Multilayer film having a continuous and disperse phase

• US 5,867,316 A
• Filed: 02/29/1996
• Issued: 02/02/1999
• Est. Priority Date: 02/29/1996
• Status: Expired due to Term

• Current Assignee: 3M Company
• Original Assignee: 3M Company
• Inventors: Weber, Michael F., Ouderkirk, Andrew J., Nevitt, Timothy J., Stover, Carl A., Allen, Richard C., Majumdar, Biswaroop, Carlson, Lockwood W., Kotz, Arthur L.
• Primary Examiner(s): Spyrou, Cassandra C.
• Assistant Examiner(s): Juba, Jr., John
• Application Number:
  US08/609,753
• Time in Patent Office: 1,069 Days
• Field of Search: 359/492, 359/495, 359/500, 359/490, 359/491, 359/494
• US Class Current: 359/487.02
• CPC Class Codes: G02B 5/3008 comprising dielectric particles, e.g. birefringent crystals embedded in a matrix
• CPC Class Codes: G02B 5/305 including organic materials, e.g. polymeric layers
• CPC Class Codes: Y10S 359/90 Methods

Abstract

An optical film is provided which includes a disperse phase of polymeric particles disposed within a continuous birefringent matrix. The film is oriented, typically by stretching, in one or more directions. The size and shape of the disperse phase particles, the volume fraction of the disperse phase, the film thickness, and the amount of orientation are chosen to attain a desired degree of diffuse reflection and total transmission of electromagnetic radiation of a desired wavelength in the resulting film.

Claims

1. An optical body, comprising:

a polymeric first phase; and

a second phase, disposed within said first phase, which is discontinuous along at least two of any three mutually perpendicular axes;

wherein said first and second phases have indices of refraction which differ along a first axis by more than about 0.05, and which differ along a second axis orthogonal to said first axis by less than about 0.05;

wherein said first phase has a birefringence of at least about 0.1; and

wherein said optical body has a total reflectivity of greater than 50% for a first polarization of visible light and a total transmission of greater than 50% for a second polarization of visible light.

2. The optical body of claim 1, wherein said first phase has a birefringence of at least about 0.15.

3. The optical body of claim 1, wherein said second phase has a birefringence of less than about 0.02.

4. The optical body of claim 1, wherein said second phase has an index of refraction which differs from said first phase by more than about 0.1 along said first axis.

5. The optical body of claim 1, wherein said second phase has an index of refraction which differs from said first phase by more than about 0.15 along said first axis.

6. The optical body of claim 1, wherein said second phase has an index of refraction which differs from said first phase by more than about 0.2 along said first axis.

7. The optical body of claim 1, wherein at least about 40% of light polarized orthogonal to a first polarization of light is transmitted through said optical body with an angle of deflection of less than about 8°

.

8. The optical body of claim 1, wherein said first phase comprises a thermoplastic resin.

9. The optical body of claim 8, wherein said thermoplastic resin comprises polyethylene naphthalate.

10. The optical body of claim 9, wherein said second phase comprises syndiotactic polystyrene.

11. The optical body of claim 8, wherein said second phase also comprises at least one thermoplastic polymer.

12. The optical body of claim 1, wherein said optical body is stretched to a stretch ratio of at least about 2.

13. The optical body of claim 1, wherein said optical body is stretched to a stretch ratio of at least about 4.

14. The optical body of claim 1, wherein said optical body is oriented in at least two directions.

15. The optical body of claim 1, wherein said second phase is present in an amount of about 5% to about 50% by volume relative to said first phase.

16. The optical body of claim 1, wherein said second phase is present in an amount of about 15% to about 30% by volume relative to said first phase.

17. The optical body of claim 1, wherein the extinction ratio of said optical body is greater than about 3.

18. The optical body of claim 1, wherein the extinction ratio of said optical body is greater than about 10.

19. The optical body of claim 1, wherein said optical body is stretched in at least one direction, wherein at least about 40% of light polarized orthogonal to a first polarization of light is diffusely transmitted through said optical body, and wherein said diffusely transmitted rays are distributed primarily along or near the surface of a cone whose surface contains the spectrally transmitted direction and whose axis is centered on the stretch direction.

