Composition for laser marking

• US 5,866,644 A
• Filed: 03/17/1997
• Issued: 02/02/1999
• Est. Priority Date: 03/17/1997
• Status: Expired due to Term

• Current Assignee: SABIC Global Technologies BV (Government of Saudi Arabia)
• Original Assignee: General Electric Company
• Inventors: Flohil-Janse, Yvonne, Mercx, Franciscus Petrus Maria, van der Weele, Chris
• Primary Examiner(s): Hoke, Veronica P.
• Application Number:
  US08/819,647
• Time in Patent Office: 687 Days
• Field of Search: 524/449, 524/417, 524/494, 524/413, 430/945
• US Class Current: 524/417
• CPC Class Codes: B41M 5/267 Marking of plastic artifacts, e.g. with laser
• CPC Class Codes: C08K 3/32 Phosphorus-containing compounds
• CPC Class Codes: C08K 3/34 Silicon-containing compounds
• CPC Class Codes: G11B 7/251 comprising inorganic materials dispersed in an organic matrix
• CPC Class Codes: Y10S 430/146 Laser beam

Abstract

A resin composition having laser marking properties with the CO₂ laser with radiation at 10600 nm comprises a polyester thermoplastic resin, a sufficient amount of dark pigment for forming a dark background coloration, a mica material for absorbing said laser radiation, and an effective amount of a hydrated metal phosphate containing water of crystallization wherein said metal phosphate decomposes in laser struck areas to release said hydrated water whereby light colored markings in laser struck areas are obtained on said dark background coloration.

Claims

1. A resin composition having laser marking properties with the CO₂ laser with radiation at 10600 nm comprises a polyester thermoplastic resin, a sufficient amount of dark pigment for forming a dark background coloration, from about 1 to about 5 percent of said composition comprising a mica material for absorbing said laser radiation, and an effective amount of hydrated zinc phosphate containing wherein said zinc phosphate decomposes in laser struck areas to release said hydrated water whereby light colored markings in laser struck areas are obtained on said dark background coloration.

2. A resin composition having laser marking properties according to claim 1 wherein said mica is present in an amount from 2 to 4 percent by weight based on the total weight of the composition.

3. A resin composition having laser marking properties according to claim 1 wherein said mica is a complex potassium aluminum silicate.

4. A resin composition having laser marking properties according to claim 1 wherein said hydrated metal phosphate is a crystalline substance containing one or more molecules of water of crystallization capable of giving up its water of crystallization in the laser struck areas.

5. A resin composition having laser marking properties according to claim 1 wherein said polyester composition comprises structural units of the following formula:

##STR2## wherein each R¹ is independently a divalent aliphatic, alicyclic or aromatic hydrocarbon or polyoxyalkylene radical, or mixtures thereof and each A¹ is independently a divalent aliphatic, alicyclic or aromatic radical, or mixtures thereof.

6. A resin composition having laser marking properties according to claim 1 additionally including reinforcing glass fibers.

7. A resin composition having laser marking properties according to claim 6 wherein said glass fibers comprise from 5 to 40 weight percent.

8. A molded article having laser radiated marked surface portions, said article comprises a polyester thermoplastic resin, a sufficient amount of dark pigment for forming a dark background coloration, from about 1 to about 5 percent of said composition comprising a mica material for absorbing said laser radiation, and an effective amount of zinc phosphate containing water of crystallization wherein said zinc phosphate decomposes in laser struck areas to release said water of crystallization whereby light colored markings in laser struck areas are obtained on said dark background coloration.

9. A molded article having laser marking properties according to claim 8 wherein said hydrated metal phosphate is a crystalline substance containing one or more molecules of water of crystallization capable of giving up its water of crystallization in the laser struck areas.

10. A molded article having laser marking properties according to claim 9 wherein said polyester composition comprises structural units of the following formula:

##STR3## wherein each R¹ is independently a divalent aliphatic, alicyclic or aromatic hydrocarbon or polyoxyalkylene radical, or mixtures thereof and each A¹ is independently a divalent aliphatic, alicyclic or aromatic radical, or mixtures thereof.

11. A molded article having laser marking properties according to claim 9 additionally including reinforcing glass fibers.

12. A molded article having laser marking properties according to claim 9 wherein said fibrous glass comprises from 5 to 40 weight percent.