Multi-functional multilayer device and method for making

• US 5,870,273 A
• Filed: 09/22/1997
• Issued: 02/09/1999
• Est. Priority Date: 10/18/1996
• Status: Expired due to Fees

• Current Assignee: TDK Corporation
• Original Assignee: TDK Corporation
• Inventors: Sogabe, Tomohiro, Enokido, Yasushi
• Primary Examiner(s): Ledynh, Bot L.
• Assistant Examiner(s): Dinkins, Anthony
• Application Number:
  US08/935,135
• Time in Patent Office: 505 Days
• Field of Search: 361/306.3, 361/305, 361/307, 361/308, 361/309, 361/311-313, 361/321.1, 361/321.2, 361/321.4, 361/321.5, 361/322, 338/20, 338/21, 333/181, 333/184
• US Class Current: 361/306.3
• CPC Class Codes: H01C 7/112 ZnO type
• CPC Class Codes: H01G 4/40 Structural combinations of fixed capacitors with other electric elements, the structure mainly consisting of a capacitor, e.g. RC combinations

Abstract

In a multi-functional multilayer device including a body (10) having a varistor section (2) and a capacitor section (3) stacked and integrated therewith, the adhesion between a varistor layer and a dielectric layer is improved when the varistor layer (22) contains zinc oxide as a main component and at least one lanthanide oxide as an auxiliary component, and the dielectric layer (32) contains titanium oxide or lanthanum/titanium oxide as a main component. The device experiences little warpage upon firing when glass is added to the dielectric layer. A high resistivity intermediate layer (5) disposed between the varistor and capacitor sections (2 and 3) prevents the deterioration or loss of varistor and capacitor properties by interdiffusion of elements between the varistor and capacitor sections.

Claims

1. A multi-functional multilayer device comprising a body having a varistor section and a capacitor section disposed thereon and a pair of terminal electrodes formed on outer surfaces of said body, wherein

said varistor section includes at least one varistor layer interleaved between said internal plates,

said capacitor section includes at least one dielectric layer interleaved between internal plates,

said varistor section and said capacitor section are electrically connected in parallel by said pair of terminal electrodes,

said varistor layer contains zinc oxide as a main component and at least one lanthanide oxide as an auxiliary component, and

said dielectric layer contains titanium oxide or an oxide containing lanthanum and titanium as a main component.

2. The device of claim 1 wherein said dielectric layer further contains glass.

3. The device of claim 2 wherein said dielectric layer contains 0.1 to 5% by weight of glass.

4. The device of claim 1 wherein said dielectric layer further contains manganese oxide.

5. The device of claim 4 wherein said dielectric layer contains 0.1 to 3% by weight of manganese oxide.

6. The device of claim 1 further comprising an intermediate layer between said varistor section and said capacitor section, said intermediate layer having a resistivity which is higher than the lower one of the resistivity of said varistor layer and the resistivity of said dielectric layer.

7. The device of claim 6 wherein said intermediate layer contains at least one oxide selected from the group consisting of zinc oxide, lanthanide oxide, titanium oxide, an oxide containing lanthanum and titanium, and mixtures thereof.

8. The device of claim 7, wherein said oxide contained in said intermediate layer is a main component.

9. The device of claim 1 wherein an internal plate of said varistor section and an internal plate of said capacitor section which are disposed adjacent to each other via an interface between said varistor section and said capacitor section are connected so as to receive an equal potential.

10. A method for preparing a multi-functional multilayer device according to claim 1, comprising the steps of:

forming a green body comprising a green sheet containing a raw material powder of the varistor layer and another green sheet containing a raw material powder of the dielectric layer and

firing the green body in an atmosphere having an oxygen concentration higher than the oxygen concentration of air in

a temperature range of higher than 700°

C.

11. The device of claim 7, wherein said oxide contained in said intermediate layer comprises an oxide selected from the group consisting of ZnO, TiO₂, and La₂ Ti ₂ O₇, and mixtures thereof.

12. The device of claim 11, wherein said oxide contained in said intermediate layer comprises ZnO as a main component and an oxide selected from the group consisting of TiO₂ and La₂ Ti₂ O₇, and mixtures thereof.