polyoxyethylene, hydroxyl functionalized polybutadiene, poly(vinyl chloride-co-vinyl acetate), poly(vinyl chloride-co-vinyl acetate-co-2-hydroxypropyl acrylate), poly(vinyl chloride-co-vinyl acetate-co-maleic acid).

25. The composite of claim 21 wherein the at least one linking group comprises nitrogen.

26. The composite of claim 25 wherein at least one atom in the linking group is nitrogen contained within a functional group in the polymeric surfactant, said functional group being selected from the group consisting of amines and nitriles.

27. The composite of claim 26 wherein the interfacial agent is selected from the group consisting of poly(acrylonitrile) and poly(acrylonitrile-co-butadiene).

28. The composite of claim 18 wherein the porosity agent is added in an amount of from 0.1% to 4% by weight.

29. The composite of claim 28 wherein the interfacial agent is added in an amount of from 0.05% to 1% by weight.

30. The composite of claim 18 wherein the natural cellulose-containing fiber is wood flour.

31. A composite article comprising:

a first zone, said first zone being comprised of a first polymer; and

a second zone, said second zone being comprised of

a second polymer,

a natural cellulose-containing fiber,

a porosity agent to control the porosity of said second zone, said second zone having an outer surface, said outer surface being porous to hold and retain wood stain or paint; and

an interfacial agent to aid in forming a homogeneous distribution of the natural cellulose-containing fiber in the second polymer, said interfacial agent having at least one portion which is hydrophilic and at least one other portion wich is hydrophobic;

said porosity agent and interfacial agent interacting and combined in a ratio to obtain fusion of said second polymer and natural cellulose-containing fiber, and a porosity of between 5-40% inclusive in said second zone; and

said first and second zones being integral and being coextruded together.

32. The article of claim 31 wherein

said second zone comprises

from 90-45% by weight inclusive of said second polymer and

from 10-55% by weight inclusive of said natural cellulose-containing fiber.

33. The composite of claim 32 wherein the porosity agent is selected from the group consisting of paraffin or hydrocarbon wax blend having a melting point of 200°

F. or lower and the interfacial agent is a polymer having at least one linking group capable of forming said chemical or physical bond with said cellulose-containing fiber.

34. The composite of claim 33 wherein the interfacial agent is a polymeric surfactant.

35. The composite of claim 34 wherein the at least one linking group comprises oxygen.

36. The composite of claim 35 wherein at least one atom in the linking group is oxygen contained within a functional group in the polymeric surfactant, said function group selected from the group consisting of carboxylic acids, esters, ethers, acrylates, acid anhydrides, amides and alcohols.

37. The composite of claim 36 wherein the interfacial agent is selected from the group consisting of oxidized polyolefin, poly(ethylene-co-acrylic acid), poly(ethylene-co-methacrylic acid), poly(ethylene-co-methyl acrylate-co-acrylic acid), poly(methyl methacrylate-co-methacrylic acid), poly(tert-butyl acrylate-co-ethyl acrylate-co-methacrylic acid), poly(styrene-co-allyl alcohol), poly(vinyl alcohol-co-ethylene), carboxylated poly(vinyl chloride), poly(vinyl chloride-co-vinyl acetate-co-maleic anhydride, polyacrylamide, poly(acrylamide-co-acrylic acid), poly(methyl methacrylate), poly(ethyl methacrylate), poly(ethylene-co-ethyl acrylate), poly(butyl acrylate), poly(ethylene-co-ethyl acrylate-co-maleic anhydride), polystyrene-b-polyacrylic acid, polystyrene-b-polymethacrylic acid, polystyrene-b-polyvinyl alcohol, polystyrene-b-polyoxyethylene, hydroxyl functionalized polybutadiene, poly(vinyl chloride-co-vinyl acetate), poly(vinyl chloride-co-vinyl acetate-co-2-hydroxypropyl acrylate), poly(vinyl chloride-co-vinyl acetate-co-maleic acid).

38. The composite of claim 34 wherein the at least one linking group comprises nitrogen.

39. The composite of claim 38 wherein at least one atom in the linking group is nitrogen contained within a functional group in the polymeric surfactant, said functional group being selected from the group consisting of amines and nitriles.

40. The composite of claim 39 wherein the interfacial agent is selected from the group consisting of poly(acrylonitrile) and poly(acrylonitrile-co-butadiene).

41. The composite of claim 31 wherein the porosity agent is added in an amount of from 0.01 to 5% by weight.

42. The composite of claim 41 wherein the porosity agent is added in an amount of from 0.1% to 4% by weight.

43. The composite of claim 31 wherein the interfacial agent is added in an amount of from 0.01% to 2% by weight.

44. The composite of claim 43 wherein the interfacial agent is added in an amount of from 0.05% to 1% by weight.

45. The composite of claim 31 wherein the first and second polymers are independently selected from the group consisting of polyolefins, polystyrenes, polyacrylics, polyvinyl chloride and polyesters.

46. The composite of claim 45 wherein the first and second polymers are different.

47. The composite of claim 45 wherein the first and second polymers are the same.

48. The composite of claim 47 wherein the first and second polymers are polyvinyl chloride.

49. The composite of claim 31 wherein the natural cellulose-containing fiber is wood flour.