Defogging article and method of producing same

• US 5,869,187 A
• Filed: 02/28/1997
• Issued: 02/09/1999
• Est. Priority Date: 03/07/1996
• Status: Expired due to Fees

• Current Assignee: Nissan Motor Co., Ltd.
• Original Assignee: Nissan Motor Co., Ltd.
• Inventors: Nakamura, Ichiro, Kai, Yasuaki, Sugawara, Satoko
• Primary Examiner(s): Turner, A. A.
• Application Number:
  US08/807,035
• Time in Patent Office: 711 Days
• Field of Search: 428/457, 428/469, 428/472, 428/428, 428/432, 428/697, 428/699, 428/701, 428/702, 427/164, 427/162, 427/372.2, 427/375, 427/376.1, 427/376.2
• US Class Current: 428/428
• CPC Class Codes: C03C 17/256 Coating containing TiO2
• CPC Class Codes: C03C 2217/212 TiO2
• CPC Class Codes: C03C 2217/23 Mixtures
• CPC Class Codes: C03C 2218/113 by sol-gel processes

Abstract

A defogging article having a defogging coating formed on a substrate such as a glass plate, a mirror, a metal article, or a plastic article. The defogging coating includes titania, and at least one oxide selected from the group consisting of P₂ O₅, B₂ O₃, boehmite, γ-Al₂ O₃, and SiO₂ --Al₂ O₃ based oxide. The defogging coating contains the at least one oxide other than titania, in an amount ranging from 0.1 to 50% by weight.

Claims

1. A defogging article comprising:

a substrate; and

a defogging coating formed on a surface of said substrate, said defogging coating including titania, and at least one oxide selected from the group consisting of P₂ O₅, B₂ O₃, boehmite, γ

-Al₂ O₃, and SiO₂ --Al₂ O₃ based oxide, said defogging coating containing said at least one oxide other than titania, in an amount ranging from 0.1 to 50% by weight, whereby a first surface of said defogging coating is exposed to and in direct contact with the air, and a second surface of said defogging coating that is opposite said first surface faces said substrate.

2. A defogging article as claimed in claim 1, wherein said SiO₂ --Al₂ O₃ based oxide contains Al₂ O₃ in an amount ranging from 15 to 40% by weight.

3. A defogging article as claimed in claim 1, wherein said defogging coating includes at least one substance selected from the group consisting of metal and electrically conductive metal oxide, said at least one substance being contained in said defogging coating.

4. A defogging article as claimed in claim 1, wherein said defogging coating includes at least one substance selected from the group consisting of metal and electrically conductive metal oxide, said at least one substance being carried on a surface of said defogging coating.

5. A defogging article as claimed in claim 3, wherein said metal is at least one metal selected from the group consisting of at least one selected from the group consisting of gold, silver, copper, zinc, platinum, palladium, rhodium, vanadium, chromium, manganese, iron, cobalt, ruthenium, nickel, niobium and tin.

6. A defogging article as claimed in claim 3, wherein said electrically conductive metal oxide is at least one metal oxide selected from the group consisting of SnO₂, ZnO, WO₃ and ITO (indium-tin oxide).

7. A defogging article as claimed in claim 1, further comprising an intermediate layer disposed between said substrate and said defogging coating, said intermediate layer including at least one oxide selected from the group consisting of SiO₂, TiO₂, ZrO₂, Al₂ O₃, SnO₂ nd ITO (indium-tin oxide) and ZnO.

8. A defogging article as claimed in claim 1, wherein said defogging coating includes at least one metal oxide selected from the group consisting of iron titanate, iron oxide, bismuth oxide, molybdenum oxide, nickel oxide, silica, yttrium oxide, manganese oxide, cobalt oxide, copper oxide, chromium oxide, and zirconium oxide.

10. A method of producing a defogging article as claimed in claim 1, comprising:

coating a liquid containing titania and at least one compound which corresponds to at least one oxide selected from the group consisting of P₂ O₅, B₂ O₅, boehmite, γ

-Al₂ O₃ and SiO₂ --Al₂ O₃ a based oxide, upon being fired, on a surface of a substrate to form a coating layer, the liquid coating step including controlling the amount of said titania and said at least one compound such that said at least one oxide other than said titania is contained in a defogging coating in an amount of 0.1 to 50% by weight upon being fired; and

firing said coating layer at a temperature ranging from 300°

to 850°

C. to form said defogging coating on the substrate.

11. A method of producing a defogging article as claims in claim 1, comprising:

preparing a sol containing titania and at least one compound which corresponds to at least one oxide selected from the group consisting of P₂ O₅, B₂ O₃, boehmite, γ

-Al₂ O₃, and SiO₂ --Al₂ O₃ based oxide, upon being fired, said preparing including controlling the amount of said titania and said at least one compound such that said at least one oxide other than said titania is contained in a defogging coating in an amount of 0.1 to 50% by weight upon being fired;

coating said sol on a surface of a substrate; and

firing said coating layer at a temperature ranging from 300°

to 850°

C. to form said defogging coating on the substrate.

12. A method as claimed in claim 11, further comprising the step of adding at least one organic polymer selected from the group consisting of polyethylene glycol and polytetrafluoroethylene to said sol.

9. A defogging glass plate comprising:

a glass plate; and

a defogging coating formed on a surface of said glass plate, said defogging coating including titania, and at least one oxide selected from the group consisting of P₂ O₅, B₂ O₃, boehmite, γ

-Al₂ O₃, and SiO₂ --Al₂ O₃ based oxide, said defogging coating containing said at least one oxide other than titania, in an amount ranging from 0.1 to 50% by weight, whereby a first surface of said defogging coating is exposed to and in direct contact with the air, and a second surface of said defogging coating that is opposite said first surface faces said glass plate.

13. A method of producing a defogging glass plate as claimed in claim 9, comprising:

coating a liquid containing titania and at least one compound which corresponds to at least one oxide selected from the group consisting of P₂ O₅, B₂ O₃, boehmite, γ

-Al₂ O₃, and SiO₂ --Al₂ O₃ based oxide upon being fired, on a surface of a glass plate to form a coating layer, the liquid coating steps including controlling the amount of said titania and said at least one compound such that said at least one oxide other than said titania is contained in a defogging coating in an amount of 0.1 to 50% by weight upon being fired; and

firing said coating layer at a temperature ranging from 300°

to 850°

C. to form said defogging coating on the substrate.