Electrochromic metal oxides

• US 5,876,633 A
• Filed: 09/26/1996
• Issued: 03/02/1999
• Est. Priority Date: 12/26/1995
• Status: Expired due to Fees

• Current Assignee: Monsanto Company (Bayer AG)
• Original Assignee: Monsanto Company (Bayer AG)
• Inventors: Coleman, James Patrick
• Primary Examiner(s): KOPEC, MARK T
• Application Number:
  US08/721,506
• Time in Patent Office: 887 Days
• Field of Search: 252/518.1, 252/520.1, 252/521.5, 428/402, 75/255, 420/557, 420/562
• US Class Current: 252/520.1
• CPC Class Codes: C09K 9/00 Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
• CPC Class Codes: C09K 9/02 Organic tenebrescent materials
• CPC Class Codes: G02F 1/1523 comprising inorganic material
• CPC Class Codes: H01B 1/08 oxides

Abstract

Tin oxide doped with an electrochemically effective amount of a metal, e.g., antimony or niobium, which provides a color change when the doped tin oxide is exposed to an electrochemical potential in the presence of mobile ions. Particles of electrochromic doped tin oxide, e.g., coated on a white or pastel pigment substrate, have a contrast ratio greater than 1.2, where contrast ratio is a measure of electrochromic functionality of a material and is the ratio of reflectance of the material in an oxidized state to the color of the material in a reduced state and where color is a photodiode measurement of the value of light reflected off the oxidized or reduced material from a constant source of light shining on the material. Such doped tin oxide-containing particles are useful as electrochromic material in display devices, and may be employed in display devices that advantageously exhibit a linear or nearly linear relationship between stored electrical charge and voltage, and which also exhibit linear or nearly linear optical characteristics as a function of voltage. Electrochromically active materials made from metal oxides and doped with substances other than antimony and niobium have also been found with high contrast ratios. These additional doped materials may be substituted for electrochromically active antimony-doped tin oxide in electrochromic displays.

Claims

1. A particle comprising an electrochromically activated doped metal oxide, said doped metal oxide being electrically conductive in an electrochromically unactivated state, and said activated, doped metal oxide electrochromically exhibiting a contrast ratio greater than 1.2 in comparison to the doped metal oxide in the electrochromically unactivated state.

2. A particle according to claim 1, said particle having been exposed to ion transfer in the presence of an electrochemical potential sufficient to cause a redox change in said particle, and further wherein said doped metal oxide comprises fluorine-doped tin oxide comprising an electrochemically effective amount of dopant providing a color change upon occurrence of the redox change.

3. A particle according to claim 1, wherein the metal oxide comprises indium oxide.

4. A particle according to claim 3, wherein said indium oxide is doped with tin.

5. A particle according to claim 4, wherein said particle comprises dried, co-precipitated indium and tin oxides.