Ink jet printing process for desensitizing carbonless paper

• US 5,880,062 A
• Filed: 06/16/1993
• Issued: 03/09/1999
• Est. Priority Date: 06/16/1993
• Status: Expired due to Term

• Current Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Original Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Inventors: Winnik, Francoise M., Breton, Marcel P., Sanders, David J.
• Primary Examiner(s): Schwartz, Pamela R.
• Application Number:
  US08/078,533
• Time in Patent Office: 2,092 Days
• Field of Search: 503/205, 503/206, 503/201, 503/203, 347/98, 347/56, 347/105, 427/150, 427/152
• US Class Current: 503/201
• CPC Class Codes: B41M 5/128 Desensitisers; Compositions for fault correction, detection or identification of the layers
• CPC Class Codes: B41M 5/52 Macromolecular coatings

Abstract

Disclosed is a printing process which comprises (a) incorporating into a printing apparatus capable of generating ink jet images a carbonless paper set comprising a first sheet, a second sheet, and optional intermediate sheets situated between the first sheet and second sheet, wherein the first sheet comprises paper coated on one surface with a color former and the second sheet comprises paper coated on one surface with a color developer, and wherein, when the carbonless paper set is assembled, the surface of the first sheet coated with the color former is in contact with the surface of a sheet coated with the color developer and the surface of the second sheet coated with the color developer is in contact with the surface of a sheet coated with the color former; (b) incorporating into the printing apparatus an ink jet ink comprising water, an organic component, and a desensitizing agent capable of interacting either (i) with the color former so that the color former'"'"'s subsequent ability to interact with the color developer is reduced, or (ii) with the color developer so that the color developer'"'"'s subsequent ability to interact with the color former is reduced; and (c) causing droplets of the ink containing the desensitizing agent to be ejected in an imagewise pattern onto either (i) at least one surface of one sheet coated with the color former, or (ii) at least one surface of one sheet coated with the color developer.

Claims

1. A printing process which comprises (a) incorporating into a thermal ink jet printing apparatus having nozzles for containing ink a carbonless paper set comprising a first sheet, a second sheet, and optional intermediate sheets situated between the first sheet and second sheet, wherein the first sheet comprises paper coated on one surface with a color former and the second sheet comprises paper coated on one surface with a color developer, and wherein, when the carbonless paper set is assembled, the surface of the first sheet coated with the color former is in contact with the surface of a sheet coated with the color developer and the surface of the second sheet coated with the color developer is in contact with the surface of a sheet coated with the color former;

(b) incorporating into the printing apparatus a desensitizing material comprising water, an organic component, and a desensitizing agent capable of interacting either (i) with the color former so that the color former'"'"'s subsequent ability to interact with the color developer is reduced, or (ii) with the color developer so that the color developer'"'"'s subsequent ability to interact with the color former is reduced; and

(c) selectively heating the desensitizing material in the nozzles in an imagewise pattern, thereby causing droplets of the desensitizing material to be ejected in an imagewise pattern onto either (i) at least one surface of one sheet coated with the color former, or (ii) at least one surface of one sheet coated with the color developer.

2. A printing process according to claim 1 wherein the desensitizing material contains a desensitizing agent selected from the group consisting of ##STR6## wherein X is a divalent aliphatic or cycloaliphatic radical, A, B, C, and D are each independently selected from hydrogen, aliphatic groups, cycloaliphatic groups, --CH₂ COOH, and --CH₂ COOR, wherein R is an aliphatic group, wherein at least one of A, B, C, and D is --CH₂ COOH or --CH₂ COOR;

##STR7## wherein a is 1, 2, 3, or 4, X is a divalent aliphatic or cycloaliphatic radical, A, B, D, E, and F are each independently selected from hydrogen, aliphatic groups, cycloaliphatic groups, --CH₂ COOH, and --CH₂ COOR, wherein R is an aliphatic group, wherein at least one of A, B, C, D, and E is --CH₂ COOH or --CH₂ COOR;

