Process of manufacturing porous separator for electrochemical power supply

• US 5,882,721 A
• Filed: 05/01/1997
• Issued: 03/16/1999
• Est. Priority Date: 05/01/1997
• Status: Expired due to Term

• Current Assignee: IMRA America Incorporated (Aisin Corp.)
• Original Assignee: IMRA America Incorporated (Aisin Corp.)
• Inventors: Delnick, Frank M.
• Primary Examiner(s): Gorgus, Kathryn
• Assistant Examiner(s): Parsons, Thomas H.
• Application Number:
  US08/847,098
• Time in Patent Office: 684 Days
• Field of Search: 429/189, 429/190, 429/194, 429/248, 429/249, 429/252, 429/191, 429/192, 429/193, 427/77, 427/243, 427/247
• US Class Current: 427/77
• CPC Class Codes: H01G 11/52 Separators
• CPC Class Codes: H01G 11/84 Processes for the manufacture of hybrid or EDL capacitors, or components thereof
• CPC Class Codes: H01M 50/434 Ceramics
• CPC Class Codes: H01M 50/443 Particulate material
• CPC Class Codes: H01M 50/46 Separators, membranes or diaphragms characterised by their combination with electrodes
• CPC Class Codes: H01M 50/491 Porosity
• CPC Class Codes: H01M 8/0293 Matrices for immobilising electrolyte solutions
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

A method of forming a porous composite separator layer for an electrochemical cell comprising the steps of printing a thin layer of a separator precursor solution on the surface of one of the electrochemical cell electrodes, curing the thin layer of separator precursor solution so that it transforms into a microporous composite separator structure. In the preferred embodiment, the separator precursor solution is formulated as an ink comprising a silica aerogel filler material dispersed in a solution of polymer binder which is dissolved in a suitable solvent. The process allows the manufacture of thin and flexible composite separators which are conformally bonded to the underlying electrodes.

Claims

1. A process for fabricating a composite separator layer having electrolyte fillable voids for an electrochemical cell which includes an electrode, comprising the steps of:

disposing a solution of separator precursor on said electrode wherein said solution comprises a solid particulate material and a polymer binder, the weight ratio of said binder to said solid particulate material is selected between 5/95 and 50/50; and

transforming said solution of separator precursor so that voids from between particles of said solid particulate material.

2. The process of claim 1, wherein said solid particulate material comprises a material selected from the group consisting of silica aerogel, fumed silica, silica gel, silica hydrogel, silica xerogel, silica sol, colloidal silica, alumina, titania, magnesia, kaolin, talc, diatomaceous earth, calcium silicate, calcium carbonate, magnesium carbonate, and mixtures thereof.

3. The process of claim 1, wherein said polymer binder comprises a material selected from the group consisting of polyvinyl chloride, polyvinylidene fluoride-hexafluoropropylene copolymer and ethylene propylene hexadiene monomer.

4. The process of claim 1, wherein said step of disposing a solution of separator precursor on said electrode comprises using a printing technique to dispose said solution of precursor on said electrode.

5. The process of claim 1, wherein said step of transforming said solution of separator precursor on said electrode comprises curing said solution of separator precursor to form a porous separator layer.

6. The process of claim 5, wherein said separator layer has a thickness in the range of 5μ

to 100μ

.

7. The process of claim 5, wherein said step of curing comprises applying heat to said solution of separator precursor in a vacuum oven at a temperature of about 90°

-130°

C. so that said solution of separator precursor forms said separator layer.

8. A process for fabricating a porous composite separator for an electrochemical cell which includes an electrode, comprising the steps of:

disposing a solution of separator precursor on said electrode wherein said solution comprises 60% to 95% by mass of 1,2,3,4-Tetrahydronaphthalene (THN) solvent; and

curing said solution of separator precursor so that said solution of separator precursor forms a porous composite separator that adheres to said electrode.

9. The process of claim 8, wherein said step of disposing a solution of separator precursor on said electrode comprises using a printing technique to dispose said solution of precursor on said electrode.

