Hydrophilic coating of surfaces of polymeric substrates

• US 5,871,823 A
• Filed: 06/09/1997
• Issued: 02/16/1999
• Est. Priority Date: 06/19/1996
• Status: Expired due to Fees

• Current Assignee: Huels Aktiengesellschaft
• Original Assignee: Huels Aktiengesellschaft
• Inventors: Lorenz, Guenter, Klee, Doris, Anders, Christine, Hoecker, Hartwig
• Primary Examiner(s): PIANALTO, BERNARD D
• Application Number:
  US08/871,551
• Time in Patent Office: 617 Days
• Field of Search: 427/491, 427/512, 427/508, 427/536, 427/558, 427/322, 427/393.5, 427/559
• US Class Current: 427/512
• CPC Class Codes: C08J 7/18 using wave energy or particle radiation

Abstract

A hydrophilic coating on a polymeric substrate is prepared by subjecting at least one hydrophilic vinyl monomer to radiation-induced graft polymerization on an activated substrate surface.

Claims

1. A process for producing a hydrophilic coating on a polymer substrate comprising:

(a) activating the polymer substrate by exposure to monochromatic, continuous UV radiation in the presence of oxygen and of a wavelength sufficient to provide hydroperoxide groups on the substrate;

(b) immersing said activated substrate in a solution of at least one hydrophilic group-containing vinyl monomer; and

(c) subjecting the immersed, activated substrate to monochromatic, continuous UV radiation of a wavelength sufficient to dissociate said hydroperoxide groups and induce graft copolymerization of the vinyl monomer onto the substrate.

2. The process as claimed in claim 1, wherein the hydrophilic vinyl monomer has a solubility in water at 20°

C. of at least 10 g/l.

3. The process as claimed in claim 1, wherein the hydrophilic vinyl monomer is acrylic acid or an acrylic acid derivative, methacrylic acid or a methacrylic acid derivative, a carboxylic acid vinyl derivative, a vinylsulfonic acid or a vinylsulfonic salt, an alkenylarylsulfonic acid or an alkenylarylsulfonic acid salt, a vinyl ether, vinyl ketone or vinylamine, a polyalkyleneoxy compound with (a) terminal allyl, vinyl, acryl or methacryl group(s) or a functionalized sugar derivative with (a) vinyl group(s).

4. The process as claimed in claim 1, wherein 2-hydroxyethyl methacrylate (HEMA) is the hydrophilic vinyl monomer.

5. The process as claimed in claim 1, wherein the polymeric substrate is a polyolefin, polyamide, polyether-block amide, polysulfone, polyvinyl chloride, polystyrene, polyurethane, polyorganosiloxane, polyester, polycarbonate, polyether, polyethylene, polypropylene, polyisoprene or polytetrafluoroethylene or a mixture of such polymers.

6. The process as claimed in claim 1 wherein residual monomers are removed from the hydrophilic coating produced by extraction with water and/or an organic solvent.

7. The process as in claim 1, wherein the activated substrate is exposed to oxygen for a period of about 1 to about 20 minutes before contacting with the vinyl monomer.

8. The process as in claim 1, wherein the solution in step (b) contains about 1% to about 40% by weight of the monomer.

9. A process as in claim 1 where the radiation in step (a) is of a wavelength of 125 to 172 nm and the radiation in step (c) is of a wavelength of 290 to 351 nm.

10. A process for producing a hydrophilic coating on a polymer substrate comprising:

(a) activating the polymer substrate by copolymerizing the monomer or monomers forming said substrate with a vinyl comonomer containing a group sensitive to UV radiation;

(b) immersing the activated substrate in a solution of at least one hydrophilic group-containing vinyl monomer; and

(c) subjecting the immersed, activated substrate to UV radiation to induce graft copolymerization of the vinyl monomer onto the substrate.

11. A process as in claim 10, wherein the vinyl comonomer in step (a) contains a furyl or cinnamoyl group.

12. A process as in claim 10, wherein the radiation in step (c) is UV radiation of a wavelength of about 250 to about 500 nm.