Method of decontaminating soils and/or residues in situ and ex situ combining horizontal radial flow technique and depolluting agents

• US 5,885,203 A
• Filed: 12/24/1996
• Issued: 03/23/1999
• Est. Priority Date: 06/28/1994
• Status: Expired due to Fees

• Current Assignee: Brascan Technology Fund
• Original Assignee: Les Expertises Environmentales Soconag Inc.
• Inventors: Pelletier, Marc-Antoine
• Primary Examiner(s): Suchfield, George A.
• Application Number:
  US08/765,480
• Time in Patent Office: 819 Days
• Field of Search: 588/205, 588/249, 588/900, 405/128, 405/129, 210/170, 210/747, 210/901, 435/262.5
• US Class Current: 588/249
• CPC Class Codes: B09C 1/005 Extraction of vapours or gases using vacuum or venting
• CPC Class Codes: B09C 1/02 Extraction using liquids, e.g. washing, leaching , flotation
• CPC Class Codes: B09C 1/06 thermally
• CPC Class Codes: B09C 1/08 chemically
• CPC Class Codes: B09C 1/10 microbiologically, biologically or by using enzymes
• CPC Class Codes: B09C 1/105 using fungi or plants
• CPC Class Codes: B09C 2101/00 In situ
• CPC Class Codes: Y10S 588/90 Apparatus

Abstract

A process for in situ remediation of contaminated soils and/or residues is disclosed. This process takes advantage of a horizontal radial flow irrigating/draining system and sensors (8) located at midspacing between parallel conduit lines (5) to create an environment propitious to the action of decontaminating agents (plants, microorganisms, salts, acids, bases, buffers, enzymes, substrates, surfactants, etc.). For example, a water-saturated zone may be created, the level of water containing decontaminating agents is raised, maintained and/or lowered, which water-saturated encourage desorption or solubilization of soluble contaminants, by adjusting and controlling all the parameters of reaction (time, temperature, pH, oxygenation, etc.) The process is easily adaptably for many classes of contaminants, including volatile compounds and light non-aqueous phase liquids, by further installing supplementary sets of conduit lines and pumping means at adequate levels. The site may be remedied by alternating gaseous and liquid modes to optimize the conditions of reaction, which alternation is advantageously achieved in a multi-unit arrangement, one unit being in gaseous mode while another is in liquid mode.

Claims

1. A system for conducting remediation of a body of contaminated flow-permeable matter, comprising:

a set of mutually spaced apart flow-producing members for producing a remediation-effective flow in said body;

a multi-level set of sensors for measuring at least one parameter related to said remediation-effective flow, said sensors each lying in a generally vertical plane situated between two adjacent flow-producing members of said set substantially at equal horizontal distance from said two adjacent flow-producing members; and

means for controlling the remediation-effective flow into said body in relation to said at least one measured parameter.

2. A system for conducting remediation of a body of contaminated flow-permeable matter as recited in claim 1, wherein said multi-level set of sensors comprises a generally vertical linear array of sensors.

3. A system for conducting in situ remediation of a body of contaminated fluid-permeable matter, comprising:

a subsurface conduit network comprising a plurality of laterally spaced apart, fluid-permeable conduit lines;

flow producing means connected to the subsurface conduit network for producing a flow of at least one remediation-effective fluid into the body of contaminated fluid-permeable matter;

a subsurface, multi-level set of sensors for measuring at least one fluid-related parameter, said sensors each lying in a generally vertical plane situated between two adjacent fluid-permeable conduit lines substantially at equal horizontal distance from said two adjacent fluid-permeable conduit lines; and

means for controlling the flow of said at least one remediation-effective fluid into said body in relation to said at least one measured parameter.

4. A system for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 3, wherein said subsurface, multi-level set of sensors comprises a generally vertical linear array of sensors.

5. A system for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 3, wherein said sensors are selected from the group consisting of:

aerodynamic sensors, hydrodynamic sensors, piezometric sensors, CO₂ metric sensors, O₂ metric sensors, pH metric sensors, nutrient metric sensors, photometric sensors, radiometric sensors, thermometric sensors and combinations thereof.

6. A system for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 3, further comprising means for substantially sealing a bottom and sides of said body of contaminated fluid-permeable matter.

7. A system for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 3, wherein said flow producing means comprises:

means for injecting said at least one remediation-effective fluid into the body of contaminated fluid-permeable matter through said subsurface conduit network; and

means for withdrawing said at least one remediation-effective fluid from the body of contaminated fluid-permeable matter through said subsurface conduit network.

8. A system for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 3, wherein said at least one remediation-effective fluid is a remediation-effective liquid and wherein said flow producing means comprises:

means for injecting said at least one remediation-effective liquid into the body of contaminated fluid-permeable matter through said subsurface conduit network; and

means for withdrawing, through said subsurface conduit network, said at least one remediation-effective liquid from the body of contaminated fluid-permeable matter when said at least one measured parameter indicates that replacement or amendment of said liquid is required.

9. A system for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 8, wherein said flow producing means further comprises means for maintaining, under the control of said flow controlling means, said at least one remediation-effective liquid into the body of contaminated fluid-permeable matter until said at least one measured parameter indicates that replacement or amendment of said liquid is required.

10. A system for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 7, wherein said at least one remediation-effective fluid is a gaseous and/or liquid fluid.

11. A system for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 3, wherein the laterally spaced apart, fluid-permeable conduit lines lie into a generally horizontal plane, and wherein said laterally spaced apart, fluid-permeable conduit lines are generally parallel to each other.