##STR8## wherein R, R'"'"', R", and R"'"'"' are each independently selected from the group consisting of hydrogen, aliphatic groups, and cycloaliphatic groups, Q is an organic radical, a and c are each 2 or 3, and b is 0, 1, 2, 3, 4, 5, 6, 7, 8, 9, or 10, provided that if b=0, a+cis 2 or 3;

space="preserve" listing-type="equation">R--(CO)--(CO)--R'"'"'

wherein R and R'"'"' are each organic radicals;

space="preserve" listing-type="equation">R--(CO)--(C═

NOH)--R'"'"'

wherein R and R'"'"' are each organic radicals;

space="preserve" listing-type="equation">R--(C═

NOH)--(C═

NOH)--R'"'"'

wherein R and R'"'"' are each organic radicals;

space="preserve" listing-type="equation">HS--R--SH

wherein R is selected from the group consisting of 1,2-disubstituted aliphatic groups, 1,2-disubstituted cycloaliphatic groups, and aromatic groups; and

mixtures thereof.

3. A printing process according to claim 1 wherein the desensitizing material contains a desensitizing agent selected from the group consisting of ethylenediaminetetraacetic acid, tartaric acid, citric acid, nitrilotriacetic acid, triethylenetetraamine, tetramethylethylenediamine, 5-ethyl-5(4-amino-2-azabutyl)-1,9-diamino-3,7-diazanonane, dimethylglyoxime, cyclohexanedione-dioxime, 1,2-dimercaptoethane, 2,3-dimercaptopropanol, trimethyl ester monoacid of trans-cyclohexane-1,2-diamine-N,N,N'"'"',N'"'"'-tetraacetic acid, tetraethyl ester monoacid of diethylenetriamine-N,N,N'"'"',N"-pentaacetic acid, trimethyl ester monoacid of EDTA, and mixtures thereof.

4. A printing process according to claim 1 wherein the desensitizing material contains a desensitizing agent selected from the group consisting of alkyl trimethyl ammonium salts, aryl trimethyl ammonium salts, dialkyl dimethyl ammonium salts, aliphatic amine acetates in which the aliphatic groups are higher than octyl, aryl amine acetates in which the aryl groups are higher than octyl, substituted oxazolines, and mixtures thereof.

5. A printing process according to claim 1 wherein the desensitizing material contains a desensitizing agent selected from the group consisting of dodecyl trimethyl ammonium salts, hexadecyl trimethyl ammonium salts, octadecyl trimethyl ammonium salts, soya trimethyl ammonium salts, benzyl trimethyl ammonium salts, di-coconut dimethyl ammonium salts, di-hydrogenated tallow dimethyl ammonium salts, di-lauryl dimethyl ammonium salts, n-dodecylamine acetate, dodecyl amine, dodecyl diamine, 2,4,4-trimethyl-2-oxazoline, 2-oleyl-4-hydromethyl-2-oxazoline, and mixtures thereof.

6. A printing process according to claim 1 wherein the desensitizing agent in the desensitizing material is ethylenediaminetetraacetic acid.

7. A printing process according to claim 1 wherein the desensitizing agent is present in the desensitizing material in an amount of at least about 0.5 percent by weight.

8. A printing process according to claim 1 wherein the desensitizing agent is present in the desensitizing material in an amount of from about 1 to about 40 percent by weight.

9. A printing process according to claim 1 wherein the desensitizing agent is present in the desensitizing material in an amount of from about 2 to about 20 percent by weight.

10. A printing process according to claim 1 wherein the desensitizing agent is present in the desensitizing material in an amount of from about 2 to about 10 percent by weight.