20. A polarizer, comprising:

a plurality of layers arranged in a repeating sequence of at least a first and second layer type;

wherein said first layer type comprises a strain-induced birefringent polymeric continuous phase and a polymeric disperse phase, disposed within said continuous phase;

wherein said polarizer diffusely reflects visible light of wavelength λ

polarized in a first direction and specularly transmits visible light of wavelength λ

polarized in a second direction;

wherein the disperse phase comprises a plurality of particles that are larger than about 2λ

in a first dimension and are larger than about λ

/30 but smaller than about λ

in a second and third dimension;

wherein the indices of refraction of the continuous and disperse phases differ by more than about 0.05 for electromagnetic radiation of wavelength λ

polarized along a first of three mutually orthogonal axes but differ by less than about 0.05 for electromagnetic radiation of wavelength λ

polarized along a second of three mutually orthogonal axes; and

wherein the diffuse reflectivity of the composition along at least one axis for at least one polarization of electromagnetic radiation of wavelength λ

is at least about 30%.

21. The polarizer of claim 20, wherein the composition is oriented until the diffuse reflectivity of the composition toward the first polarization electromagnetic radiation of wavelength λ

is greater than about 50%.

22. The polarizer of claim 20, wherein the plurality of particles are larger than about 4λ

in the first dimension.

23. The polarizer of claim 20, wherein the plurality of particles are smaller than about 0.5λ

in at least one of the second and third dimensions.

24. The polarizer of claim 20, wherein the plurality of particles are smaller than about 0.5λ

in both of the second and third dimensions.

25. The polarizer of claim 20, wherein λ

is in the visible region of the spectrum.

26. The polarizer of claim 20, wherein said disperse phase is essentially randomly distributed throughout said continuous phase.

27. The polarizer of claim 20, wherein said continuous phase comprises a polyester.

28. The polarizer of claim 20, wherein said repeating sequence has at least a first, second, and third layer type.

29. The polarizer of claim 20, wherein said disperse phase is present in an amount within the range of about 15% to about 30% by volume relative to said continuous phase.

30. The polarizer of claim 20, wherein said first layer type further comprises a compatibilizer.

31. The polarizer of claim 20, wherein said disperse phase has a core and shell construction.

32. The polarizer of claim 20, wherein said disperse phase comprises a plurality of particles having essentially elliptical cross-sections.

33. The polarizer of claim 20, wherein said continuous and disperse phases have indices of refraction which differ by less than about 0.05 for visible light polarized along a first axis, and which differ by more than about 0.05 for visible light polarized along a second axis.

34. The polarizer of claim 20, wherein said polarizer has a total diffuse reflectivity of at least 30% for visible light.

35. A polarizer, comprising:

a plurality of layers, each of said layers comprising a polymeric first phase having a birefringence of at least about 0.05, and a polymeric second phase, disposed within said first phase, which is discontinuous along at least two of any three mutually perpendicular axes;

wherein said first and second phases have indices of refraction which differ along a first axis by more than about 0.05, and which differ along a second axis orthogonal to said first axis by less than about 0.05.

36. The polarizer of claim 35, wherein said plurality of layers comprise a first layer and a second layer contiguous to said first layer.

37. The polarizer of claim 35, wherein said first and second phases have indices of refraction which differ by less than about 0.05 for visible light polarized along a first axis, and which differ by more than about 0.05 for visible light polarized along a second axis.

38. The polarizer of claim 35, wherein said polarizer has a total diffuse reflectivity of at least 30% for visible light.

39. The polarizer of claim 35, wherein said disperse phase is present in an amount within the range of about 15% to about 30% by volume relative to said continuous phase.

40. The polarizer of claim 35, wherein said second phase is essentially randomly distributed throughout said continuous phase.

41. A polarizer, comprising:

a continuous phase having a birefringence of at least about 0.05; and

a disperse phase, disposed within said continuous phase;

wherein said continuous and disperse phases comprise first and second diverse thermoplastic polymers, respectively;

wherein said first polymer is a polyester; and

wherein said continuous and disperse phases have indices of refraction which differ by more than about 0.05 for visible light polarized along a first axis, and which differ by less than about 0.05 for visible light polarized along a second axis.