10. The process of claim 8, wherein said step of curing comprises applying heat to said solution of separator precursor in a vacuum oven at a temperature of about 90°

-130°

C. so that said solution of separator precursor forms said porous separator material.

11. A process of forming a separator layer having electrolyte fillable voids for an electrochemical cell which includes an electrode, comprising:

printing a continuous layer of said separator on said electrode by disposing a solution comprised of a solid particulate material, a binder for said solid particulate material and a solvent to dissolve said binder wherein the weight ratio of said binder to said solid particulate material is selected between 5/95 and 50/50; and

curing said layer to form interconnected empty interstices between particles of said solid particulate material therein.

12. The process of claim 11, wherein said binder comprises a material selected from the group consisting of polyvinyl chloride, polyvinylidene fluoride-hexafluoropropylene copolymer and ethylene propylene hexadiene monomer.

13. The process of claim 11, wherein said solid particulate material comprises a material selected from the group consisting of silica aerogel, fumed silica, silica gel, silica hydrogel, silica xerogel, silica sol, colloidal silica, alumina, titania, magnesia, kaolin, talc, diatomaceous earth, calcium silicate, calcium carbonate, magnesium carbonate, and mixtures thereof.

14. The process of claim 11, wherein said step of curing comprises applying heat to said continuous layer of separator on said electrode in a vacuum oven at a temperature of about 90°

-130°

C.

15. The process of claim 11, wherein said step of printing said continuous layer of said separator on said electrode comprises using either a stencil or a screen printing technique.

16. A process of forming a separator layer having electrolyte fillable voids for an electrochemical cell which includes an electrode, comprising:

conformally bonding a continuous layer of said separator on said electrode by disposing a solution comprised of a solid particulate material, a polymer binder for said solid particulate material and 60% to 95% by mass 1,2,3,4-Tetrahydronaphthalene (THN) solvent to dissolve said polymer binder wherein the weight ratio of said polymer binder to said solid particulate material is selected between 5/95 and 50/50; and

curing said layer to form micropores therein.

17. The process of claim 16, wherein said solid particulate material comprises a material selected from the group consisting of silica aerogel, fumed silica, silica gel, silica hydrogel, silica xerogel, silica sol, colloidal silica, alumina, titania, magnesia, kaolin, talc, diatomaceous earth, calcium silicate, calcium carbonate, magnesium carbonate, and mixtures thereof.

18. The process of claim 16, wherein said polymer binder comprises a material selected from the group consisting of polyvinyl chloride, polyvinylidene fluoride-hexafluoropropylene copolymer and ethylene propylene hexadiene monomer.

19. The process of claim 16, wherein said step of disposing said solution on said electrode comprises using a printing technique to dispose said solution on said electrode.

20. The process of claim 16, wherein said step of curing comprises applying heat to said continuous layer of separator on said electrode in a vacuum oven at a temperature of about 90°

-130°

C.

21. A process for fabricating a separator layer having electrolyte fillable voids for an electrochemical cell, comprising:

providing a sheet of solid particles separated by interconnected voids; and

binding said solid particles together without filling said voids.

22. A process as defined in claim 21 wherein said providing step comprises disposing said sheet of solid particles on a substrate.

23. A process as defined in claim 22 wherein said providing step further comprises disposing a binding agent and a solvent within said sheet of solid particles.

24. A process as defined in claim 23 wherein said binding step comprises evaporating said solvent.

25. A process as defined in claim 24 wherein said substrate comprises an electrode.

26. A process for fabricating a separator layer having electrolyte fillable voids for an electrochemical cell, comprising:

providing an electrode; and

forming a continuous layer of solid particulate material and solvent on said electrode; and

removing said solvent from said layer.

27. A process as defined in claim 26 wherein said forming step additionally comprises including a binder within said continuous layer to form electrolyte fillable voids in said layer.

28. A process as defined in claim 26 wherein said continuous layer is not self supporting without said electrode.

29. A process as defined in claim 26 wherein said forming step comprises printing.

30. A process for fabricating a separator layer having electrolyte fillable voids for an electrochemical cell, comprising:

providing an electrode; and

forming a non-self-supporting separator layer of insulating material having said voids on said electrode.

31. A process for fabricating a separator for an electrochemical cell as defined in claim 30, wherein said forming step comprises printing.

32. A process for fabricating a separator for an electrochemical cell as defined in claim 30 wherein said forming step comprises forming a continuous layer.