Process for the polymerization of alpha olefins using a new aluminophosphate support

• US 5,869,587 A
• Filed: 10/31/1996
• Issued: 02/09/1999
• Est. Priority Date: 10/31/1996
• Status: Expired due to Fees

• Current Assignee: Chevron Chemical Company (Chevron Corp.)
• Original Assignee: Chevron Chemical Company (Chevron Corp.)
• Inventors: Pecoraro, Theresa A., Auburn, Pamela R.
• Primary Examiner(s): Zitomer, Fred
• Application Number:
  US08/741,595
• Time in Patent Office: 831 Days
• Field of Search: 502/208, 502/439, 526/226, 526/233, 526/348, 526/348.5, 526/348.6, 526/348.7, 526/351, 526/352
• US Class Current: 526/233
• CPC Class Codes: B01J 23/26 Chromium
• CPC Class Codes: B01J 27/16 containing oxygen , i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
• CPC Class Codes: B01J 37/036 to form a gel or a cogel
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 4/025 Metal oxides
• CPC Class Codes: C08F 4/24 Oxides

Abstract

Novel catalysts are provided for the polymerization of olefins such as ethylene. These catalysts comprise a novel amorphous aluminophosphate comprising, on a microlevel, sheets of aluminophosphate as well as spheres of aluminophosphate plus a chromium compound. These new catalysts are surprisingly active; result in more co-monomer incorporation than prior art catalysts and reduce the amount of low molecular weight material in the product.

Claims

1. A polymerization process comprising:

contacting at least one mono-1-olefin having from 2 to 8 carbon atoms per molecule inclusive under polymerization reaction conditions in a polymerization reaction zone with a catalyst comprising an active catalytic component on an aluminophosphate support PREPARED FROM AQUEOUS SOLUTIONS OF ALUMINUM AND PHOSPHORUS IONS, and wherein the phosphorous to aluminum mole ratio of said aluminophosphate is less than one, said aluminophosphate being further characterized as (a) amorphous and (b) having, on a microlevel, sheets of aluminophosphate as well as spheres of aluminophosphate, and recovering a polymer.

2. A process according to claim 1 wherein said catalytic component comprises a chromium component on the aluminophosphate support.

3. A process according to claim 1 wherein said at least one mono-1-olefin is selected from ethylene, propylene;

butene-1;

hexene-1 and octene-1.

4. A process according to claim 3 wherein said at least one mono-1-olefin comprises ethylene and from 0.5 to 2 mole percent of one additional mono-1-olefin selected from propylene;

butene-1, hexene-1 and octene-1.

5. A process according to claim 2 wherein the phosphorus to aluminum mole ratio is from 0.2:

1 to 0.8;

1.

6. A process according to claim 3 wherein said aluminophosphate has a macropore volume of at least 0.1 cc'"'"'s per gram.

7. A process according to claim 3 wherein said aluminophosphate has a fragmentation potential of at least 30.

8. A process according to claim 7 wherein said aluminophosphate has a macropore volume of at least 0.1 cc'"'"'s per gram.

9. A process according to claim 8 wherein said catalytic component comprises a chromium component on the aluminophosphate support.

10. A process according to claim 1 wherein the N_L in a photomicrograph at about 12,000×

magnification is from 0.1 to 3 micron^-1.