11. A printing process according to claim 1 wherein the organic component in the desensitizing material is selected from the group consisting of ethylene glycol monomethyl ether, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, dipropylene glycol monomethyl ether, tripropylene glycol monomethyl ether, propylene glycol mono-t-butyl ether, ethylene glycol ethyl ether acetate, ethylene glycol methyl ether acetate, ethylene glycol butyl ether, diethylene glycol butyl ether, diethylene glycol butyl ether acetate, propylene glycol methyl ether acetate, dipropylene glycol methyl ether acetate, tripropylene glycol methyl ether acetate, glycerol, D-sorbitol, ethylene glycol, propylene glycol, propylene carbonate, ethylene carbonate, 1-cyclohexyl-2-pyrrolidone, 1-methyl-2-pyrrolidone, pyrazole, 1,3-dimethyl-2-imidazolidinone, trimethyl phosphate, triethyl phosphate, tributyl phosphate, trioctyl phosphate, tributoxyethyl phosphate, tricresyl phosphate, dimethyl phthalate, diethyl phthalate, dibutyl phthalate, dioctyl phthalate, dialkyl sulfones, dialkyl sulfoxides, aliphatic nitriles, cycloaliphatic nitriles, aromatic nitriles, aliphatic nitro compounds, aliphatic methyl ketones, cycloaliphatic methyl ketones, aromatic methyl ketones, anhydrides, liquid alkanols, 2-amino-2-methyl-1-propanol, methyl diethanol amine, phosphoric acid amides of the formula (R₂ N)₃ PO, wherein R is hydrogen or aliphatic, and mixtures thereof.

12. A printing process according to claim 1 wherein the organic component in the desensitizing material is selected from the group consisting of ethylene glycol monomethyl ether, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, dipropylene glycol monomethyl ether, tripropylene glycol monomethyl ether, propylene glycol mono-t-butyl ether, ethylene glycol ethyl ether acetate, ethylene glycol methyl ether acetate, ethylene glycol butyl ether, diethylene glycol butyl ether, diethylene glycol butyl ether acetate, propylene glycol methyl ether acetate, dipropylene glycol methyl ether acetate, tripropylene glycol methyl ether acetate, glycerol, D-sorbitol, ethylene glycol, propylene glycol, diethylene glycol, liquid alkanols, and mixtures thereof.

13. A printing process according to claim 1 wherein the organic component in the desensitizing material comprises glycerol and diethylene glycol monobutyl ether.

14. A printing process according to claim 1 wherein the organic component in the desensitizing material comprises dipropylene glycol monomethyl ether acetate.

15. A printing process according to claim 1 wherein the organic component in the desensitizing material is present in an amount by weight such that the ratio of water to organic component is from about 98:

2 to about 50;

50.

16. A printing process according to claim 1 wherein the organic component in the desensitizing material is selected from the group consisting of ethylene glycol monomethyl ether, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, dipropylene glycol monomethyl ether, tripropylene glycol monomethyl ether, propylene glycol mono-t-butyl ether, ethylene glycol ethyl ether acetate, ethylene glycol methyl ether acetate, ethylene glycol butyl ether, diethylene glycol butyl ether, diethylene glycol butyl ether acetate, propylene glycol methyl ether acetate, dipropylene glycol methyl ether acetate, tripropylene glycol methyl ether acetate, glycerol, D-sorbitol, ethylene glycol, propylene glycol, propylene carbonate, ethylene carbonate, 1-cyclohexyl-2-pyrrolidone, 1-methyl-2-pyrrolidone, pyrazole, 1,3-dimethyl-2-imidazolidinone, trimethyl phosphate, triethyl phosphate, tributyl phosphate, trioctyl phosphate, tributoxyethyl phosphate, tricresyl phosphate, dimethyl phthalate, diethyl phthalate, dibutyl phthalate, dioctyl phthalate, dialkyl sulfones, dialkyl sulfoxides, aliphatic nitriles, cycloaliphatic nitriles, aromatic nitriles, aliphatic nitro compounds, aliphatic methyl ketones, cycloaliphatic methyl ketones, aromatic methyl ketones, anhydrides, methyl diethanol amine, phosphoric acid amides of the formula (R₂ N)₃ PO, wherein R is hydrogen or aliphatic, and mixtures thereof.