42. The polarizer of claim 41, wherein said continuous phase has a birefringence of at least about 0.1.

43. The polarizer of claim 41, wherein said disperse phase has a birefringence of less than about 0.01.

44. The polarizer of claim 41, wherein said first and second axes are mutually orthogonal.

45. The polarizer of claim 41, wherein said disperse phase is present in an amount of at least about 1% by volume relative to said continuous phase.

46. The polarizer of claim 41, wherein said disperse phase is present in an amount within the range of 5% to 50% by volume relative to said continuous phase.

47. The polarizer of claim 41, wherein said disperse phase is present in an amount within the range of about 15% to about 30% by volume relative to said continuous phase.

48. The polarizer of claim 41, wherein said polarizer has a total reflectivity of greater than about 70% for visible light polarized along said first axis and a total transmission of greater than about 70% for visible light polarized along said second axis.

49. The polarizer of claim 41, wherein said first and second axes are in-plane axes, and wherein said continuous and disperse phases have indices of refraction which differ by less than about 0.05 for visible light polarized along a third axis which is perpendicular to said first and second axes.

50. The polarizer of claim 41, further comprising a compatibilizer.

51. The polarizer of claim 41, wherein said second polymer is a polyester.

52. The polarizer of claim 41, wherein at least one of said first and second polymers is a naphthalene dicarboxylic acid polyester.

53. The polarizer of claim 52, wherein said naphthalene dicarboxylic acid polyester is polyethylene naphthalate.

54. The polarizer of claim 53, wherein said second polymer is polystyrene.

55. The polarizer of claim 53, wherein at least one of said first and second polymers is syndiotactic polystyrene.

56. The polarizer of claim 55, wherein said syndiotactic polystyrene contains at least 4% of para-methylstyrene units.

57. The polarizer of claim 53, wherein at least one of said first and second polymers is polymethylmethacrylate.

58. The polarizer of claim 41, wherein at least one of said first and second polymers is a terephthalic acid polyester.

59. The polarizer of claim 58, wherein said terephthalic acid polyester is polyethylene terephthalate.

60. The polarizer of claim 41, wherein said second polymer is polystyrene.

61. The polarizer of claim 60, wherein said polystyrene is syndiotactic polystyrene.

62. The polarizer of claim 41, wherein at least one of said first and second polymers is polymethylmethacrylate.

63. The polarizer of claim 41, wherein at least one of said first and second polymers is an ionomer.

64. The polarizer of claim 41, wherein at least one of said first and second polymers is a copolymer based on naphthalene dicarboxylate, dimethylisophthalate, and ethylene glycol.

65. The polarizer of claim 41, wherein at least one of said first and second polymers is a copolymer based on cyclohexane dicarboxylate, polytetramethylene ether glycol, and cyclohexanedimethanol.

66. The polarizer of claim 41, wherein at least one of said first and second polymers is a copolymer based on interpolymerized units derived from terephthalic acid and naphthalene dicarboxylic acid.

67. The polarizer of claim 41, wherein at least one of said first and second polymers is crosslinked.

68. The polarizer of claim 41, wherein said disperse phase has a core-and-shell construction.

69. The polarizer of claim 41, wherein said polarizer further comprises a dichroic dye.

70. A polarizer, comprising:

a continuous phase having a birefringence of at least about 0.05;

a disperse phase, disposed within said continuous phase; and

a compatibilizer;

wherein said continuous and disperse phases comprise first and second diverse thermoplastic polymers, respectively; and

wherein said continuous and disperse phases have indices of refraction which differ by more than about 0.05 for visible light polarized along a first axis, and which differ by less than about 0.05 for visible light polarized along a second axis.

71. The polarizer of claim 70, wherein said compatibilizer is a block copolymer containing interpolymerized units of at least one of said first and second polymers.

72. The polarizer of claim 71, wherein said first polymer is polyethylene naphthalate, said second polymer is polystyrene, and said compatibilizer is polystyrene glycidyl methacrylate.

73. The polarizer of claim 72, wherein said polystyrene is syndiotactic polystyrene.

74. The polarizer of claim 70, wherein said compatibilizer is present in an amount of at least about 0.05% by weight based on the total weight of said continuous phase, said disperse phase, and said compatibilizer.

