Method and device for introducing liquid into an exhaust-gas purification system

• US 5,884,475 A
• Filed: 03/13/1997
• Issued: 03/23/1999
• Est. Priority Date: 09/13/1994
• Status: Expired due to Term

• Current Assignee: Johnson Matthey Catalysts (Germany) Gmbh (Johnson Matthey PLC)
• Original Assignee: Siemens AG
• Inventors: Hofmann, Lothar, Mathes, Wieland, Neufert, Ronald
• Primary Examiner(s): Denion, Thomas E.
• Application Number:
  US08/816,365
• Time in Patent Office: 740 Days
• Field of Search: 60/302, 60/299, 60/301, 60/286, 60/303, 60/274
• US Class Current: 60/274
• CPC Class Codes: B01D 53/9431 Processes characterised by a specific device
• CPC Class Codes: B01D 53/9495 Controlling the catalytic process
• CPC Class Codes: F01N 2240/02 a heat exchanger
• CPC Class Codes: F01N 2240/16 an electric heater, i.e. a resistance heater
• CPC Class Codes: F01N 2610/02 the substance being ammonia or urea
• CPC Class Codes: F01N 2610/08 with prior mixing of the substances with a gas, e.g. air
• CPC Class Codes: F01N 2610/10 the substance being heated, e.g. by heating tank or supply line of the added substance
• CPC Class Codes: F01N 2610/1406 Storage means for substances, e.g. tanks or reservoirs
• CPC Class Codes: F01N 2610/1486 Means to prevent the substance from freezing
• CPC Class Codes: F01N 2610/1493 Purging the reducing agent out of the conduits or nozzle
• CPC Class Codes: F01N 3/2066 Selective catalytic reduction [SCR]
• CPC Class Codes: F23J 15/003 for supplying chemicals to fumes, e.g. using injection devices
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

Nitrogen oxides emitted by an internal-combustion engine operated with excess air are normally converted by the method of selective catalytic reduction by bringing the nitrogen oxides, together with ammonia, into contact with a selective catalyst. Due to the dangers associated with the use of ammonia, in a motor vehicle ammonia should only be carried in the form of a substance which liberates ammonia, generally an aqueous urea solution. A method and a device for introducing liquid into an exhaust-gas purification system according to the invention avoids frost damage to sections of the system during shutdown times and permits operation of the system at temperatures below the freezing point of the reducing agent solution being used. The method and device include a (thermally insulated) reservoir for the reducing agent liquid and a liquid supply line which is connected thereto and terminates in an outlet opening for the liquid. The reservoir and the liquid supply line can be heated. Furthermore, a heater is provided for liquefying a starting volume which is small as compared with the volume of the reservoir. The liquid supply line may also have a back-flush valve to which a gas that is under pressure can be applied. The supply line can consequently be blown free.

Claims

1. A method for operating an exhaust-gas purification device, which comprises:

drawing a liquid from a reservoir through a supply line;

introducing the liquid into an exhaust gas in an exhaust of a combustion system during combustion, for chemical purification of the exhaust gas; and

draining at least a section of the supply line with a pressurized gas during a shutdown of the combustion system.

2. The method according to claim 1, which comprises feeding the pressurized gas through a pressurized-gas inlet and a valve into the supply line between the reservoir and the exhaust of the combustion system, for draining a part of the supply line between the pressurized-gas inlet and the reservoir into the reservoir, and for draining a part of the supply line between the pressurized-gas inlet and the exhaust into the exhaust.

3. The method according to claim 1, which comprises introducing an aqueous urea solution as the liquid into the exhaust gas of an internal-combustion engine of a motor vehicle as the combustion system.

4. The method according to claim 3, which comprises operating the internal-combustion engine operated with an excess of air.

7. The method according to claim 3, which comprises introducing an aqueous urea solution as the liquid into the exhaust gas of an internal-combustion engine of a motor vehicle as the combustion system.

8. The,method according to claim 7, which comprises operating the internal-combustion engine operated with an excess of air.

5. A method of operating an exhaust-gas purification device, which comprises:

drawing a liquid through a supply line from a reservoir having a given volume;

introducing the liquid into an exhaust gas in an exhaust of a combustion system during combustion, for chemical purification of the exhaust gas; and

heating a starting volume of the liquid being smaller than the given volume with a heater and introducing the starting volume into the exhaust gas, no later than during startup of the combustion system.

6. The method according to claim 5, which comprises storing the starting volume of the liquid in a further container.

9. A device for operating an exhaust-gas purification device, comprising:

a reservoir for a liquid;

a supply line connected between said reservoir and an exhaust-gas purification device;

a pressurized-gas inlet; and

a valve connected between said pressurized-gas inlet and said supply line for introducing pressurized gas into said supply line in a direction towards said reservoir.

10. The device according to claim 9, wherein said valve is a back-flush valve disposed in said supply line.

11. The device according to claim 10, including further back-flushable structural components disposed in said liquid supply line between said valve and said reservoir.

12. The device according to claim 9, wherein said valve has a first state permitting a flow through said supply line from said reservoir to the exhaust-gas purification device and a second state permitting a flow through said supply line from said pressurized-gas inlet to said reservoir.

13. The device according to claim 12, wherein said valve has a third state in which said reservoir is closed.

14. The device according to claim 12, wherein said valve configuration has a state in which said pressurized-gas inlet is connected to the exhaust-gas purification device.

15. The device according to claim 13, wherein said valve configuration has a state in which said pressurized-gas inlet is connected to the exhaust-gas purification device.

16. The device according to claim 9, wherein the pressurized gas is introduced into said supply line at a location immediately alongside the exhaust-gas purification device.

17. The device according to claim 9, wherein the pressurized gas is introduced into said supply line at a location nearer to the exhaust-gas purification device than to said reservoir.

18. The device according to claim 9, including a device for heating said liquid supply line.

19. The device according to claim 18, wherein said reservoir has a given volume, and including an intermediate container associated with said heatable liquid supply line for a volume of the liquid smaller than said given volume.

20. The device according to claim 9, wherein said reservoir has a given volume, and including a heater for liquefying a starting volume of the liquid smaller than said given volume.

21. The device according to claim 20, wherein said heater for the starting volume is ad electrical heater.

22. The device according to claim 20, wherein said reservoir is a tank, and including an intermediate container accommodating the starting volume.

23. The device according to claim 22, including a device for heating at least said tank and said supply line with a liquid heating medium.

24. The device according to claim 20, including a device for heating said supply line electrically.

25. The device according to claim 20, including a device associated with said reservoir for at least one of temperature monitoring and temperature control.

26. An exhaust-gas purification system of a utility motor vehicle having an internal-combustion engine, the system comprising:

a reservoir for a liquid;

a supply line connected between said reservoir and an exhaust-gas purification device;

a pressurized-gas inlet; and

a valve connected between said pressurized-gas inlet and said supply line for introducing pressurized gas into said supply line in a direction towards said reservoir.

27. The system according to claim 26, wherein the internal-combustion engine is operated with an excess of air.