12. A system for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 3, wherein:

the subsurface conduit network is divided into a first conduit network section and a second conduit network section; and

said flow producing means comprises;

(a) means for injecting said at least one remediation-effective fluid into the body of contaminated fluid-permeable matter through one of said first and second conduit network sections and means for withdrawing, through the other of said first and second conduit network sections, said at least one remediation-effective fluid from the body of contaminated fluid-permeable matter;

(b) means for injecting said at least one remediation-effective fluid into the body of contaminated fluid-permeable matter through both said first and second conduit network sections; and

(c) means for withdrawing, through both said first and second conduit network sections, said at least one remediation-effective fluid from the body of contaminated fluid-permeable matter.

13. A system for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 10, wherein said first and second conduit network sections are both lying in the body of contaminated fluid-permeable matter substantially at the same level.

14. A system for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 12, wherein said first and second conduit network sections are lying in the body of contaminated fluid-permeable matter at different levels.

15. A system for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 3, wherein said at least one remediation-effective fluid is a liquid containing at least one decontaminating agent selected from the group consisting of:

bacteria, acids, bases, salts, buffers, chelator agents, vitamins, nutrient source substrates, enzymes surfactants, and combinations thereof.

16. A system for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 3, wherein said body comprises a top layer of soil for growing plants that contribute to remediation of said body.

17. A system for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 3, further comprising remediation-effective means selected from the group consisting of heating means, vibrating means, electric means, magnetic means and combinations thereof implanted into the body of contaminated fluid-permeable matter to contribute to remediation of said body.

18. A process for conducting remediation of a body of contaminated flow-permeable matter, comprising the steps of:

producing a remediation-effective flow in said body through a set of mutually spaced apart flow-producing members;

measuring at least one parameter related to said remediation-effective flow at a plurality of different sensing levels comprising sensors, with each sensor lying in a generally vertical plane situated between two adjacent flow-producing members of said set substantially at equal horizontal distance from said two adjacent flow-producing members; and

controlling the remediation-effective flow into said body in relation to said at least one measured parameter.

19. A process for conducting in situ remediation of a body of contaminated fluid-permeable matter, comprising the steps of:

installing a subsurface conduit network comprising a plurality of laterally spaced apart, fluid-permeable conduit lines;

producing a flow of at least one remediation-effective fluid into the body of contaminated fluid-permeable matter through the subsurface conduit network;

measuring at least one fluid-related parameter at a plurality of different sensing levels comprising sensors, with each sensor lying in a generally vertical plane situated between two adjacent fluid-permeable conduit lines substantially at equal horizontal distance from said two adjacent fluid-permeable conduit lines; and

controlling the flow of said at least one remediation-effective fluid into said body in relation to said at least one measured parameter.

20. A process for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 19, wherein said flow producing step comprises the steps of:

injecting said at least one remediation-effective fluid into the body of contaminated fluid-permeable matter through said subsurface conduit network; and

withdrawing said at least one remediation-effective fluid from the body of contaminated fluid-permeable matter through said subsurface conduit network.

21. A process for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 19, wherein said remediation-effective fluid is a remediation-effective liquid and wherein said flow producing step comprises the steps of:

injecting said at least one remediation-effective liquid into the body of contaminated fluid-permeable matter through said subsurface conduit network; and

withdrawing, through said subsurface conduit network, said at least one remediation-effective liquid from the body of contaminated fluid-permeable matter when said at least one measured parameter indicates that replacement or amendment of said liquid is required.

22. A process for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 21, wherein said flow producing step further comprises the step of maintaining, under the control of said flow controlling step, said at least one remediation-effective liquid into the body of contaminated fluid-permeable matter until said at least one measured parameter indicates that replacement or amendment of said liquid is required.

23. A process for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 19, wherein said remediation-effective fluid is a gaseous and/or liquid fluid.

24. A process for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 19, wherein:

the subsurface conduit network is divided into a first conduit network section and a second conduit network section; and

said flow producing step comprises at least one of the following steps;

(a) a step of injecting said at least one remediation-effective fluid into the body of contaminated fluid-permeable matter through one of said first and second conduit network sections and a step of withdrawing, through the other of said first and second conduit network sections, said at least one remediation-effective fluid from the body of contaminated fluid-permeable matter;

(b) a step of injecting said at least one remediation-effective fluid into the body of contaminated fluid-permeable matter through both said first and second conduit network sections; and

(c) a step of withdrawing, through both said first and second conduit network sections, said at least one remediation-effective fluid from the body of contaminated fluid-permeable matter.

25. A process for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 19, wherein said flow producing step comprises a step of producing a flow of remediation-effective liquid and a step of producing a flow of remediation-effective gaseous fluid.

26. A process for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 19, wherein said flow producing step comprises the step of producing alternately a flow of remediation-effective liquid and a flow of remediation-effective gaseous fluid.

27. A process for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 19, wherein said remediation-effective fluid is a liquid, said process further comprising the step of adding in said liquid at least one decontaminating agent selected from the group consisting of:

bacteria, acids, bases, salts, buffers, chelator agents, vitamins, nutrient source substrates, enzymes surfactants, and combinations thereof.

28. A process for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 19, further comprising the step of growing, on a top layer of soil of said body, plants that contribute to remediation of said body.

29. A process for conducting in situ remediation of a body of contaminated fluid-permeable matter as recited in claim 19, further comprising the step of sealing a bottom and sides of said body of contaminated fluid-permeable matter.