Polymer-dispersed liquid crystal device having an ultraviolet-polymerizable matrix and a variable optical transmission and a method for preparing same

• US 5,867,238 A
• Filed: 08/19/1996
• Issued: 02/02/1999
• Est. Priority Date: 01/11/1991
• Status: Expired due to Fees

• Current Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Original Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Inventors: Huffman, William A., Miller, Stephen A., Gilbert, Laurence R., Vesley, George F.
• Primary Examiner(s): Sikes, William L.
• Assistant Examiner(s): Parker, Kenneth
• Application Number:
  US08/698,443
• Time in Patent Office: 897 Days
• Field of Search: 359/51, 359/52, 349/92, 349/93, 349/158, 349/80
• US Class Current: 349/92
• CPC Class Codes: G02F 1/1333 Constructional arrangements; Manufacturing methodsG02F1/135, G02F1/136 take precedence

Abstract

A polymer-dispersed liquid crystal device comprises a multiplicity of droplets of a birefringent, functionally nematic liquid crystal material dispersed in a matrix comprising the reaction product of ultraviolet radiation polymerizable materials. The device specularly transmits incident light as a function of the magnitude of an electric field applied across the device. The difference between a first applied voltage corresponding to a first percentage of the total incident light transmitted by the device as specular light and a second applied voltage corresponding to a second percentage of the total incident light transmitted by the device as specular light is greater than or equal to 15 volts. As a result, a polymer-dispersed liquid crystal device according to the invention displays a variable grey scale which has a uniform optical transmission. A method for preparing a PDLC device in general is also disclosed.

Claims

1. A liquid crystal-containing sandwich construction comprising:

a first flexible, polymeric substrate having an electrode material on one major surface thereof;

a second flexible, polymeric substrate having an electrode material on one major surface thereof, the major surfaces of the first and second substrates having electrode material thereon being in a facing relationship; and

a liquid crystal-containing layer comprising a liquid crystal material blended with an ultraviolet radiation polymerizable liquid medium, the layer being disposed between the major surfaces of the first and second substrates having electrode material thereon;

wherein the sandwich construction is free from mechanical spacers that separate the major surfaces of the first and second substrates and control the thickness of the liquid crystal-containing layer therebetween.

2. A liquid crystal-containing sandwich construction according to claim 1 wherein the liquid crystal material is selected from the group consisting of birefringent chiral nematic type liquid crystal material, chiral nematic type liquid crystal material, cholesteric type liquid crystal material, and mixtures thereof.

3. A liquid crystal-containing sandwich construction according to claim 2 wherein the liquid crystal material has at least one nematic mesophase.

4. A liquid crystal-containing sandwich construction according to claim 1 wherein the liquid crystal material has an optical anisotropy in the range of about 0.01 to 0.5.

5. A liquid crystal-containing sandwich construction according to claim 1 wherein the parts by weight ratio of the liquid crystal material to the ultraviolet radiation polymerizable medium is in the range of 40:

60 to 60;

40.

6. A device according to claim 1 wherein each of the first and second substrates is a polyester or a copolyester.

7. A liquid crystal containing sandwich construction according to claim 1 wherein each of the first and second substrates is at least partially transparent.

8. A device according to claim 1 wherein each of the first and second substrates is about 25 to 50 microns thick.

9. A liquid crystal containing sandwich construction according to claim 1 wherein each of the first and second electrodes is formed of a material selected from the group consisting of chromium, indium oxide, tin oxide, stainless steel, indium tin oxide, gold, silver, copper, aluminum, titanium, cadmium stanate, and mixtures and alloys thereof.

10. A liquid crystal-containing sandwich construction according to claim 1 wherein each of the first and second substrates is a polyester or a copolyester.

11. A liquid crystal-containing sandwich construction according to claim 10 wherein each of the first and second substrates is about 25 to 50 microns thick.

12. A liquid crystal-containing sandwich construction according to claim 1 wherein the ultraviolet radiation polymerizable medium comprises materials that are selected from the group consisting of alkyl acrylates or methacrylates, acrylated or methacrylated polyurethanes, acrylated or methacrylated polyesters, acrylated or methacrylated polyols, acrylated or methacrylated polybutadienes, acrylated or methacrylated epoxies, and mixtures thereof.

