Process for the filtration of suspensions containing sulfur

• US 5,861,099 A
• Filed: 01/31/1994
• Issued: 01/19/1999
• Est. Priority Date: 02/06/1993
• Status: Expired due to Fees

• Current Assignee: Kronos Incorporated (Seahawk Acquisition Corp.)
• Original Assignee: Rheox, Inc. (Elementis PLC)
• Inventors: Hartmann, Achim
• Primary Examiner(s): Hruskoci, Peter A.
• Application Number:
  US08/188,978
• Time in Patent Office: 1,814 Days
• Field of Search: 23/293 S, 210/702, 210/710, 210/737, 210/772, 423/224, 423/578.1
• US Class Current: 210/710
• CPC Class Codes: B01D 53/52 Hydrogen sulfide
• CPC Class Codes: C01B 17/02 Preparation of sulfur; Purification
• CPC Class Codes: C01B 17/0205 Separation of sulfur from liquids, e.g. by coalescence
• CPC Class Codes: C01B 17/05 by wet processes

Abstract

To improve the separation of dispersedly precipitated sulfur from a washing solution used in the oxidative washing of hydrogen sulfide containing waste gases, the suspension is heated before filtration to about 45° C. to 70° C. Such heating causes the sulfur contained in the solution to coagulate into large flocks and form a mass of high purity sulfur which is largely non-thixotropic. This mass, often called a filter cake, can be washed and utilized in a large number of ways as a source of sulfur.

Claims

1. A process for separating dispersed sulfur contained in a sulfur containing alkaline suspension formed by the oxidative washing of a hydrogen sulfide containing gas comprising the steps of heating the suspension to increase its temperature to at least 45°

C. but no more than about 70°

C. thereby causing coagulated sulfur solid particles to form and then filtering the suspension to form from such particles a non-thixotropic sulfur-containing filter cake.

2. The process according to claim 1, wherever the suspension is heated through direct introduction of steam.

3. The process according to claim 1, wherein the suspension is heated to about 60°

C. before filtering.

4. The process according to claim 1, wherein the suspension is held for at least 5 minutes at the increased temperature.

5. The process according to claim 1, comprising the additional step of washing the sulfur-containing filter cake with water.

6. The process according to claim 1, wherein the hydrogen sulfide containing gas was obtained from a manufacturing process selected from titanium dioxide manufacture, coal burning public electrical utility manufacture and pharmaceutical manufacture.