Polycyclic iminooxadiazinediones from (cyclo)aliphatic 1,4-diisocyanates

• US 5,882,544 A
• Filed: 12/11/1997
• Issued: 03/16/1999
• Est. Priority Date: 12/20/1996
• Status: Expired due to Term

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Richter, Frank, Mager, Dieter, Pedain, Josef
• Primary Examiner(s): Richter, Johann
• Assistant Examiner(s): KEATING, DOMINIC J
• Application Number:
  US08/989,066
• Time in Patent Office: 460 Days
• Field of Search: 540/545, 540/552, 544/67, 544/68, 514/229.2, 594/68, 252/183.12
• US Class Current: 252/183.12
• CPC Class Codes: C07D 498/04 Ortho-condensed systems
• CPC Class Codes: C08G 18/79 characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
• CPC Class Codes: C08G 2101/00 Manufacture of cellular products
• CPC Class Codes: C08G 2150/20 Compositions for powder coatings

Abstract

The present invention relates to polycyclic iminooxadiazinediones A corresponding to formula I ##STR1## The present invention also relates to mixtures of these polycyclic iminooxadiazinediones with other isocyanate derivatives and to their use for the production of optionally foamed polyurethane plastics, for the production of paints and coatings and for the production or formulation of active ingredients, pharmaceutical products, etc.

Claims

1. A polycyclic iminooxadiazinedione corresponding to formula (I) ##STR8## wherein R¹ to R⁸ are identical or different and represent hydrogen or alkyl, cycloalkyl, aralkyl and aryl groups, which may be substituted by isocyanato(cyclo)alkyl groups or by groups which are not reactive with isocyanate groups, or R¹ and/or R² form one or more, optionally partially unsaturated rings, with one another and also with one or more substituents from among R³ to R⁸ and the corresponding carbon atoms of the seven membered ring segment in A or R³ or R⁴ form an aromatic ring with R⁵ or R⁶ and with the two carbon atoms of the seven-membered ring segment in A which are not bonded to nitrogen, and

R⁹ represents hydrogen or an alkyl, cycloalkyl, alralkyl, aryl, or heterocyclic, group which may be substituted by isocyanato(cyclo)alkyl groups or by groups which are not reactive with isocyanate groups.

2. The polycyclic iminooxadiazinedione of claim 1, wherein

R⁹ represents a group corresponding to formula II ##STR9## wherein R¹ to R⁸ are as previously defined.

3. The polycyclic iminooxadiazinedione of claim 1 which has been prepared from an optionally branched, open-chain aliphatic diisocyanate wherein the two isocyanate groups are arranged in the 1,4 positions to one another.

5. A composition containing at least 10 mole % of the polycyclic iminooxadiazinedione of claim 1, in which the remainder comprises an isocyanate derivative containing isocyanurate, uretdione, biuret, allophanate, carbodiimide and/or urethane groups wherein the isocyanate groups may optionally be present in blocked form.

6. A composition for the preparation of an optionally foamed, polyurethane plastics or for the production of a coating which contains the polycyclic iminooxadiazinedione of claim 1.

4. 10-(4-isocyanatobutyl)-8-oxa-1,6,10-triazabicyclo-undec-6-en-9,11 -dione corresponding to the formula ##STR10##