13. A liquid crystal-containing sandwich construction according to claim 1 wherein the ultraviolet radiation polymerizable medium comprises (a) an allyl compound selected from the group consisting of monoallyl compounds, polyallyl compounds and mixtures thereof and (b) a polythiol selected from the group consisting of Z OCO(CH₂)_n SH!_m wherein Z=a polyvalent organic moiety which is a CH_0-3 group-containing nucleus of a tri- or tetravalent alcohol of the type of glycerol or pentaerythritol, m=3 or 4, and n=1 to 5.

14. A liquid crystal-containing sandwich construction according to claim 1 wherein the ultraviolet radiation polymerizable medium comprises (a) first material that comprises the reaction product of an allyl compound selected from the group consisting of monofunctional allyl compounds containing an hydroxyl group, multifunctional allyl compounds containing an hydroxyl group, and mixtures thereof and (2) a mono-or multifunctional isocyanate;

(b) a polythiol selected from the group consisting of Z OCO(CH₂)SH!_m wherein Z=a polyvalent organic moiety which is a CH_0-3 group-containing nucleus of a tri- or tetravalent alcohol of the type of glycerol or pentaerythritol, m=3 or 4, and n=1 to 5; and

(c) and an optional third material that is a mono-, di-, or triallyl functional compound that can react with the polythiol.

15. A liquid crystal-containing sandwich construction according to claim 1 wherein the ultraviolet polymerizable medium comprises (a) an acrylate compound selected from the group consisting of monofunctional acrylates, monofunctional methacrylates, multifunctional acrylates, multifunctional methacrylates, and mixtures thereof and (b) a polythiol selected from the group consisting of Z OCO(CH₂)_n SH!_m wherein Z=a polyvalent organic moiety which is a CH_0-3 group-containing nucleus of a tri- or tetravalent alcohol of the type of glycerol or pentaerythritol, m=3 or 4, and n=1 to 5.

16. A liquid crystal-containing sandwich construction according to claim 1 wherein the liquid crystal-containing layer further comprises a photoinitiator.

17. A liquid crystal-containing sandwich construction according to claim 1 wherein the ultraviolet radiation polymerizable medium comprises (a) a multifunctional allyl;

(b) a polythiol selected from the group consisting of Z OCO(CH₂)_m SH!_m wherein Z is a polyvalent organic moiety which is a CH_0-3 group-containing nucleus of a tri- or tetravalent alcohol of the type of glycerol or pentaerythritol, m=3 or 4, and n=1 to 5; and

(c) an acrylate selected from the group consisting of monofunctional acrylates, monofunctional methacrylates, and mixtures thereof.

18. A liquid crystal-containing sandwich construction according to claim 1 wherein the ultraviolet radiation polymerizable medium comprises (a) a multifunctional allyl;

(b) a polythiol selected from the group consisting of Z OCO(CH₂)_m SH!_m wherein Z is a polyvalent organic moiety which is a CH_0-3 group-containing nucleus of a tri- or tetravalent alcohol of the type of glycerol or pentaerythritol, m=3 or 4, and n=1 to 5;

(c) an acrylate selected from the group consisting of monofunctional acrylates, monofuctional methacrylates, and mixtures thereof; and

(d) a monoallyl.

19. A liquid crystal-containing sandwich construction according to claim 1 wherein the ultraviolet radiation polymerizable medium comprises (a) a multifunctional allyl;

(b) a polythiol selected from the group consisting of Z OCO(CH₂)_m SH!_m wherein Z is a polyvalent organic moiety which is a CH_0-3 group-containing nucleus of a tri- or tetravalent alcohol of the type of glycerol or pentaerythritol, m=3 or 4, and n=1 to 5; and

(c) an acrylate selected from the group consisting of multifunctional acrylates, multifunctional methacrylates, and mixtures thereof.

20. A liquid crystal-containing sandwich construction according to claim 1 wherein the ultraviolet radiation polymerizable medium comprises (a) a multifunctional allyl;

(b) a polythiol selected from the group consisting of Z OCO(CH₂)_m SH!_m wherein Z is a polyvalent organic moiety which is a CH_0-3 group-containing nucleus of a tri- or tetravalent alcohol of the type of glycerol or pentaerythritol, m=3 or 4, and n=1 to 5;

(c) an acrylate selected from the group consisting of multifunctional acrylates, multifunctional methacrylates, and mixtures thereof; and

(d) a monoallyl.