75. The polarizer of claim 70, wherein said compatibilizer is present in an amount of about 2% to about 6% by weight based on the total weight of said continuous phase, said disperse phase, and said compatibilizer.

76. A polarizer, comprising:

a continuous phase comprising a syndiotactic vinyl aromatic polymer; and

a disperse phase, disposed within said continuous phase;

wherein said continuous and disperse phases have indices of refraction which differ by more than about 0.05 for visible light polarized along a first axis, and which differ by less than about 0.05 for visible light polarized along a second axis orthogonal to said first axis.

77. The polarizer of claim 76, wherein said syndiotactic vinyl aromatic polymer is syndiotactic polystyrene.

78. The polarizer of claim 77, wherein said disperse phase is polyethylene naphthalate.

79. The polarizer of claim 78, wherein said polyethylene naphthalate has an intrinsic viscosity of between about 0.42 and about 0.56.

80. A polarizer, comprising:

a continuous phase comprising a naphthalene dicarboxylic acid polyester; and

a disperse phase, disposed within said continuous phase;

wherein said continuous and disperse phases have indices of refraction which differ by more than about 0.05 for visible light polarized along a first axis, and which differ by less than about 0.05 for visible light polarized along a second axis orthogonal to said first axis.

81. The polarizer of claim 80, wherein said naphthalene dicarboxylic acid is polyethylene naphthalate and has an intrinsic viscosity within the range of about 0.42 to about 0.56.

82. An optical body, comprising:

a biaxially oriented polymeric continuous phase; and

a disperse phase, disposed within said continuous phase;

wherein said continuous and disperse phases have indices of refraction which differ along a first axis by more than about 0.05, and which differ along a second axis orthogonal to said first axis by less than about 0.05.

83. A polarizing film, comprising:

a polymeric continuous phase; and

a disperse phase, disposed within said continuous phase;

wherein said continuous and disperse phases have indices of refraction which differ by less than about 0.05 for visible light polarized along a first axis and which differ by more than about 0.05 for visible light polarized along a second axis; and

wherein said first axis is perpendicular to the plane of said film.

84. An optical body, comprising:

a continuous phase having a birefringence of at least about 0.05; and

a disperse phase, disposed within said continuous phase;

wherein said continuous and disperse phases comprise first and second diverse thermoplastic polymers, respectively;

wherein said continuous and disperse phases have indices of refraction which differ by more than about 0.05 for visible light polarized along first and second in-plane axes; and

wherein said optical body has a total reflectivity of greater than about 50% for visible light polarized along said first and second axes.

85. The optical body of claim 84, wherein said optical body has a total diffuse reflectivity of at least 30% for visible light.

86. The optical body of claim 84, wherein said continuous phase comprises a syndiotactic vinyl aromatic polymer.

87. The optical body of claim 84, wherein said continuous phase comprises syndiotactic polystyrene.

88. The optical body of claim 84, wherein said continuous and disperse phases have indices of refraction which differ by less than about 0.05 for visible light polarized along a third axis which is orthogonal to said first and second in-plane axes.

89. The optical body of claim 84, wherein said continuous and disperse phases have indices of refraction which differ by less than about 0.02 for visible light polarized along a third axis which is orthogonal to said first and second in-plane axes.

90. An optical body, comprising:

a polymeric first phase; and

a second phase, disposed within said first phase, which is discontinuous along at least two of any three mutually perpendicular axes;

wherein said first and second phases have indices of refraction which differ by more than about 0.05 for visible light polarized along a first axis, and which differ by less than about 0.05 for visible light polarized along a second axis orthogonal to said first axis;

wherein said first phase has a birefringence of at least about 0.1; and

wherein at least about 40% of visible light polarized along said second axis is transmitted through said optical body with an angle of deflection of less than about 8°

.

91. The optical body of claim 90, wherein said first and second phases are thermoplastic polymers.

92. The optical body of claim 90, wherein said first phase is a polyester.

93. The optical body of claim 90, wherein at least about 60% of visible light polarized along said second axis is transmitted through said optical body with an angle of deflection of less than about 8°

.

94. The optical body of claim 90, wherein at least about 70% of visible light polarized along said second axis is transmitted through said optical body with an angle of deflection of less than about 8°

.