Bipolar electroluminescent device

• US 5,858,561 A
• Filed: 03/02/1995
• Issued: 01/12/1999
• Est. Priority Date: 03/02/1995
• Status: Expired due to Term

• Current Assignee: Ohio State Innovation Foundation (Ohio State University)
• Original Assignee: Ohio State University
• Inventors: Epstein, Arthur J., Wang, Yunzhang, Gebler, Darren Douglas
• Primary Examiner(s): YAMNITZKY, MARIE ROSE
• Application Number:
  US08/396,465
• Time in Patent Office: 1,412 Days
• Field of Search: 428/411.1, 428/457, 428/461, 428/688, 428/689, 428/698, 428/699, 428/917, 428/690, 313/504, 313/509, 257/79
• US Class Current: 428/690
• CPC Class Codes: H05B 33/12 Light sources with substantially two-dimensional radiating surfaces
• CPC Class Codes: H05B 33/14 characterised by the chemical or physical composition or the arrangement of the electroluminescent material , or by the simultaneous addition of the electroluminescent material in or onto the light source
• CPC Class Codes: H05B 33/22 characterised by the chemical or physical composition or the arrangement of auxiliary dielectric or reflective layers
• CPC Class Codes: H05B 33/26 characterised by the composition or arrangement of the conductive material used as an electrode
• CPC Class Codes: H10K 50/00 Organic light-emitting devices integrated devices or assemblies of multiple devices H10K59/00, H10K65/00; organic semiconductor lasers H01S5/36
• CPC Class Codes: H10K 71/841 Applying alternating current [AC] during manufacturing or treatment
• CPC Class Codes: Y10S 428/917 Electroluminescent
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]
• CPC Class Codes: Y10T 428/31678 Of metal

Abstract

Light emitting bipolar devices consist of an electroluminescent organic light emitting material sandwiched between two layers of insulating material each of which is in contact with an electrode. The devices operate with AC voltage at voltages of less than twenty four volts and in some instances at less than five volts. Under AC driving, the device produces modulated light output that can be frequency or amplitude modulated. Under DC driving, the device operates in both forward and reverse bias.

Claims

1. A bipolar electroluminescent device comprising:

a) an electroluminescent organic light-emitting material;

b) a first electrically insulating material contacting said electroluminescent organic light-emitting material;

c) a second electrically insulating material contacting said electroluminescent organic light-emitting material;

d) said electroluminescent organic light-emitting material, said first electrically insulating material and said second electrically insulating material positioned and of a thickness to emit light in both a forward and a reverse current direction;

e) a first electrode in electrical contact with said first electrically insulating material;

f) a second electrode in electrical contact with said second electrically insulating material, and

g) connection means for electrically connecting said first electrode and said second electrode to a voltage source.

2. The bipolar electroluminescent device according to claim 1 wherein said voltage source is an alternating voltage source.

3. The bipolar electroluminescent device according to claim 1 wherein at least one of said first electrically insulating material and said second insulating material is selected from the group of insulating materials consisting of ceramic insulating materials, organic insulating materials, and inorganic polymer insulating materials.

4. The bipolar electroluminescent device according to claim 3 with at least one of said first electrically insulating material and said second insulating material being an organic insulating material.

5. The bipolar electroluminescent device according to claim 4 wherein said organic insulating material is selected from the group of organic insulating materials consisting of conjugated polymers, acrylic polymers, nylon polymers, polyvinylcarbazoles, conjugated copolymers, acrylic copolymers, nylon copolymers, polyvinylcarbazole copolymers, organic insulating molecules, and mixtures thereof.

6. The bipolar electroluminescent device according to claim 5 with said organic insulating material being a conjugated polymer.

7. The bipolar electroluminescent device according to claim 6 with said conjugated polymer being a polyaniline polymer.

8. The bipolar electroluminescent device according to claim 7 with said polyaniline polymer being a polyaniline emeraldine base.

9. The bipolar electroluminescent device according to claim 5 with said organic insulating material being an organic insulating molecule.

10. The bipolar electroluminescent device according to claim 9 with said organic insulating molecule dispersed in a host polymer.

11. The bipolar electroluminescent device according to claim 10 with said organic insulating molecule being 2-(4-biphenyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole.

12. The bipolar electroluminescent device according to claim 10 with said host polymer being emeraldine base.

13. The bipolar electroluminescent device according to claim 11 with said host polymer being emeraldine base.

14. The bipolar electroluminescent device according to claim 10 with said host polymer being polyvinylcarbazole.

15. The bipolar electroluminescent device according to claim 11 with said host polymer being polyvinylcarbazole.

16. The bipolar electroluminescent device according to claim 5 with said organic insulating material being an acrylic polymer.