21. A liquid crystal-containing sandwich construction according to claim 1 wherein the ultraviolet radiation polymerizable medium comprises (a) a multifunctional allyl;

and (b) an acrylate selected from the group consisting of multifunctional acrylates, multifunctional methacrylates, and mixtures thereof.

22. A liquid crystal-containing sandwich construction according to claim 1 wherein the ultraviolet radiation polymerizable medium comprises (a) a multifunctional allyl;

and (b) an acrylate selected from the group consisting of monofunctional acrylates, monofunctional methacrylates, and mixtures thereof.

23. A liquid crystal-containing sandwich construction according to claim 1 wherein the ultraviolet radiation polymerizable medium comprises (a) a monofunctional allyl;

(b) a polythiol selected from the group consisting of Z OCO(CH₂)_m SH!_m wherein Z is a polyvalent organic moiety which is a CH_0-3 group-containing nucleus of a tri- or tetravalent alcohol of the type of glycerol or pentaerythritol, m=3 or 4, and n=1 to 5; and

(c) an acrylate selected from the group consisting of multifunctional acrylates, multifunctional methacrylates, and mixtures thereof.

24. A liquid crystal-containing sandwich construction according to claim 1 wherein the ultraviolet radiation polymerizable medium comprises (a) a monofunctional allyl;

(b) a polythiol selected from the group consisting of Z OCO(CH₂)_m SH!_m wherein Z is a polyvalent organic moiety which is a CH_0-3 group-containing nucleus of a tri- or tetravalent alcohol of the type of glycerol or pentaerythritol, m=3 or 4, and n=1 to 5; and

(c) an acrylate selected from the group consisting of monofunctional acrylates, monofunctional methacrylates, and mixtures thereof.

25. A liquid crystal-containing sandwich construction according to claim 1 wherein the sandwich construction has a thickness which does not exceed about 254 microns.

26. A liquid crystal-containing sandwich construction according to claim 1 wherein the liquid crystal-containing layer has a substantially equal thickness.

27. A liquid crystal-containing sandwich construction according to claim 1 wherein the liquid crystal-containing layer forms a polymer dispersed liquid crystal film of substantially equal thickness and comprising a multiplicity of droplets of a liquid crystal material dispersed in an ultraviolet radiation polymerized matrix when the liquid crystal-containing layer is subjected to ultraviolet radiation.

28. A flexible film construction comprising:

a first flexible, polymeric substrate having an electrode material on one major surface thereof,

a second flexible, polymeric substrate having an electrode material on one major surface thereof, the major surfaces of the first and second substrates having electrode material thereon being in a facing relationship;

wherein the first and second substrates are separated from each other only by a layer of liquid that is disposed between the major surfaces of the substrates having electrode material thereon, the layer of liquid comprising a liquid crystal material and an ultraviolet radiation polymerizable liquid.

29. A flexible film construction according to claim 28 wherein the layer of liquid is capable of forming a polymer dispersed liquid crystal film comprising a multiplicity of droplets of a liquid crystal material dispersed in an ultraviolet radiation polymerized matrix when subjected to ultraviolet radiation.

30. A flexible film construction according to claim 28 wherein the homogeneous liquid solution is capable of forming a polymer dispersed liquid crystal film comprising a multiplicity of droplets of a liquid crystal material dispersed in an ultraviolet radiation polymerized matrix when subjected to ultraviolet radiation.

31. A flexible film construction according to claim 28 wherein the film construction has a thickness which does not exceed about 254 microns.

32. A flexible film construction according to claim 28 wherein the layer of liquid has a substantially equal thickness.

33. A flexible film construction according to claim 28 wherein the layer of liquid forms a polymer dispersed liquid crystal film of substantially equal thickness and comprising a multiplicity of droplets of a liquid crystal material dispersed in an ultraviolet radiation polymerized matrix when the layer of liquid is subjected to ultraviolet radiation.