17. A printing process according to claim 1 wherein the organic component in the desensitizing material is selected from the group consisting of ethylene glycol monomethyl ether, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, dipropylene glycol monomethyl ether, tripropylene glycol monomethyl ether, propylene glycol mono-t-butyl ether, ethylene glycol ethyl ether acetate, ethylene glycol methyl ether acetate, ethylene glycol butyl ether, diethylene glycol butyl ether, diethylene glycol butyl ether acetate, propylene glycol methyl ether acetate, dipropylene glycol methyl ether acetate, tripropylene glycol methyl ether acetate, glycerol, D-sorbitol, ethylene glycol, propylene glycol, diethylene glycol, and mixtures thereof.

18. A printing process according to claim 1 wherein the desensitizing material is applied at least twice to a selected area of either (i) at least one surface of one sheet coated with the color former, or (ii) at least one surface of one sheet coated with the color developer.

19. A printing process which comprises (a) incorporating into an imaging apparatus capable of generating both electrostatic images and thermal ink jet images a carbonless paper set comprising a first sheet, a second sheet, and optional intermediate sheets situated between the first sheet and second sheet, wherein the first sheet comprises paper coated on one surface with a color former and the second sheet comprises paper coated on one surface with a color developer, and wherein, when the carbonless paper set is assembled, the surface of the first sheet coated with the color former is in contact with the surface of a sheet coated with the color developer and the surface of the second sheet coated with the color developer is in contact with the surface of a sheet coated with the color former;

(b) generating an electrostatic latent image on an imaging member in the imaging apparatus, developing the latent image with a toner, and contacting the developed image on the imaging member with the first sheet of the carbonless paper set, thereby transferring the developed image to the first sheet;

(c) generating an electrostatic latent image on the imaging member in the imaging apparatus, developing the latent image with a toner, and contacting the developed image on the imaging member with the second sheet of the carbonless paper set, thereby transferring the developed image to the second sheet;

(d) optionally permanently affixing the transferred images to the first and second sheets;

(e) incorporating into ink nozzles in the printing apparatus a desensitizing material comprising water, an organic component, and a desensitizing agent capable of interacting either (i) with the color former so that the color former'"'"'s subsequent ability to interact with the color developer is reduced, or (ii) with the color developer so that the color developer'"'"'s subsequent ability to interact with the color former is reduced; and

(f) selectively heating the desensitizing material in the nozzles in an imagewise pattern, thereby causing droplets of the desensitizing material to be ejected in an imagewise pattern onto either (i) at least one surface of one sheet coated with the color former, or (ii) at least one surface of one sheet coated with the color developer.

20. A printing process which comprises (a) incorporating into a thermal ink jet imaging apparatus having nozzles for containing ink a carbonless paper set comprising a first sheet, a second sheet, and optional intermediate sheets situated between the first sheet and second sheet, wherein the first sheet comprises paper coated on one surface with a color former and the second sheet comprises paper coated on one surface with a color developer, and wherein, when the carbonless paper set is assembled, the surface of the first sheet coated with the color former is in contact with the surface of a sheet coated with the color developer and the surface of the second sheet coated with the color developer is in contact with the surface of a sheet coated with the color former;

(b) incorporating into the printing apparatus an ink jet ink comprising water and a colorant;

(c) selectively heating the ink containing the colorant in the nozzles in an imagewise pattern, thereby causing droplets of the ink containing the colorant to be ejected in an imagewise pattern onto at least one surface of the first sheet;

(d) selectively heating the ink containing the colorant in the nozzles in an imagewise pattern, thereby causing droplets of the ink containing the colorant to be ejected in an imagewise pattern onto at least one surface of the second sheet;

(e) incorporating into the printing apparatus a desensitizing material comprising water, an organic component, and a desensitizing agent capable of interacting either (i) with the color former so that the color former'"'"'s subsequent ability to interact with the color developer is reduced, or (ii) with the color developer so that the color developer'"'"'s subsequent ability to interact with the color former is reduced; and

(f) selectively heating the desensitizing material in the nozzles in an imagewise pattern, thereby causing droplets of the ink containing the desensitizing agent to be ejected in an imagewise pattern onto either (i) at least one surface of one sheet coated with the color former, or (ii) at least one surface of one sheet coated with the color developer.