17. The bipolar electroluminescent device according to claim 16 with said acrylic polymer being polymethylmethacrylate.

18. The bipolar electroluminescent device according to claim 3 with said insulating material being a ceramic insulating material.

19. The bipolar electroluminescent device according to claim 18, with said ceramic insulating material being aluminum oxide.

20. The bipolar electroluminescent device according to claim 1 wherein at least one of the first electrically insulating material and said second electrically insulating material is at least partially transparent.

21. The bipolar electroluminescent device according to claim 1 wherein said electroluminescent organic light-emitting material is selected from the group of organic light-emitting materials consisting of electroluminescent organic light-emitting molecules and electroluminescent organic light-emitting polymers.

22. The bipolar electroluminescent device according to claim 21 with said electroluminescent organic light-emitting material being an electroluminescent organic light-emitting polymer.

23. The bipolar electroluminescent device according to claim 22 wherein said electroluminescent organic light-emitting polymer is a polymer selected from the group of electroluminescent polymers consisting of polypyridines, polypyridylvinylenes, polyphenylenes, polyphenylenevinylenes, polythiophenes, polyvinylcarbazoles, polyfluorenes, polynaphthalenevinylenes, polyphenyleneacetylenes, polyphenylenediacetylenes, polycyanoterephthalylidenes, polyphenylenebenzobisthiazoles, polybenzimidazobenzophenanthrolines, polypyridine copolymers, polypyridylvinylene copolymers, polyphenylene copolymers, polyphenylenevinylene copolymers, polythiophene copolymers, polyvinylcarbazole copolymers, polyfluorene copolymers, polynaphthalenevinylene copolymers, polyphenyleneacetylene copolymers, polyphenylenediacetylene copolymers, polycyanoterephthalylidene copolymers, polyphenylenebenzobisthiazole copolymers, polybenzimidazobenzophenanthroline copolymers, and mixtures thereof.

24. The bipolar electroluminescent device according to claim 23 with said electroluminescent polymer being a polypyridine.

25. The bipolar electroluminescent device according to claim 24 with said polypyridine being poly(p-pyridine).

26. The bipolar electroluminescent device according to claim 23 with said electroluminescent organic polymer being a copolymer.

27. The bipolar electroluminescent device according to claim 26 wherein said electroluminescent copolymer is poly(phenylenevinylene pyridylvinylene).

28. The bipolar electroluminescent device according to claim 23 with said electroluminescent organic polymer being an electroluminescent polyphenylene.

29. The bipolar electroluminescent device according to claim 23 with said electroluminescent organic polymer being an electroluminescent polyphenylenevinylene.

30. The bipolar electroluminescent device according to claim 29 with said electroluminescent polyphenylenevinylene being poly(p-phenylenevinylene).

31. The bipolar electroluminescent device according to claim 23 with said electroluminescent organic polymer being an electroluminescent polyphenylenebenzobisthiazole.

32. The bipolar electroluminescent device according to claim 1 with at least one of said first electrode and said second electrode being an electrode material that is at least partially transparent.

33. The bipolar electroluminescent device according to claim 1 with at least one of said first electrode and said second electrode being an electrode material selected from the group of electrode materials consisting of In--SnO₂, metals, alloys, conducting non-metals, and conducting organic polymers.

34. The bipolar electroluminescent device according to claim 33 with said electrode material being In--SnO₂.

35. The bipolar electroluminescent device according to claim 1 further comprising a substrate in contact with one of said first electrode and said second electrode.

36. The bipolar electroluminescent device according to claim 35 wherein said substrate is at least partially transparent.

37. The bipolar electroluminescent device according to claim 35 with said substrate being electrically non-conducting.

38. The bipolar electroluminescent device according to claim 35 wherein said substrate is selected from the group of substrates consisting of glass and plastic.

39. The bipolar electroluminescent device according to claim 38 with said substrate being glass.

40. The bipolar electroluminescent device according to claim 39 with said electrode contacting said substrate being In--SnO₂.

41. The bipolar electroluminescent device according to claim 1 having a turn-on voltage of less than about 24 volts.

42. The bipolar electroluminescent device according to claim 1 having a turn-on voltage of less than about 12 volts.

43. The bipolar electroluminescent device according to claim 1 having a turn-on voltage of less than about 6 volts.

44. The bipolar electroluminescent device according to claim 1 having modulated light output.

45. The bipolar electroluminescent device according to claim 44 having frequency modulated light output.

46. The bipolar electroluminescent device according to claim 44 having amplitude modulated light output.

47. The bipolar electroluminescent device according to claim 1 wherein said first electrode and said second electrode are said connection means for electrically connecting said first electrode and said second electrode to said voltage source.