Polymer alloy blend or composition and shaped articial obtained therefrom

• US 5,863,986 A
• Filed: 01/23/1997
• Issued: 01/26/1999
• Est. Priority Date: 12/27/1993
• Status: Expired due to Fees

• Current Assignee: Ticona GmbH (Celanese Corporation)
• Original Assignee: Ticona GmbH (Celanese Corporation), Mitsui Petrochemical Industries, Ltd.
• Inventors: Herrmann-Schonherr, Otto, Osan, Frank
• Primary Examiner(s): Mullis, Jeff
• Application Number:
  US08/787,889
• Time in Patent Office: 733 Days
• Field of Search: 525/63, 525/64, 525/75, 525/98, 525/165, 525/210, 525/211
• US Class Current: 525/63
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 45/00 Compositions of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Compositions of derivatives of such polymers of cyclic anhydrides or imides C08L35/00; of cyclic esters of polyfunctional acids C08L31/00
• CPC Class Codes: C08L 51/00 Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds for ABS polymers C08L55/02; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers

Abstract

Polymer alloy comprising a) one or more cycloolefin copolymers and b) one or more types of core-shell particles and c) one or more block copolymers.

Claims

1. A polymer alloy, blend or composition comprising

(a) at least one cycloolefin copolymer containing

0.1-99% by weight, based on the total mass of the cycloolefin copolymer, of structural units obtained the polymerization of at least one monomer of formulas (I) or (III) ##STR6## wherein the radicals R¹ through R⁶ are identical or different and are hydrogen or a C₁ -C₂₀ -hydrocarbon radical, or two or more radicals R¹ to R⁶ form a ring;

and

10to 60% by weight, based on the total mass of the cycloolefin copolymer, of structural units obtained from the polymerization of at least one acyclic olefin of the formula (VIII)

space="preserve" listing-type="equation">R.sup.9 R.sup.11 C═

CR.sup.10 R.sup.12 (VIII)

where R⁹ through R¹² are identical or different and are hydrogen or C₁ -C₈ alky; and

(b) 3 to 25% by weight, based on the total weight of the alloy, blend or composition, of core-shell particles, said core-shell particles containing;

from 30 to 60% by volume, based on the total volume of said core-shell particles, of at least one rubber phase, and

from 40 to 70% by volume, based on the total volume of said core-shell particles, of at least one hard, non-rubbery phase; and

(c) from 1 to 10% by weight, based on the total mass of the alloy, blend or composition, of a block copolymer.

2. A polymer alloy, blend or composition as claimed in claim 1, wherein said alloy, blend or composition has an elongation at break of 4 to 200% and a notched impact toughness of from 2.5 to 100 KJ/m².

3. A polymer alloy, blend or composition as claimed in claim 2, wherein said alloy, blend or composition has an elongation at break of at least 5% and a notched impact toughness of at least 4 KJ/m².

4. A polymer alloy, blend or composition as claimed in claim 2, wherein one or more of said cycloolefin polymers has a solubility parameter of at least about 13.5 J^1/2 cm^3/2.

5. The polymer alloy, blend or composition as claimed in claim 1, wherein said structural units obtained from the polymerization of at least one acyclic olefin comprise units obtained from ethylene.

6. The polymer alloy, blend or composition as claimed in claim 5, wherein said cycloolefin copolymer consists essentially of structural units obtained from the polymerization of a monomer of formula (I), alone or in combination with a monomer of formula (III).

7. The polymer alloy, blend or composition as claimed in claim 1, wherein said cycloolefin copolymer comprises structural units obtained from the polymerization of ethylene and norbornene or tetracyclododecene.

8. A shaped article formed from the polymer alloy, blend or composition of claim 1.

9. A process for preparing a polymer alloy, blend or composition, comprising:

forming a masterbatch by mixing together (a) one or more cycloolefin copolymers, (b) a particulate mass comprising core-shell particles, and (c) one or more block copolymers, to obtain the masterbatch, and

mixing the resulting masterbatch with one or more cycloolefin copolymers.