34. A flexible film construction comprising:

a first flexible, polymeric substrate having an electrode material on one major surface thereof;

a second flexible, polymeric substrate having an electrode material on one major surface thereof, the major surfaces of the first and second substrates having electrode material thereon being in a facing relationship; and

a homogeneous liquid solution disposed between the major surfaces of the first and second substrates having electrode material thereon, the homogeneous liquid solution comprising a liquid crystal material and an ultraviolet radiation polymerizable liquid;

wherein the film construction is free from mechanical spacers that separate the major surfaces of the first and second substrates and control the thickness of the homogeneous liquid solution therebetween.

35. A flexible film construction according to claim 34 wherein the film construction has a thickness which does not exceed about 254 microns.

36. A flexible film construction according to claim 34 wherein the layer of liquid has a substantially equal thickness.

37. A flexible film construction according to claim 34 wherein the layer of liquid forms a polymer dispersed liquid crystal film of substantially equal thickness and comprising a multiplicity of droplets of a liquid crystal material dispersed in an ultraviolet radiation polymerized matrix when the layer of liquid is subjected to ultraviolet radiation.

38. A film construction comprising:

a first flexible, polymeric substrate having an electrode material on one major surface thereof;

a second flexible, polymeric substrate having an electrode material on one major surface thereof, the major surfaces of the first and second substrates having electrode material thereon being in a facing relationship;

wherein the first and second substrates are separated from each other only by a layer of liquid that is disposed between the major surfaces of the substrates having electrode material thereon, the layer of liquid comprising a liquid crystal material and an ultraviolet radiation polymerizable liquid, and further wherein the film construction is not in fixed supportive contact with a rigid plate.

39. A film construction according to claim 38 wherein the film construction has a thickness which does not exceed about 254 microns.

40. A film construction according to claim 38 wherein the layer of liquid has a substantially equal thickness.

41. A film construction according to claim 38 wherein the layer of liquid forms a polymer dispersed liquid crystal film of substantially equal thickness and comprising a multiplicity of droplets of a liquid crystal material dispersed in an ultraviolet radiation polymerized matrix when the layer of liquid is subjected to ultraviolet radiation.

42. A film construction comprising:

a first flexible, polymeric substrate having an electrode material on one major surface thereof;

a second flexible, polymeric substrate having an electrode material on one major surface thereof, the major surfaces of the first and second substrates having electrode material thereon being in a facing relationship; and

a homogeneous liquid solution disposed between the major surfaces of the first and second substrates having electrode material thereon, the homogeneous liquid solution comprising a liquid crystal material and an ultraviolet radiation polymerizable liquid;

wherein the film construction is free from mechanical spacers that separate the major surfaces of the first and second substrates and control the thickness of the homogeneous liquid solution therebetween, and further wherein the film construction is not in fixed supportive contact with a rigid plate.

43. A film construction according to claim 42 wherein the film construction has a thickness which does not exceed about 254 microns.

44. A film construction according to claim 42 wherein the layer of liquid has a substantially equal thickness.

45. A film construction according to claim 42 wherein the layer of liquid forms a polymer dispersed liquid crystal film of substantially equal thickness and comprising a multiplicity of droplets of a liquid crystal material dispersed in an ultraviolet radiation polymerized matrix when the layer of liquid is subjected to ultraviolet radiation.

46. A method of preparing a light transmission device comprising:

(a) providing a liquid crystal-containing sandwich construction comprising;

a first flexible, polymeric substrate having an electrode material on one major surface thereof;

a second flexible, polymeric substrate having an electrode material on one major surface thereof, the major surfaces of the first and second substrates having electrode material thereon being in a facing relationship; and

a liquid crystal-containing layer comprising a liquid crystal material blended with an ultraviolet radiation polymerizable liquid medium, the layer being disposed between the major surfaces of the first and second substrates having electrode material thereon;

wherein the sandwich construction is free from mechanical spacers that would otherwise separate the major surfaces of the first and second substrates and control the thickness of the liquid crystal-containing layer therebetween; and

(b) exposing the liquid crystal-containing layer to ultraviolet radiation to form a polymer dispersed liquid crystal film of substantially equal thickness that comprises a multiplicity of droplets of liquid crystal material dispersed in an ultraviolet radiation polymerized matrix.