Multicolor interference coating

• US 5,877,895 A
• Filed: 03/20/1995
• Issued: 03/02/1999
• Est. Priority Date: 03/20/1995
• Status: Expired due to Term

• Current Assignee: Presstek Incorporated (MAI Holdings, Inc.)
• Original Assignee: Catalina Coatings Incorporated
• Inventors: Langlois, Marc, Shaw, David G., Cline, Daniel S., Dawson, Eric P.
• Primary Examiner(s): YOON, TAE H
• Application Number:
  US08/406,566
• Time in Patent Office: 1,443 Days
• Field of Search: 359/584, 359/585, 359/586, 359/588, 428/463
• US Class Current: 359/588
• CPC Class Codes: B42D 2035/24 Colours
• CPC Class Codes: B42D 25/29 Securities; Bank notes
• CPC Class Codes: G02B 5/28 Interference filters
• CPC Class Codes: G02B 5/286 having four or fewer layers, e.g. for achieving a colour effect
• CPC Class Codes: G02B 5/287 comprising at least one layer of organic material
• CPC Class Codes: G06K 19/06046 Constructional details
• CPC Class Codes: G06K 2019/06225 using wavelength selection, e.g. colour code
• CPC Class Codes: Y10T 428/31699 Ester, halide or nitrile of addition polymer

Abstract

Several techniques may be used for forming a colored interference filter coating on a substrate such as polyester film. The interference filter has two metal reflective films, at least one of which is semi-transparent. A layer of transparent acrylate polymer dielectric between the metal layers completes the interference filter, which may be sandwiched between protective layers. The dielectric is formed by evaporating an acrylate monomer having a molecular weight in the range of from 150 to 600. Preferably the acrylate monomer has a molecular weight to acrylate group ratio in the range of from 150 to 400. The acrylate condenses on the substrate and is polymerized in situ for forming a monolithic film with a sufficient thickness to produce an interference color. In several embodiments different areas of the film have different thicknesses for producing different interference colors. The thickness of the dielectric can be controlled by the amount of monomer condensed, by either controlling the temperature of the condensation surface or controlling the amount of monomer evaporated adjacent a predetermined area of the substrate. Thickness may also be controlled by condensing a uniform layer of monomer and polymerizing the monomer to different degrees for varying the shrinkage of the film and hence the thickness of the film and color.

Claims

1. An interference color filter comprising:

a first at least partially reflective and partially transparent layer;

an evaporated, condensed and crosslinked transparent acrylate layer on the at least partially reflective layer having a molecular weight to acrylate group ratio in the range of from 150 to 400, the acrylate layer having a thickness sufficient for producing an interference color; and

a second at least partially reflective layer on the opposite face of the acrylate layer from the first reflective layer; and

wherein the filter is broken up to form colored pigment flakes.

2. An interference color filter as recited in claim 1 wherein one of the reflective layers comprises a substantially completely reflective metal.

3. An interference color filter as recited in claim 1 further comprising a protective layer of crosslinked acrylate covering at least one of the reflective layers.

4. An interference color filter as recited in claim 1 wherein both reflective layers are semi-reflective.

5. An interference color filter comprising:

a first evaporated, condensed and crosslinked transparent acrylate layer having a molecular weight per acrylate group in the range of from 150 to 400, the acrylate layer having a thickness sufficient for producing an interference color;

an at least partially reflective layer on one face of the acrylate layer; and

a second evaporated, condensed and crosslinked transparent acrylate layer having a molecular weight per acrylate group in the range of from 150 to 400, the acrylate layer having a thickness sufficient for producing an interference color; and

wherein the filter is broken up to form colored pigment flakes.

6. A reflective flake pigment comprising:

a first crosslinked transparent acrylate layer having a molecular weight per acrylate group in the range of from 150 to 400;

a reflective metal layer on one face of the acrylate layer; and

a second crosslinked transparent acrylate layer having a molecular weight per acrylate group in the range of from 150 to 400.

7. An interference color filter comprising:

a first crosslinked transparent acrylate layer having a molecular weight per acrylate group in the range of from 150 to 400;

a first at least partially reflective layer on one face of the acrylate layer;

a second crosslinked transparent acrylate layer having a molecular weight per acrylate group in the range of from 150 to 400, the acrylate layer having a thickness sufficient for producing an interference color;

a second at least partially reflective layer over the second acrylate layer; and

a third crosslinked transparent acrylate layer having a molecular weight per acrylate group in the range of from 150 to 400 over the second reflective layer; and

wherein the filter is broken up to form colored pigment flakes.

8. An interference color filter comprising:

a first at least partially reflective and partially transparent layer;

an evaporated condensed and crosslinked transparent acrylate layer on the at least partially reflective layer having a molecular weight to acrylate group ratio in the range of from 150 to 400, the acrylate layer having a thickness in the range of from 800 to 4000 Å

ngstroms for producing an interference color; and

a second at least partially reflective layer on the opposite face of the acrylate layer from the first reflective layer.

9. A multiple color interference filter comprising:

a substrate; and

a monolithic acrylate polymer film deposited on the substrate with a sufficient thickness for producing interference color, a predetermined area of the acrylate film having a first thickness and a second area of the acrylate film adjacent to the predetermined area having a second thickness different from the thickness of the predetermined area.

10. A multiple color interference filter comprising:

a substrate; and

a monolithic acrylate polymer film deposited on the substrate with a sufficient thickness for producing interference color, a predetermined area of the acrylate film having a first degree of polymerization and a second area of the acrylate film adjacent to the predetermined area having a second degree of polymerization different from the polymerization of the predetermined area.