Fluorescent marking composition and fluorescent mark formed by said composition

• US 5,880,176 A
• Filed: 10/20/1995
• Issued: 03/09/1999
• Est. Priority Date: 10/21/1994
• Status: Expired due to Fees

• Current Assignee: Hitachi Maxell Limited (Hitachi, Ltd.)
• Original Assignee: Hitachi Maxell Limited (Hitachi, Ltd.)
• Inventors: Sueyoshi, Toshinobu, Yamamoto, Yoshinori, Kamoto, Takanori
• Primary Examiner(s): McCamish, Marion
• Assistant Examiner(s): Guarriello, John J.
• Application Number:
  US08/546,456
• Time in Patent Office: 1,236 Days
• Field of Search: 523/172, 523/201, 260/DIG. 38, 106/21 R, 106/21 A, 106/31.14, 106/31.23, 524/522, 524/523, 524/534
• US Class Current: 523/172
• CPC Class Codes: C09D 11/50 Sympathetic, colour changing or similar inks
• CPC Class Codes: Y10S 260/38 Ink

Abstract

A fluorescent marking composition containing particles of an organic material which has a glass transition temperature of at least 30° C. and an average particle size of at least 30 nm, and emitting fluorescence in a visible light range, or absorbing infrared light having a wavelength of at least 700 nm and emitting a light in an infrared wavelength range, which composition is excellent in dispersion stability, light resistance, and heat and light resistance, and provides a mark which does not bleed.

Claims

1. A fluorescent marking composition for ink jet printing, comprising particles of an organic resin having a glass transition temperature of at least 30°

C. and an average particle size of at least 30 nm, and a fluorescent dye emitting fluorescence in a visible light wavelength range that is present in an amount of 0.001 wt. % to 10 wt. %, based on the weight of the particles of the organic resin; and

wherein the organic resin is selected from the group consisting of polymethacrylate, polyacrylate, polyvinyl chloride, benzoquanamine, alkyd, urea, vinyl chloride, vinyl acetate copolymer and aromatic sulfonamide resins.

2. The fluorescent marking composition according to claim 1, wherein said particles comprise hollow particles.

3. The fluorescent marking composition according to claim 1, which is used in an ink jet printer and in which a ratio of a viscosity of the composition (mPa.s) to a nozzle diameter of said ink jet printer (μ

m) is from 0.01 to 1.

4. The fluorescent marking composition according to claim 3, which has a Reynolds number of 10.5 to 2100.

5. The fluorescent marking composition according to claim 3, which has a Weber number of 38.2 to 3360.

6. The fluorescent marking composition according to claim 3, wherein a ratio of a viscosity of said composition (mPa.s) to a surface tension of said composition (mN/m) is from 0.03 to 1.0.

7. An infrared fluorescent marking composition for ink jet printing, comprising particles of an organic resin having a glass transition temperature of at least 30°

C. and an average particle size of at least 30 nm, and an infrared fluorescent dye absorbing infrared light having a wavelength of at least 700 nm and emitting light in an infrared wavelength range that is present in an amount of 0.001 wt. % to 15 wt. %, based on the weight of the particles of the organic resin; and

wherein the organic resin is selected from the group consisting of polymethacrylate, polyacrylate, polyvinyl chloride, benzoquanamine, alkyd, urea, vinyl chloride, vinyl acetate copolymer and aromatic sulfonamide resins.

8. The infrared fluorescent marking composition according to claim 7, wherein said particles comprise hollow particles.

9. The infrared fluorescent marking composition according to claim 7, which is used in an ink jet printer and in which a ratio of a viscosity of the composition (mPa.s) to a nozzle diameter of said ink jet printer (μ

m) is from 0.01 to 1.

10. The infrared fluorescent marking composition accodeing to claim 9, which has a Reynolds number of 10.5 to 2100.

11. The infrared fluorescent marking composition according to claim 9, which has a Weber number of 38.2 to 3360.

12. The infrared fluorescent marking composition according to claim 9, wherein a ratio of a viscosity of said composition (mPa.s) to a surface tension of said composition (mN/m) is from 0.03 to 1.0.

13. A fluorescent mark comprising particles of an organic resin having a glass transition temperature of at least 30°

C. and an average particle size of at least 30 nm, and a fluorescent dye emitting fluorescence in a visible light wavelength range that is present in an amount of 0.001 wt. % to 10 wt. %, based on the weight of the particles of the organic resin;

wherein the organic resin is selected from the group consisting of polymethacrylate, polyacrylate, polyvinyl chloride, benzoquanamine, alkyd, urea, vinyl chloride, vinyl acetate copolymer and aromatic sulfonamide resins.

14. The fluorescent mark according to claim 13, wherein said particles comprise hollow particles.

15. An infrared fluorescent mark comprising particles of an organic resin having a glass transition temperature of at least 30°

C. and an average particle size of at least 30 nm, and an infrared dye absorbing infrared light having a wavelength of at least 700 nm and emitting light in an infrared wavelength range that is present in an amount of 0.001 wt % to 15 wt. %, based on the weight of the particles of the organic resin; and

wherein the organic resin is selected from the group consisting of polymethacrylate, polyacrylate, polyvinyl chloride, benzoquanamine, alkyd, urea, vinyl chloride, vinyl acetate copolymer and aromatic sulfonamide resins.

16. The infrared florescent mark according to claim 15, wherein said particles comprise hollow particles.

17. The infrared fluorescent mark according to claim 15, wherein a rise time from 10% to 90% of the maximum light emitting output is 10 μ

sec. or less, when infrared light is irradiated on said mark.